ChemInform Abstract: Proximal Ester Assistance vs. Stereoelectronic Prohibition in Catalytic N‐Acyliminium Ion Reactions: Stereoselective Formation of Aza‐Heterocycles with Two Contiguous Quaternary‐Tertiary Stereocenters.
Identifieur interne : 000074 ( Istex/Checkpoint ); précédent : 000073; suivant : 000075ChemInform Abstract: Proximal Ester Assistance vs. Stereoelectronic Prohibition in Catalytic N‐Acyliminium Ion Reactions: Stereoselective Formation of Aza‐Heterocycles with Two Contiguous Quaternary‐Tertiary Stereocenters.
Auteurs : Moussa Saber ; Sebastien Comesse ; Vincent Dalla ; Pierre Netchitailo ; Adam DaichSource :
- ChemInform [ 0931-7597 ] ; 2012-02-07.
English descriptors
Abstract
The intermolecular and intramolecular α‐amidoalkylation of hemicyclic N,O‐acetals proceeds in the presence of NHTf2.
Url:
DOI: 10.1002/chin.201206098
Affiliations:
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<front><div type="abstract" xml:lang="en">The intermolecular and intramolecular α‐amidoalkylation of hemicyclic N,O‐acetals proceeds in the presence of NHTf2.</div>
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