Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines
Identifieur interne : 000B62 ( PascalFrancis/Corpus ); précédent : 000B61; suivant : 000B63Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines
Auteurs : V. Prevost ; A. Petit ; F. PlaSource :
- Synthetic metals [ 0379-6779 ] ; 1999.
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Abstract
The chemical oxidative copolymerization of aniline (An) with o-alkoxysulfonated anilines, i.e., 1-(o-amino)-propane-3-sulfonic acid (APPrS) and 1-(o-amino)-butane-3-sulfonic acid (APBuS), was a new way to produce water-soluble and self-doped polyaniline derivatives. Poly(An-co-APPrS) and poly(An-co-APBuS) were obtained in H2SO4 acidic medium by chemical oxidation, using ammonium persulfate, of a comonomer mixture containing An and APPrS, or APBuS, in various initial ratios. The copolymers thus obtained with high or low yields, were characterized by elemental microanalysis, FTIR spectroscopy, size exclusion chromatography and conductivity measurements. Due to the electron-donating effects of the alkoxysulfonated groups, the two aniline-derivatives were easily incorporated in the macromolecular chains and strongly enhanced water-solubility of the products. The electrical conductivities of these copolymers, which depend on both self- and external-dopings, were reduced by the incorporation of alkoxysulfonated substituents compared with the one of parent polyaniline.
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| NO : | PASCAL 99-0319930 INIST |
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| ET : | Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines |
| AU : | PREVOST (V.); PETIT (A.); PLA (F.) |
| AF : | Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811/France (1 aut., 3 aut.); Laboratoire de Chimie-Physique Macromoléculaire, CNRS UMR 7568 ENSIC-INPL. 1, rue Grandville, BP 451/54001 Nancy/France (2 aut.) |
| DT : | Publication en série; Niveau analytique |
| SO : | Synthetic metals; ISSN 0379-6779; Coden SYMEDZ; Suisse; Da. 1999; Vol. 104; No. 2; Pp. 79-87; Bibl. 53 ref. |
| LA : | Anglais |
| EA : | The chemical oxidative copolymerization of aniline (An) with o-alkoxysulfonated anilines, i.e., 1-(o-amino)-propane-3-sulfonic acid (APPrS) and 1-(o-amino)-butane-3-sulfonic acid (APBuS), was a new way to produce water-soluble and self-doped polyaniline derivatives. Poly(An-co-APPrS) and poly(An-co-APBuS) were obtained in H2SO4 acidic medium by chemical oxidation, using ammonium persulfate, of a comonomer mixture containing An and APPrS, or APBuS, in various initial ratios. The copolymers thus obtained with high or low yields, were characterized by elemental microanalysis, FTIR spectroscopy, size exclusion chromatography and conductivity measurements. Due to the electron-donating effects of the alkoxysulfonated groups, the two aniline-derivatives were easily incorporated in the macromolecular chains and strongly enhanced water-solubility of the products. The electrical conductivities of these copolymers, which depend on both self- and external-dopings, were reduced by the incorporation of alkoxysulfonated substituents compared with the one of parent polyaniline. |
| CC : | 001D09D02E |
| FD : | Aniline copolymère; Sulfonate copolymère; Polymère dopé; Polyélectrolyte; Polymère conducteur; Préparation; Polymérisation oxydante; Conductivité électrique; Etude expérimentale; Autodopage; Aniline(2-[3-sulfopropoxy]) copolymère; Aniline(2-[4-sulfobutoxy]) copolymère |
| FG : | Propriété électrique |
| ED : | Aniline copolymer; Sulfonate copolymer; Doped polymer; Polyelectrolyte; Conducting polymers; Preparation; Oxidative polymerization; Electrical conductivity; Experimental study |
| EG : | Electrical properties |
| SD : | Anilina copolímero; Sulfonato copolímero; Polímero dopado; Polielectrolito; Preparación; Polimerizacion oxidante; Conductividad eléctrica; Estudio experimental |
| LO : | INIST-18315.354000084686300020 |
| ID : | 99-0319930 |
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Pascal:99-0319930Le document en format XML
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Pla</name><affiliation><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">99-0319930</idno><date when="1999">1999</date><idno type="stanalyst">PASCAL 99-0319930 INIST</idno><idno type="RBID">Pascal:99-0319930</idno><idno type="wicri:Area/PascalFrancis/Corpus">000B62</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines</title><author><name sortKey="Prevost, V" sort="Prevost, V" uniqKey="Prevost V" first="V." last="Prevost">V. Prevost</name><affiliation><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14></affiliation></author><author><name sortKey="Petit, A" sort="Petit, A" uniqKey="Petit A" first="A." last="Petit">A. Petit</name><affiliation><inist:fA14 i1="02"><s1>Laboratoire de Chimie-Physique Macromoléculaire, CNRS UMR 7568 ENSIC-INPL. 1, rue Grandville, BP 451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ></inist:fA14></affiliation></author><author><name sortKey="Pla, F" sort="Pla, F" uniqKey="Pla F" first="F." last="Pla">F. Pla</name><affiliation><inist:fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14></affiliation></author></analytic><series><title level="j" type="main">Synthetic metals</title><title level="j" type="abbreviated">Synth. met.