Analytical resolution of a cyclic two-way chromatographic binary system
Identifieur interne : 000891 ( PascalFrancis/Corpus ); précédent : 000890; suivant : 000892Analytical resolution of a cyclic two-way chromatographic binary system
Auteurs : C. Castel ; M. Sardin ; M. O. SimnnnotSource :
- AIChE journal [ 0001-1541 ] ; 2002.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.
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NO : | PASCAL 02-0221531 INIST |
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ET : | Analytical resolution of a cyclic two-way chromatographic binary system |
AU : | CASTEL (C.); SARDIN (M.); SIMNNNOT (M. O.) |
AF : | LSGC-CNRS-INPL/54001 Nancy/France (1 aut., 2 aut.); LSGC and EEIGM/54000 Nancy/France (3 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | AIChE journal; ISSN 0001-1541; Coden AICEAC; Etats-Unis; Da. 2002; Vol. 48; No. 2; Pp. 245-251; Bibl. 18 ref. |
LA : | Anglais |
EA : | The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution. |
CC : | 001D17 |
FD : | Etude théorique; Simulation numérique; Elution; Mélange binaire; Chlorure; Hydrogénocarbonate; Anion minéral; Equilibre local; Distribution concentration; Bilan masse; Chromatographie échange ion; Résine échangeuse anion; Méthode cyclique |
ED : | Theoretical study; Numerical simulation; Elution; Binary mixture; Chlorides; Hydrogencarbonates; Inorganic anion; Local equilibrium; Concentration distribution; Mass balance; Ion exchange chromatography; Anionic resin; Cyclic method |
SD : | Estudio teórico; Simulación numérica; Elución; Mezcla binaria; Cloruro; Hidrógenocarbonato; Anión inorgánico; Equilibrio local; Distribución concentración; Cromatografía cambio iónico; Resina de cambio aniónico; Método cíclico |
LO : | INIST-7678.354000100234310070 |
ID : | 02-0221531 |
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Pascal:02-0221531Le document en format XML
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<front><div type="abstract" xml:lang="en">The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</div>
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<ET>Analytical resolution of a cyclic two-way chromatographic binary system</ET>
<AU>CASTEL (C.); SARDIN (M.); SIMNNNOT (M. O.)</AU>
<AF>LSGC-CNRS-INPL/54001 Nancy/France (1 aut., 2 aut.); LSGC and EEIGM/54000 Nancy/France (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>AIChE journal; ISSN 0001-1541; Coden AICEAC; Etats-Unis; Da. 2002; Vol. 48; No. 2; Pp. 245-251; Bibl. 18 ref.</SO>
<LA>Anglais</LA>
<EA>The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</EA>
<CC>001D17</CC>
<FD>Etude théorique; Simulation numérique; Elution; Mélange binaire; Chlorure; Hydrogénocarbonate; Anion minéral; Equilibre local; Distribution concentration; Bilan masse; Chromatographie échange ion; Résine échangeuse anion; Méthode cyclique</FD>
<ED>Theoretical study; Numerical simulation; Elution; Binary mixture; Chlorides; Hydrogencarbonates; Inorganic anion; Local equilibrium; Concentration distribution; Mass balance; Ion exchange chromatography; Anionic resin; Cyclic method</ED>
<SD>Estudio teórico; Simulación numérica; Elución; Mezcla binaria; Cloruro; Hidrógenocarbonato; Anión inorgánico; Equilibrio local; Distribución concentración; Cromatografía cambio iónico; Resina de cambio aniónico; Método cíclico</SD>
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