Solvent-driven room-temperature synthesis of nanoparticles BiPO4:Eu3+.
Identifieur interne : 000062 ( PubMed/Checkpoint ); précédent : 000061; suivant : 000063Solvent-driven room-temperature synthesis of nanoparticles BiPO4:Eu3+.
Auteurs : Chaochao Fu [République populaire de Chine] ; Guangshe Li ; Minglei Zhao ; Liusai Yang ; Jing Zheng ; Liping LiSource :
- Inorganic chemistry [ 1520-510X ] ; 2012.
Abstract
In this work, a novel solvent-driven room-temperature synthesis of BiPO(4):Eu(3+) nanoparticles was presented. By virtue of 11 solvents with different properties and function groups, phase structure and composition of BiPO(4):Eu(3+) can be systematically tailored. Hexagonal phase (HP) of BiPO(4):Eu(3+) was obtained in water and hydrophobic organic solvents such as arenes and cyclohexane, while low-temperature monoclinic phase (LTMP) was prepared in hydrophilic alcohols. In other solvents (i.e., hydrophilic ethers, aldehydes, ketones, and carboxylic acids), a mixture of HP and LTMP was formed, in which the relative content of LTMP gradually increased following the above solvent sequence. It is also found that particle sizes of BiPO(4):Eu(3+) nanoparticles were closely related to the phase structure: HP exhibited a comparatively larger particle size. The phase evolution processes for both polymorphs with varying solvents were investigated in details. Photoluminescence (PL) properties were sensitive to the phase structure and compositions of the final products. With increasing the phase content of LTMP, the lifetimes and quantum yields both increased. The methodology reported here is fundamentally important, which may give a novel insight into the polymorph-controlled synthesis for further optimized materials performance.
DOI: 10.1021/ic300465r
PubMed: 22554087
Affiliations:
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By virtue of 11 solvents with different properties and function groups, phase structure and composition of BiPO(4):Eu(3+) can be systematically tailored. Hexagonal phase (HP) of BiPO(4):Eu(3+) was obtained in water and hydrophobic organic solvents such as arenes and cyclohexane, while low-temperature monoclinic phase (LTMP) was prepared in hydrophilic alcohols. In other solvents (i.e., hydrophilic ethers, aldehydes, ketones, and carboxylic acids), a mixture of HP and LTMP was formed, in which the relative content of LTMP gradually increased following the above solvent sequence. It is also found that particle sizes of BiPO(4):Eu(3+) nanoparticles were closely related to the phase structure: HP exhibited a comparatively larger particle size. The phase evolution processes for both polymorphs with varying solvents were investigated in details. Photoluminescence (PL) properties were sensitive to the phase structure and compositions of the final products. With increasing the phase content of LTMP, the lifetimes and quantum yields both increased. The methodology reported here is fundamentally important, which may give a novel insight into the polymorph-controlled synthesis for further optimized materials performance.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">22554087</PMID><DateCreated><Year>2012</Year><Month>05</Month><Day>21</Day></DateCreated><DateCompleted><Year>2012</Year><Month>09</Month><Day>07</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-510X</ISSN><JournalIssue CitedMedium="Internet"><Volume>51</Volume><Issue>10</Issue><PubDate><Year>2012</Year><Month>May</Month><Day>21</Day></PubDate></JournalIssue><Title>Inorganic chemistry</Title><ISOAbbreviation>Inorg Chem</ISOAbbreviation></Journal><ArticleTitle>Solvent-driven room-temperature synthesis of nanoparticles BiPO4:Eu3+.</ArticleTitle><Pagination><MedlinePgn>5869-80</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/ic300465r</ELocationID><Abstract><AbstractText>In this work, a novel solvent-driven room-temperature synthesis of BiPO(4):Eu(3+) nanoparticles was presented. By virtue of 11 solvents with different properties and function groups, phase structure and composition of BiPO(4):Eu(3+) can be systematically tailored. Hexagonal phase (HP) of BiPO(4):Eu(3+) was obtained in water and hydrophobic organic solvents such as arenes and cyclohexane, while low-temperature monoclinic phase (LTMP) was prepared in hydrophilic alcohols. In other solvents (i.e., hydrophilic ethers, aldehydes, ketones, and carboxylic acids), a mixture of HP and LTMP was formed, in which the relative content of LTMP gradually increased following the above solvent sequence. It is also found that particle sizes of BiPO(4):Eu(3+) nanoparticles were closely related to the phase structure: HP exhibited a comparatively larger particle size. The phase evolution processes for both polymorphs with varying solvents were investigated in details. Photoluminescence (PL) properties were sensitive to the phase structure and compositions of the final products. With increasing the phase content of LTMP, the lifetimes and quantum yields both increased. The methodology reported here is fundamentally important, which may give a novel insight into the polymorph-controlled synthesis for further optimized materials performance.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Fu</LastName><ForeName>Chaochao</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>Key Lab of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Graduate School of Chinese Academy of Sciences, Fuzhou 350002, People's Republic of China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Guangshe</ForeName><Initials>G</Initials></Author><Author ValidYN="Y"><LastName>Zhao</LastName><ForeName>Minglei</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Yang</LastName><ForeName>Liusai</ForeName><Initials>L</Initials></Author><Author ValidYN="Y"><LastName>Zheng</LastName><ForeName>Jing</ForeName><Initials>J</Initials></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Liping</ForeName><Initials>L</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>05</Month><Day>03</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Inorg Chem</MedlineTA><NlmUniqueID>0366543</NlmUniqueID><ISSNLinking>0020-1669</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2012</Year><Month>5</Month><Day>3</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>5</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>5</Month><Day>5</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>5</Month><Day>5</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/ic300465r</ArticleId><ArticleId IdType="pubmed">22554087</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>République populaire de Chine</li></country><region><li>Fujian</li></region><settlement><li>Fuzhou</li></settlement></list><tree><noCountry><name sortKey="Li, Guangshe" sort="Li, Guangshe" uniqKey="Li G" first="Guangshe" last="Li">Guangshe Li</name><name sortKey="Li, Liping" sort="Li, Liping" uniqKey="Li L" first="Liping" last="Li">Liping Li</name><name sortKey="Yang, Liusai" sort="Yang, Liusai" uniqKey="Yang L" first="Liusai" last="Yang">Liusai Yang</name><name sortKey="Zhao, Minglei" sort="Zhao, Minglei" uniqKey="Zhao M" first="Minglei" last="Zhao">Minglei Zhao</name><name sortKey="Zheng, Jing" sort="Zheng, Jing" uniqKey="Zheng J" first="Jing" last="Zheng">Jing Zheng</name></noCountry><country name="République populaire de Chine"><region name="Fujian"><name sortKey="Fu, Chaochao" sort="Fu, Chaochao" uniqKey="Fu C" first="Chaochao" last="Fu">Chaochao Fu</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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