</title><idno type="ISSN">0379-6779</idno><imprint><date when="1999">1999</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Synthetic metals</title><title level="j" type="abbreviated">Synth. met.</title><idno type="ISSN">0379-6779</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aniline copolymer</term><term>Conducting polymers</term><term>Doped polymer</term><term>Electrical conductivity</term><term>Experimental study</term><term>Oxidative polymerization</term><term>Polyelectrolyte</term><term>Preparation</term><term>Sulfonate copolymer</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Aniline copolymère</term><term>Sulfonate copolymère</term><term>Polymère dopé</term><term>Polyélectrolyte</term><term>Polymère conducteur</term><term>Préparation</term><term>Polymérisation oxydante</term><term>Conductivité électrique</term><term>Etude expérimentale</term><term>Autodopage</term><term>Aniline(2-[3-sulfopropoxy]) copolymère</term><term>Aniline(2-[4-sulfobutoxy]) copolymère</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The chemical oxidative copolymerization of aniline (An) with o-alkoxysulfonated anilines, i.e., 1-(o-amino)-propane-3-sulfonic acid (APPrS) and 1-(o-amino)-butane-3-sulfonic acid (APBuS), was a new way to produce water-soluble and self-doped polyaniline derivatives. Poly(An-co-APPrS) and poly(An-co-APBuS) were obtained in H<sub>2</sub>SO<sub>4</sub> acidic medium by chemical oxidation, using ammonium persulfate, of a comonomer mixture containing An and APPrS, or APBuS, in various initial ratios. The copolymers thus obtained with high or low yields, were characterized by elemental microanalysis, FTIR spectroscopy, size exclusion chromatography and conductivity measurements. Due to the electron-donating effects of the alkoxysulfonated groups, the two aniline-derivatives were easily incorporated in the macromolecular chains and strongly enhanced water-solubility of the products. The electrical conductivities of these copolymers, which depend on both self- and external-dopings, were reduced by the incorporation of alkoxysulfonated substituents compared with the one of parent polyaniline.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0379-6779</s0></fA01><fA02 i1="01"><s0>SYMEDZ</s0></fA02><fA03 i2="1"><s0>Synth. met.</s0></fA03><fA05><s2>104</s2></fA05><fA06><s2>2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines</s1></fA08><fA11 i1="01" i2="1"><s1>PREVOST (V.)</s1></fA11><fA11 i1="02" i2="1"><s1>PETIT (A.)</s1></fA11><fA11 i1="03" i2="1"><s1>PLA (F.)</s1></fA11><fA14 i1="01"><s1>Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811</s1><s3>FRA</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire de Chimie-Physique Macromoléculaire, CNRS UMR 7568 ENSIC-INPL. 1, rue Grandville, BP 451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ></fA14><fA20><s1>79-87</s1></fA20><fA21><s1>1999</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>18315</s2><s5>354000084686300020</s5></fA43><fA44><s0>0000</s0><s1>© 1999 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>53 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>99-0319930</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Synthetic metals</s0></fA64><fA66 i1="01"><s0>CHE</s0></fA66><fC01 i1="01" l="ENG"><s0>The chemical oxidative copolymerization of aniline (An) with o-alkoxysulfonated anilines, i.e., 1-(o-amino)-propane-3-sulfonic acid (APPrS) and 1-(o-amino)-butane-3-sulfonic acid (APBuS), was a new way to produce water-soluble and self-doped polyaniline derivatives. Poly(An-co-APPrS) and poly(An-co-APBuS) were obtained in H<sub>2</sub>SO<sub>4</sub> acidic medium by chemical oxidation, using ammonium persulfate, of a comonomer mixture containing An and APPrS, or APBuS, in various initial ratios. The copolymers thus obtained with high or low yields, were characterized by elemental microanalysis, FTIR spectroscopy, size exclusion chromatography and conductivity measurements. Due to the electron-donating effects of the alkoxysulfonated groups, the two aniline-derivatives were easily incorporated in the macromolecular chains and strongly enhanced water-solubility of the products. The electrical conductivities of these copolymers, which depend on both self- and external-dopings, were reduced by the incorporation of alkoxysulfonated substituents compared with the one of parent polyaniline.