LrgpV1, PascalFrancis, Curation, bibRecord, 000296

Controlled polymerization of functional monomers and synthesis of block copolymers using a β-phosphonylated nitroxide

Identifieur interne : 000296 ( PascalFrancis/Curation ); précédent : 000295; suivant : 000297

Controlled polymerization of functional monomers and synthesis of block copolymers using a β-phosphonylated nitroxide

Auteurs : T. Diaz [France] ; A. Fischer [France] ; A. Jonquikres [France] ; A. Brembilla [France] ; P. Lochon [France]

Source :

Macromolecules [ 0024-9297 ] ; 2003.

RBID : Pascal:03-0251666

Descripteurs français

Pascal (Inist)
- Régulateur réaction, Nitroxyle, Phosphonate organique, Polymérisation radicalaire, Polymérisation masse, Acrylamide dérivé polymère, Pyridine(4-vinyl)polymère, Polymère vivant, Préparation, Acrylamide dérivé copolymère, Copolymère biséquencé, Pyridine(4-vinyl)copolymère, Etude expérimentale, Acrylamide(N,N-diméthyl) polymère, Acrylamide(N,N-diméthyl) copolymère.

English descriptors

KwdEn :
- Acrylamide derivative copolymer, Acrylamide derivative polymer, Bulk polymerization, Diblock copolymer, Experimental study, Free radical polymerization, Living polymer, Nitroxyl, Organic phosphonate, Preparation, Pyridine(4-vinyl) copolymer, Pyridine(4-vinyl) polymer, Reaction regulator.

Abstract

4-Vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) were polymerized in a controlled manner using a β-phosphonylated nitroxide (N-tert-butyl-N-( 1-diethylphosphono-2,2-dimethyl-propyl) nitroxide, commonly designated as DEPN) as a control agent. Compared to the results that had previously been reported for the nitroxide-mediated radical polymerization (NMRP) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), the polymerization of 4VP was much faster and very well controlled up to higher monomer conversions. Unlike 4VP, the controlled radical polymerization of DMAA using different types of nitroxides had so far remained limited to a very low conversion range (typically inferior to 10%). The use of DEPN gave rise to a very significant improvement of the NMRP of DMAA by providing a good reaction control up to high conversion (approximately 60%). For the first time, the ability of DEPN to control the homopolymerization of DMAA even at high conversion allowed the synthesis of poly(DMAA-b-4VP) block copolymers with a hydrophilic poly(DMAA) block which was longer than the poly(4VP) block. This particular feature should fairly improve the hydrosolubility of the derived amphiphilic cationic polymers, which can be obtained by simple quaternization of the former block copolymers, and extend the scope of their applications.

