An experimental and kinetic investigation of premixed furan/oxygen/argon flames
Identifieur interne : 000169 ( Pmc/Curation ); précédent : 000168; suivant : 000170An experimental and kinetic investigation of premixed furan/oxygen/argon flames
Auteurs : Zhenyu Tian [France, République populaire de Chine] ; Tao Yuan [République populaire de Chine] ; Rene Fournet [France] ; Pierre-Alexandre Glaude [France] ; Baptiste Sirjean [France] ; Frédérique Battin-Leclerc [France] ; Kuiwen Zhang [République populaire de Chine] ; Fei Qi [République populaire de Chine]Source :
- Combustion and flame [ 0010-2180 ] ; 2011.
Abstract
The detailed chemical structures of three low-pressure (35 Torr) premixed laminar furan/oxygen/argon flames with equivalence ratios of 1.4, 1.8 and 2.2 have been investigated by using tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry. About 40 combustion species including hydrocarbons and oxygenated intermediates have been identified by measurements of photoionization efficiency spectra. Mole fraction profiles of the flame species including reactants, intermediates and products have been determined by scanning burner position with some selected photon energies near ionization thresholds. Flame temperatures have been measured by a Pt-6%Rh/Pt-30%Rh thermocouple. A new mechanism involving 206 species and 1368 reactions has been proposed whose predictions are in reasonable agreement with measured species profiles for the three investigated flames. Rate-of-production and sensitivity analyses have been performed to track the key reaction paths governing furan consumption for different equivalence ratios. Both experimental and modeling results indicate that few aromatics could be formed in these flames. Furthermore, the current model has been validated against previous pyrolysis results of the literature obtained behind shock waves and the agreement is reasonable as well.
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DOI: 10.1016/j.combustflame.2010.12.022
PubMed: 23814311
PubMed Central: 3695461
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R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author><author><name sortKey="Qi, Fei" sort="Qi, Fei" uniqKey="Qi F" first="Fei" last="Qi">Fei Qi</name><affiliation wicri:level="1"><nlm:aff id="A2">National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">23814311</idno><idno type="pmc">3695461</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3695461</idno><idno type="RBID">PMC:3695461</idno><idno type="doi">10.1016/j.combustflame.2010.12.022</idno><date when="2011">2011</date><idno type="wicri:Area/Pmc/Corpus">000169</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000169</idno><idno type="wicri:Area/Pmc/Curation">000169</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000169</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">An experimental and kinetic investigation of premixed furan/oxygen/argon flames</title><author><name sortKey="Tian, Zhenyu" sort="Tian, Zhenyu" uniqKey="Tian Z" first="Zhenyu" last="Tian">Zhenyu Tian</name><affiliation wicri:level="1"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex</wicri:regionArea></affiliation><affiliation wicri:level="1"><nlm:aff id="A2">National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author><author><name sortKey="Yuan, Tao" sort="Yuan, Tao" uniqKey="Yuan T" first="Tao" last="Yuan">Tao Yuan</name><affiliation wicri:level="1"><nlm:aff id="A2">National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author><author><name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="Rene" last="Fournet">Rene Fournet</name><affiliation wicri:level="1"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex</wicri:regionArea></affiliation></author><author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name><affiliation wicri:level="1"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex</wicri:regionArea></affiliation></author><author><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name><affiliation wicri:level="1"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex</wicri:regionArea></affiliation></author><author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation wicri:level="1"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex</wicri:regionArea></affiliation></author><author><name sortKey="Zhang, Kuiwen" sort="Zhang, Kuiwen" uniqKey="Zhang K" first="Kuiwen" last="Zhang">Kuiwen Zhang</name><affiliation wicri:level="1"><nlm:aff id="A2">National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author><author><name sortKey="Qi, Fei" sort="Qi, Fei" uniqKey="Qi F" first="Fei" last="Qi">Fei Qi</name><affiliation wicri:level="1"><nlm:aff id="A2">National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029</wicri:regionArea></affiliation></author></analytic><series><title level="j">Combustion and flame</title><idno type="ISSN">0010-2180</idno><idno type="eISSN">1556-2921</idno><imprint><date when="2011">2011</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p id="P2">The detailed chemical structures of three low-pressure (35 Torr) premixed laminar furan/oxygen/argon flames with equivalence ratios of 1.4, 1.8 and 2.2 have been investigated by using tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry. About 40 combustion species including hydrocarbons and oxygenated intermediates have been identified by measurements of photoionization efficiency spectra. Mole fraction profiles of the flame species including reactants, intermediates and products have been determined by scanning burner position with some selected photon energies near ionization thresholds. Flame temperatures have been measured by a Pt-6%Rh/Pt-30%Rh thermocouple. A new mechanism involving 206 species and 1368 reactions has been proposed whose predictions are in reasonable agreement with measured species profiles for the three investigated flames. Rate-of-production and sensitivity analyses have been performed to track the key reaction paths governing furan consumption for different equivalence ratios. Both experimental and modeling results indicate that few aromatics could be formed in these flames. Furthermore, the current model has been validated against previous pyrolysis results of the literature obtained behind shock waves and the agreement is reasonable as well.</p></div></front></TEI><pmc article-type="research-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