</s0></fC01><fC02 i1="01" i2="X"><s0>001D09D02E</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Aniline copolymère</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Aniline copolymer</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Anilina copolímero</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Sulfonate copolymère</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Sulfonate copolymer</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Sulfonato copolímero</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Polymère dopé</s0><s5>04</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Doped polymer</s0><s5>04</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Polímero dopado</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Polyélectrolyte</s0><s5>05</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Polyelectrolyte</s0><s5>05</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Polielectrolito</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Polymère conducteur</s0><s5>06</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Conducting polymers</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Préparation</s0><s5>08</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Preparation</s0><s5>08</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Preparación</s0><s5>08</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Polymérisation oxydante</s0><s5>09</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Oxidative polymerization</s0><s5>09</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Polimerizacion oxidante</s0><s5>09</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Conductivité électrique</s0><s5>12</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Electrical conductivity</s0><s5>12</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Conductividad eléctrica</s0><s5>12</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>15</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Experimental study</s0><s5>15</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>15</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Autodopage</s0><s4>INC</s4><s5>32</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Aniline(2-[3-sulfopropoxy]) copolymère</s0><s2>NK</s2><s4>INC</s4><s5>33</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Aniline(2-[4-sulfobutoxy]) copolymère</s0><s2>NK</s2><s4>INC</s4><s5>34</s5></fC03><fC07 i1="01" i2="X" l="FRE"><s0>Propriété électrique</s0><s5>11</s5></fC07><fC07 i1="01" i2="X" l="ENG"><s0>Electrical properties</s0><s5>11</s5></fC07><fC07 i1="01" i2="X" l="SPA"><s0>Propiedad eléctrica</s0><s5>11</s5></fC07><fN21><s1>200</s1></fN21></pA></standard><server><NO>PASCAL 99-0319930 INIST</NO><ET>Studies on chemical oxidative copolymerization of aniline and o-alkoxysulfonated anilines : I. Synthesis and characterization of novel self-doped polyanilines</ET><AU>PREVOST (V.); PETIT (A.); PLA (F.)</AU><AF>Laboratoire des Sciences du Génie Chimique, CNRS UPR 6811/France (1 aut., 3 aut.); Laboratoire de Chimie-Physique Macromoléculaire, CNRS UMR 7568 ENSIC-INPL. 1, rue Grandville, BP 451/54001 Nancy/France (2 aut.)</AF><DT>Publication en série; Niveau analytique</DT><SO>Synthetic metals; ISSN 0379-6779; Coden SYMEDZ; Suisse; Da. 1999; Vol. 104; No. 2; Pp. 79-87; Bibl. 53 ref.</SO><LA>Anglais</LA><EA>The chemical oxidative copolymerization of aniline (An) with o-alkoxysulfonated anilines, i.e., 1-(o-amino)-propane-3-sulfonic acid (APPrS) and 1-(o-amino)-butane-3-sulfonic acid (APBuS), was a new way to produce water-soluble and self-doped polyaniline derivatives. Poly(An-co-APPrS) and poly(An-co-APBuS) were obtained in H<sub>2</sub>SO<sub>4</sub> acidic medium by chemical oxidation, using ammonium persulfate, of a comonomer mixture containing An and APPrS, or APBuS, in various initial ratios. The copolymers thus obtained with high or low yields, were characterized by elemental microanalysis, FTIR spectroscopy, size exclusion chromatography and conductivity measurements. Due to the electron-donating effects of the alkoxysulfonated groups, the two aniline-derivatives were easily incorporated in the macromolecular chains and strongly enhanced water-solubility of the products. The electrical conductivities of these copolymers, which depend on both self- and external-dopings, were reduced by the incorporation of alkoxysulfonated substituents compared with the one of parent polyaniline.</EA><CC>001D09D02E</CC><FD>Aniline copolymère; Sulfonate copolymère; Polymère dopé; Polyélectrolyte; Polymère conducteur; Préparation; Polymérisation oxydante; Conductivité électrique; Etude expérimentale; Autodopage; Aniline(2-[3-sulfopropoxy]) copolymère; Aniline(2-[4-sulfobutoxy]) copolymère</FD><FG>Propriété électrique</FG><ED>Aniline copolymer; Sulfonate copolymer; Doped polymer; Polyelectrolyte; Conducting polymers; Preparation; Oxidative polymerization; Electrical conductivity; Experimental study</ED><EG>Electrical properties</EG><SD>Anilina copolímero; Sulfonato copolímero; Polímero dopado; Polielectrolito; Preparación; Polimerizacion oxidante; Conductividad eléctrica; Estudio experimental</SD><LO>INIST-18315.354000084686300020</LO><ID>99-0319930</ID></server></inist></record>Pour manipuler ce document sous Unix (Dilib)
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