Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes
Identifieur interne : 000147 ( Pmc/Corpus ); précédent : 000146; suivant : 000148Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes
Auteurs : Olivier Herbinet ; Sarah Bax ; Pierre-Alexandre Glaude ; Vincent Carré ; Frédérique Battin-LeclercSource :
- Fuel (London, England) [ 0016-2361 ] ; 2011.
Abstract
Cyclic ethers are important intermediate species formed during the low-temperature oxidation of hydrocarbons. Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification.
Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available.
Url:
DOI: 10.1016/j.fuel.2010.09.047
PubMed: 24092947
PubMed Central: 3787300
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PMC:3787300Le document en format XML
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Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification.</p><p id="P2">Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available.</p></div></front></TEI><pmc article-type="research-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
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<front><journal-meta><journal-id journal-id-type="nlm-journal-id">101556828</journal-id><journal-id journal-id-type="pubmed-jr-id">41758</journal-id><journal-id journal-id-type="nlm-ta">Fuel (Lond)</journal-id><journal-id journal-id-type="iso-abbrev">Fuel (Lond)</journal-id><journal-title-group><journal-title>Fuel (London, England)</journal-title></journal-title-group><issn pub-type="ppub">0016-2361</issn><issn pub-type="epub">1873-7153</issn></journal-meta><article-meta><article-id pub-id-type="pmid">24092947</article-id><article-id pub-id-type="pmc">3787300</article-id><article-id pub-id-type="doi">10.1016/j.fuel.2010.09.047</article-id><article-id pub-id-type="manuscript">EMS53507</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title-group><article-title>Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes</article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Herbinet</surname><given-names>Olivier</given-names></name><xref ref-type="aff" rid="A1">a</xref><xref ref-type="corresp" rid="CR1">*</xref></contrib><contrib contrib-type="author"><name><surname>Bax</surname><given-names>Sarah</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Glaude</surname><given-names>Pierre-Alexandre</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Carré</surname><given-names>Vincent</given-names></name><xref ref-type="aff" rid="A2">b</xref></contrib><contrib contrib-type="author"><name><surname>Battin-Leclerc</surname><given-names>Frédérique</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib></contrib-group><aff id="A1"><label>a</label>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS UPR 3349, BP 20451, 1 rue Grandville, 54000 Nancy, France</aff><aff id="A2"><label>b</label>Laboratoire de Spectrométrie de Masse et de Chimie Laser, Institut Jean Barriol–Fédération de Recherche 2843, Université Paul Verlaine–Metz, 1, Boulevard Arago, 57078 Metz,Technopole Cedex 03, France</aff><author-notes><corresp id="CR1"><label>*</label>Corresponding author: Olivier Herbinet, Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS UPR 3349, BP 20451, 1 rue Grandville, 54000 Nancy, France. Tel : +33 3 83 17 53 60 ; Fax : +33 3 83 37 81 20 <email>olivier.herbinet@ensic.inpl-nancy.fr</email></corresp></author-notes><pub-date pub-type="nihms-submitted"><day>23</day><month>9</month><year>2013</year></pub-date><pub-date pub-type="ppub"><month>2</month><year>2011</year></pub-date><pub-date pub-type="pmc-release"><day>01</day><month>10</month><year>2013</year></pub-date><volume>90</volume><issue>2</issue><fpage>528</fpage><lpage>535</lpage><self-uri xlink:href="http://www.sciencedirect.com/science/article/pii/S0016236110005181"></self-uri><abstract><p id="P1">Cyclic ethers are important intermediate species formed during the low-temperature oxidation of hydrocarbons. Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification.</p><p id="P2">Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available.</p></abstract><kwd-group><kwd>Cyclic ether</kwd><kwd>Engine exhaust gases</kwd><kwd>Combusion</kwd><kwd>n-Alkanes</kwd><kwd>Mass spectrum</kwd></kwd-group><funding-group><award-group><funding-source country="International">European Research Council : </funding-source><award-id>227669 || ERC_</award-id></award-group></funding-group></article-meta></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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