<pmc-dir>properties manuscript</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-journal-id">9891739</journal-id><journal-id journal-id-type="pubmed-jr-id">41274</journal-id><journal-id journal-id-type="nlm-ta">Combust Flame</journal-id><journal-id journal-id-type="iso-abbrev">Combust Flame</journal-id><journal-title-group><journal-title>Combustion and flame</journal-title></journal-title-group><issn pub-type="ppub">0010-2180</issn><issn pub-type="epub">1556-2921</issn></journal-meta><article-meta><article-id pub-id-type="pmid">23814311</article-id><article-id pub-id-type="pmc">3695461</article-id><article-id pub-id-type="doi">10.1016/j.combustflame.2010.12.022</article-id><article-id pub-id-type="manuscript">EMS53645</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title-group><article-title>An experimental and kinetic investigation of premixed furan/oxygen/argon flames</article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Tian</surname><given-names>Zhenyu</given-names></name><xref ref-type="aff" rid="A1">1</xref><xref ref-type="aff" rid="A2">2</xref><xref ref-type="author-notes" rid="FN1">†</xref></contrib><contrib contrib-type="author"><name><surname>Yuan</surname><given-names>Tao</given-names></name><xref ref-type="aff" rid="A2">2</xref></contrib><contrib contrib-type="author"><name><surname>Fournet</surname><given-names>Rene</given-names></name><xref ref-type="aff" rid="A1">1</xref></contrib><contrib contrib-type="author"><name><surname>Glaude</surname><given-names>Pierre-Alexandre</given-names></name><xref ref-type="aff" rid="A1">1</xref></contrib><contrib contrib-type="author"><name><surname>Sirjean</surname><given-names>Baptiste</given-names></name><xref ref-type="aff" rid="A1">1</xref></contrib><contrib contrib-type="author"><name><surname>Battin-Leclerc</surname><given-names>Frédérique</given-names></name><xref ref-type="aff" rid="A1">1</xref><xref ref-type="corresp" rid="CR1">*</xref></contrib><contrib contrib-type="author"><name><surname>Zhang</surname><given-names>Kuiwen</given-names></name><xref ref-type="aff" rid="A2">2</xref></contrib><contrib contrib-type="author"><name><surname>Qi</surname><given-names>Fei</given-names></name><xref ref-type="aff" rid="A2">2</xref><xref ref-type="corresp" rid="CR1">*</xref></contrib></contrib-group><aff id="A1"><label>1</label>Laboratoire Réactions et Génie des Procédés, CNRS, Nancy Université, ENSIC, 1, rue Grandville, BP 451, 54001 Nancy Cedex, France</aff><aff id="A2"><label>2</label>National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China</aff><author-notes><corresp id="CR1"><label>*</label>Corresponding authors Dr. Frédérique Battin-Leclerc (FBL) <email>Frederique.Battin-Leclerc@ensic.inpl-nancy.fr</email> Tel: 0033(0)3 83 17 51 25 Fax: 0033(0)3 83 37 81 20 Prof. Fei Qi (FQ) <email>fqi@ustc.edu.cn</email> Tel: 0086(0)551 3602125 Fax: 0086(0)551 5141078
</corresp><fn fn-type="present-address" id="FN1"><label>†</label><p id="P1">Current address: Physikalische Chemie I, Universität Bielefeld, Universitätsstr. 25, 33615 Bielefeld, Germany.</p></fn></author-notes><pub-date pub-type="nihms-submitted"><day>11</day><month>6</month><year>2013</year></pub-date><pub-date pub-type="ppub"><month>4</month><year>2011</year></pub-date><pub-date pub-type="pmc-release"><day>28</day><month>6</month><year>2013</year></pub-date><volume>158</volume><issue>4</issue><fpage>756</fpage><lpage>773</lpage><self-uri xlink:href="http://www.sciencedirect.com/science/article/pii/S0010218010003767"></self-uri><abstract><p id="P2">The detailed chemical structures of three low-pressure (35 Torr) premixed laminar furan/oxygen/argon flames with equivalence ratios of 1.4, 1.8 and 2.2 have been investigated by using tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry. About 40 combustion species including hydrocarbons and oxygenated intermediates have been identified by measurements of photoionization efficiency spectra. Mole fraction profiles of the flame species including reactants, intermediates and products have been determined by scanning burner position with some selected photon energies near ionization thresholds. Flame temperatures have been measured by a Pt-6%Rh/Pt-30%Rh thermocouple. A new mechanism involving 206 species and 1368 reactions has been proposed whose predictions are in reasonable agreement with measured species profiles for the three investigated flames. Rate-of-production and sensitivity analyses have been performed to track the key reaction paths governing furan consumption for different equivalence ratios. Both experimental and modeling results indicate that few aromatics could be formed in these flames. Furthermore, the current model has been validated against previous pyrolysis results of the literature obtained behind shock waves and the agreement is reasonable as well.</p></abstract><kwd-group><kwd>Premixed laminar flame</kwd><kwd>Kinetic modeling</kwd><kwd>Furan</kwd><kwd>Tunable synchrotron VUV photoionization</kwd><kwd>Molecular-beam mass spectrometry</kwd></kwd-group><funding-group><award-group><funding-source country="International">European Research Council : </funding-source><award-id>227669 || ERC_</award-id></award-group></funding-group></article-meta></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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