A01	`01`	`1`		`@0 0024-9297`
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A08	`01`	`1`	`ENG`	`@1 Controlled polymerization of functional monomers and synthesis of block copolymers using a β-phosphonylated nitroxide`
A11	`01`	`1`		`@1 DIAZ (T.)`
A11	`02`	`1`		`@1 FISCHER (A.)`
A11	`03`	`1`		`@1 JONQUIKRES (A.)`
A11	`04`	`1`		`@1 BREMBILLA (A.)`
A11	`05`	`1`		`@1 LOCHON (P.)`
A14	`01`			`@1 Equipe de Chimie Physique Organique et Colloïdale, Unité Mixte de Recherche CNRS-UHP 7565, Université Henri Poincaré-Nancy 1, B.P. 239 @2 54506 Vandoeuvre-les-Nancy @3 FRA @Z 1 aut. @Z 2 aut. @Z 4 aut.`
A14	`02`			`@1 Laboratoire de Chimie Physique Macromoléculaire, Unité Mixte de Recherche CNRS-INPL 7568, Groupe ENSIC, 1, rue Grandville-B. P. 451 @2 54001 Nancy @3 FRA @Z 3 aut. @Z 5 aut.`
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A21				`@1 2003`
A23	`01`			`@0 ENG`
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A44				`@0 0000 @1 © 2003 INIST-CNRS. All rights reserved.`
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A61				`@0 A`
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C01	`01`		`ENG`	@0 4-Vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) were polymerized in a controlled manner using a β-phosphonylated nitroxide (N-tert-butyl-N-( 1-diethylphosphono-2,2-dimethyl-propyl) nitroxide, commonly designated as DEPN) as a control agent. Compared to the results that had previously been reported for the nitroxide-mediated radical polymerization (NMRP) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), the polymerization of 4VP was much faster and very well controlled up to higher monomer conversions. Unlike 4VP, the controlled radical polymerization of DMAA using different types of nitroxides had so far remained limited to a very low conversion range (typically inferior to 10%). The use of DEPN gave rise to a very significant improvement of the NMRP of DMAA by providing a good reaction control up to high conversion (approximately 60%). For the first time, the ability of DEPN to control the homopolymerization of DMAA even at high conversion allowed the synthesis of poly(DMAA-b-4VP) block copolymers with a hydrophilic poly(DMAA) block which was longer than the poly(4VP) block. This particular feature should fairly improve the hydrosolubility of the derived amphiphilic cationic polymers, which can be obtained by simple quaternization of the former block copolymers, and extend the scope of their applications.
C02	`01`	`X`		`@0 001D09D02B`
C03	`01`	`X`	`FRE`	`@0 Régulateur réaction @5 01`
C03	`01`	`X`	`ENG`	`@0 Reaction regulator @5 01`
C03	`01`	`X`	`SPA`	`@0 Regulador reacción @5 01`
C03	`02`	`X`	`FRE`	`@0 Nitroxyle @1 ACT @5 02`
C03	`02`	`X`	`ENG`	`@0 Nitroxyl @1 ACT @5 02`
C03	`02`	`X`	`SPA`	`@0 Nitroxilo @1 ACT @5 02`
C03	`03`	`X`	`FRE`	`@0 Phosphonate organique @1 ACT @5 03`
C03	`03`	`X`	`ENG`	`@0 Organic phosphonate @1 ACT @5 03`
C03	`03`	`X`	`SPA`	`@0 Fosfonato orgánico @1 ACT @5 03`
C03	`04`	`X`	`FRE`	`@0 Polymérisation radicalaire @5 06`
C03	`04`	`X`	`ENG`	`@0 Free radical polymerization @5 06`
C03	`04`	`X`	`SPA`	`@0 Polimerización radicalar @5 06`
C03	`05`	`X`	`FRE`	`@0 Polymérisation masse @5 07`
C03	`05`	`X`	`ENG`	`@0 Bulk polymerization @5 07`
C03	`05`	`X`	`SPA`	`@0 Polimerización masa @5 07`
C03	`06`	`X`	`FRE`	`@0 Acrylamide dérivé polymère @2 NK @5 08`
C03	`06`	`X`	`ENG`	`@0 Acrylamide derivative polymer @2 NK @5 08`
C03	`06`	`X`	`SPA`	`@0 Acrilamida derivado polímero @2 NK @5 08`
C03	`07`	`X`	`FRE`	`@0 Pyridine(4-vinyl)polymère @2 NK @5 09 @6 Pyridine(«4»-vinyl)polymère`
C03	`07`	`X`	`ENG`	`@0 Pyridine(4-vinyl) polymer @2 NK @5 09`
C03	`07`	`X`	`SPA`	`@0 Piridina(4-vinil) polímero @2 NK @5 09`
C03	`08`	`X`	`FRE`	`@0 Polymère vivant @5 10`
C03	`08`	`X`	`ENG`	`@0 Living polymer @5 10`
C03	`08`	`X`	`SPA`	`@0 Polímero viviente @5 10`
C03	`09`	`X`	`FRE`	`@0 Préparation @5 12`
C03	`09`	`X`	`ENG`	`@0 Preparation @5 12`
C03	`09`	`X`	`SPA`	`@0 Preparación @5 12`
C03	`10`	`X`	`FRE`	`@0 Acrylamide dérivé copolymère @2 NK @5 13`
C03	`10`	`X`	`ENG`	`@0 Acrylamide derivative copolymer @2 NK @5 13`
C03	`10`	`X`	`SPA`	`@0 Acrilamida derivado copolímero @2 NK @5 13`
C03	`11`	`X`	`FRE`	`@0 Copolymère biséquencé @2 NK @5 14`
C03	`11`	`X`	`ENG`	`@0 Diblock copolymer @2 NK @5 14`
C03	`11`	`X`	`SPA`	`@0 Copolímero bisecuencia @2 NK @5 14`
C03	`12`	`X`	`FRE`	`@0 Pyridine(4-vinyl)copolymère @2 NK @5 15 @6 Pyridine(«4»-vinyl)copolymère`
C03	`12`	`X`	`ENG`	`@0 Pyridine(4-vinyl) copolymer @2 NK @5 15`
C03	`12`	`X`	`SPA`	`@0 Piridina(4-vinil) copolímero @2 NK @5 15`
C03	`13`	`X`	`FRE`	`@0 Etude expérimentale @5 17`
C03	`13`	`X`	`ENG`	`@0 Experimental study @5 17`
C03	`13`	`X`	`SPA`	`@0 Estudio experimental @5 17`
C03	`14`	`X`	`FRE`	`@0 Acrylamide(N,N-diméthyl) polymère @2 NK @4 INC @5 32 @6 Acrylamide(«N,N»-diméthyl) polymère`
C03	`15`	`X`	`FRE`	`@0 Acrylamide(N,N-diméthyl) copolymère @2 NK @4 INC @5 33 @6 Acrylamide(«N,N»-diméthyl) copolymère`
N21				`@1 160`
N82				`@1 PSI`

