Synthesis of thienothiazocinoisoindolediones and thienothiazinoisoindolones from mercaptothiophenes and chloromethylphthalimide
Identifieur interne : 001294 ( France/Analysis ); précédent : 001293; suivant : 001295Synthesis of thienothiazocinoisoindolediones and thienothiazinoisoindolones from mercaptothiophenes and chloromethylphthalimide
Auteurs : Pierre Netchitaïlo [France] ; Mohamed Othman [France] ; Bernard Decroix [France]Source :
- Journal of Heterocyclic Chemistry [ 0022-152X ] ; 1997-01.
Abstract
2‐Thienylthiomethylphthalimides 3a,b were synthesized by action of Chloromethylphthalimide on 2‐or 3‐mercaptothiophene. Reduction of 3a,b and Wittig reaction using carbethoxycarbonyltriphenyl‐phosphorane gave the corresponding acetic acids 5a,b which cyclized under Friedel and Crafts conditions to lead the thienothiazocinoisoindolediones 6a,b. Thienothiazinoisoindolones 7a,b were obtained from hydroxyisoindolones derivatives 4a,b in acid conditions via an acyliminium ion.
Url:
DOI: 10.1002/jhet.5570340150
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000076
- to stream Istex, to step Curation: 000076
- to stream Istex, to step Checkpoint: 000D16
- to stream Main, to step Merge: 001E25
- to stream Main, to step Curation: 001D73
- to stream Main, to step Exploration: 001D73
- to stream France, to step Extraction: 001294
Links to Exploration step
ISTEX:AAF58EF18C872C0B92DCB2B5B2CA3952900B3CB9Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthesis of thienothiazocinoisoindolediones and thienothiazinoisoindolones from mercaptothiophenes and chloromethylphthalimide</title><author><name sortKey="Netchitailo, Pierre" sort="Netchitailo, Pierre" uniqKey="Netchitailo P" first="Pierre" last="Netchitaïlo">Pierre Netchitaïlo</name></author><author><name sortKey="Othman, Mohamed" sort="Othman, Mohamed" uniqKey="Othman M" first="Mohamed" last="Othman">Mohamed Othman</name></author><author><name sortKey="Decroix, Bernard" sort="Decroix, Bernard" uniqKey="Decroix B" first="Bernard" last="Decroix">Bernard Decroix</name><affiliation><country>France</country><placeName><settlement type="city">Le Havre</settlement><region type="region" nuts="2">Région Normandie</region><region type="old region" nuts="2">Haute-Normandie</region></placeName><orgName type="university" n="3">Université du Havre</orgName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:AAF58EF18C872C0B92DCB2B5B2CA3952900B3CB9</idno><date when="1997" year="1997">1997</date><idno type="doi">10.1002/jhet.5570340150</idno><idno type="url">https://api.istex.fr/document/AAF58EF18C872C0B92DCB2B5B2CA3952900B3CB9/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000076</idno><idno type="wicri:Area/Istex/Curation">000076</idno><idno type="wicri:Area/Istex/Checkpoint">000D16</idno><idno type="wicri:doubleKey">0022-152X:1997:Netchitailo P:synthesis:of:thienothiazocinoisoindolediones</idno><idno type="wicri:Area/Main/Merge">001E25</idno><idno type="wicri:Area/Main/Curation">001D73</idno><idno type="wicri:Area/Main/Exploration">001D73</idno><idno type="wicri:Area/France/Extraction">001294</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Synthesis of thienothiazocinoisoindolediones and thienothiazinoisoindolones from mercaptothiophenes and chloromethylphthalimide</title><author><name sortKey="Netchitailo, Pierre" sort="Netchitailo, Pierre" uniqKey="Netchitailo P" first="Pierre" last="Netchitaïlo">Pierre Netchitaïlo</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de chimie, Université Le Havre, 30 rue Gabriel Peri, 76600 Le Havre</wicri:regionArea><placeName><region type="region" nuts="2">Région Normandie</region><region type="old region" nuts="2">Haute-Normandie</region><settlement type="city">Le Havre</settlement></placeName></affiliation></author><author><name sortKey="Othman, Mohamed" sort="Othman, Mohamed" uniqKey="Othman M" first="Mohamed" last="Othman">Mohamed Othman</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de chimie, Université Le Havre, 30 rue Gabriel Peri, 76600 Le Havre</wicri:regionArea><placeName><region type="region" nuts="2">Région Normandie</region><region type="old region" nuts="2">Haute-Normandie</region><settlement type="city">Le Havre</settlement></placeName></affiliation></author><author><name sortKey="Decroix, Bernard" sort="Decroix, Bernard" uniqKey="Decroix B" first="Bernard" last="Decroix">Bernard Decroix</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de chimie, Université Le Havre, 30 rue Gabriel Peri, 76600 Le Havre</wicri:regionArea><placeName><region type="region" nuts="2">Région Normandie</region><region type="old region" nuts="2">Haute-Normandie</region><settlement type="city">Le Havre</settlement></placeName><placeName><settlement type="city">Le Havre</settlement><region type="region" nuts="2">Région Normandie</region><region type="old region" nuts="2">Haute-Normandie</region></placeName><orgName type="university" n="3">Université du Havre</orgName></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Heterocyclic Chemistry</title><idno type="ISSN">0022-152X</idno><idno type="eISSN">1943-5193</idno><imprint><publisher>Wiley‐Blackwell</publisher><pubPlace>Hoboken</pubPlace><date type="published" when="1997-01">1997-01</date><biblScope unit="volume">34</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="321">321</biblScope><biblScope unit="page" to="324">324</biblScope></imprint><idno type="ISSN">0022-152X</idno></series><idno type="istex">AAF58EF18C872C0B92DCB2B5B2CA3952900B3CB9</idno><idno type="DOI">10.1002/jhet.5570340150</idno><idno type="ArticleID">JHET5570340150</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-152X</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">2‐Thienylthiomethylphthalimides 3a,b were synthesized by action of Chloromethylphthalimide on 2‐or 3‐mercaptothiophene. Reduction of 3a,b and Wittig reaction using carbethoxycarbonyltriphenyl‐phosphorane gave the corresponding acetic acids 5a,b which cyclized under Friedel and Crafts conditions to lead the thienothiazocinoisoindolediones 6a,b. Thienothiazinoisoindolones 7a,b were obtained from hydroxyisoindolones derivatives 4a,b in acid conditions via an acyliminium ion.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Haute-Normandie</li><li>Région Normandie</li></region><settlement><li>Le Havre</li></settlement><orgName><li>Université du Havre</li></orgName></list><tree><country name="France"><region name="Région Normandie"><name sortKey="Netchitailo, Pierre" sort="Netchitailo, Pierre" uniqKey="Netchitailo P" first="Pierre" last="Netchitaïlo">Pierre Netchitaïlo</name></region><name sortKey="Decroix, Bernard" sort="Decroix, Bernard" uniqKey="Decroix B" first="Bernard" last="Decroix">Bernard Decroix</name><name sortKey="Othman, Mohamed" sort="Othman, Mohamed" uniqKey="Othman M" first="Mohamed" last="Othman">Mohamed Othman</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/France/explor/LeHavreV1/Data/France/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001294 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 001294 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/France
|area= LeHavreV1
|flux= France
|étape= Analysis
|type= RBID
|clé= ISTEX:AAF58EF18C872C0B92DCB2B5B2CA3952900B3CB9
|texte= Synthesis of thienothiazocinoisoindolediones and thienothiazinoisoindolones from mercaptothiophenes and chloromethylphthalimide
}}
| This area was generated with Dilib version V0.6.25. |  |