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Pascal:03-0251666

Le document en format XML

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<series><title level="j" type="main">Macromolecules</title>
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<term>Experimental study</term>
<term>Free radical polymerization</term>
<term>Living polymer</term>
<term>Nitroxyl</term>
<term>Organic phosphonate</term>
<term>Preparation</term>
<term>Pyridine(4-vinyl) copolymer</term>
<term>Pyridine(4-vinyl) polymer</term>
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</keywords>
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<front><div type="abstract" xml:lang="en">4-Vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) were polymerized in a controlled manner using a β-phosphonylated nitroxide (N-tert-butyl-N-( 1-diethylphosphono-2,2-dimethyl-propyl) nitroxide, commonly designated as DEPN) as a control agent. Compared to the results that had previously been reported for the nitroxide-mediated radical polymerization (NMRP) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), the polymerization of 4VP was much faster and very well controlled up to higher monomer conversions. Unlike 4VP, the controlled radical polymerization of DMAA using different types of nitroxides had so far remained limited to a very low conversion range (typically inferior to 10%). The use of DEPN gave rise to a very significant improvement of the NMRP of DMAA by providing a good reaction control up to high conversion (approximately 60%). For the first time, the ability of DEPN to control the homopolymerization of DMAA even at high conversion allowed the synthesis of poly(DMAA-b-4VP) block copolymers with a hydrophilic poly(DMAA) block which was longer than the poly(4VP) block. This particular feature should fairly improve the hydrosolubility of the derived amphiphilic cationic polymers, which can be obtained by simple quaternization of the former block copolymers, and extend the scope of their applications.</div>
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<fC01 i1="01" l="ENG"><s0>4-Vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) were polymerized in a controlled manner using a β-phosphonylated nitroxide (N-tert-butyl-N-( 1-diethylphosphono-2,2-dimethyl-propyl) nitroxide, commonly designated as DEPN) as a control agent. Compared to the results that had previously been reported for the nitroxide-mediated radical polymerization (NMRP) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), the polymerization of 4VP was much faster and very well controlled up to higher monomer conversions. Unlike 4VP, the controlled radical polymerization of DMAA using different types of nitroxides had so far remained limited to a very low conversion range (typically inferior to 10%). The use of DEPN gave rise to a very significant improvement of the NMRP of DMAA by providing a good reaction control up to high conversion (approximately 60%). For the first time, the ability of DEPN to control the homopolymerization of DMAA even at high conversion allowed the synthesis of poly(DMAA-b-4VP) block copolymers with a hydrophilic poly(DMAA) block which was longer than the poly(4VP) block. This particular feature should fairly improve the hydrosolubility of the derived amphiphilic cationic polymers, which can be obtained by simple quaternization of the former block copolymers, and extend the scope of their applications.</s0>
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<fC03 i1="01" i2="X" l="FRE"><s0>Régulateur réaction</s0>
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<fC03 i1="02" i2="X" l="FRE"><s0>Nitroxyle</s0>
<s1>ACT</s1>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Nitroxyl</s0>
<s1>ACT</s1>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Nitroxilo</s0>
<s1>ACT</s1>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Phosphonate organique</s0>
<s1>ACT</s1>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Organic phosphonate</s0>
<s1>ACT</s1>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Fosfonato orgánico</s0>
<s1>ACT</s1>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Polymérisation radicalaire</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Free radical polymerization</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Polimerización radicalar</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Polymérisation masse</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Bulk polymerization</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Polimerización masa</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Acrylamide dérivé polymère</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Acrylamide derivative polymer</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Acrilamida derivado polímero</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Pyridine(4-vinyl)polymère</s0>
<s2>NK</s2>
<s5>09</s5>
<s6>Pyridine(«4»-vinyl)polymère</s6>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Pyridine(4-vinyl) polymer</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Piridina(4-vinil) polímero</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Polymère vivant</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Living polymer</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Polímero viviente</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Préparation</s0>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Preparation</s0>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Preparación</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Acrylamide dérivé copolymère</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Acrylamide derivative copolymer</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Acrilamida derivado copolímero</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Copolymère biséquencé</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Diblock copolymer</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Copolímero bisecuencia</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Pyridine(4-vinyl)copolymère</s0>
<s2>NK</s2>
<s5>15</s5>
<s6>Pyridine(«4»-vinyl)copolymère</s6>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Pyridine(4-vinyl) copolymer</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Piridina(4-vinil) copolímero</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Acrylamide(N,N-diméthyl) polymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>32</s5>
<s6>Acrylamide(«N,N»-diméthyl) polymère</s6>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Acrylamide(N,N-diméthyl) copolymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>33</s5>
<s6>Acrylamide(«N,N»-diméthyl) copolymère</s6>
</fC03>
<fN21><s1>160</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Controlled polymerization of functional monomers and synthesis of block copolymers using a β-phosphonylated nitroxide

Controlled polymerization of functional monomers and synthesis of block copolymers using a β-phosphonylated nitroxide

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