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Analytical resolution of a cyclic two-way chromatographic binary system

Identifieur interne : 000891 ( PascalFrancis/Corpus ); précédent : 000890; suivant : 000892

Analytical resolution of a cyclic two-way chromatographic binary system

Auteurs : C. Castel ; M. Sardin ; M. O. Simnnnot

Source :

RBID : Pascal:02-0221531

Descripteurs français

English descriptors

Abstract

The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0001-1541
A02 01      @0 AICEAC
A03   1    @0 AIChE j.
A05       @2 48
A06       @2 2
A08 01  1  ENG  @1 Analytical resolution of a cyclic two-way chromatographic binary system
A11 01  1    @1 CASTEL (C.)
A11 02  1    @1 SARDIN (M.)
A11 03  1    @1 SIMNNNOT (M. O.)
A14 01      @1 LSGC-CNRS-INPL @2 54001 Nancy @3 FRA @Z 1 aut. @Z 2 aut.
A14 02      @1 LSGC and EEIGM @2 54000 Nancy @3 FRA @Z 3 aut.
A20       @1 245-251
A21       @1 2002
A23 01      @0 ENG
A43 01      @1 INIST @2 7678 @5 354000100234310070
A44       @0 0000 @1 © 2002 INIST-CNRS. All rights reserved.
A45       @0 18 ref.
A47 01  1    @0 02-0221531
A60       @1 P
A61       @0 A
A64 01  1    @0 AIChE journal
A66 01      @0 USA
C01 01    ENG  @0 The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.
C02 01  X    @0 001D17
C03 01  X  FRE  @0 Etude théorique @5 01
C03 01  X  ENG  @0 Theoretical study @5 01
C03 01  X  SPA  @0 Estudio teórico @5 01
C03 02  X  FRE  @0 Simulation numérique @5 02
C03 02  X  ENG  @0 Numerical simulation @5 02
C03 02  X  SPA  @0 Simulación numérica @5 02
C03 03  X  FRE  @0 Elution @5 03
C03 03  X  ENG  @0 Elution @5 03
C03 03  X  SPA  @0 Elución @5 03
C03 04  X  FRE  @0 Mélange binaire @5 04
C03 04  X  ENG  @0 Binary mixture @5 04
C03 04  X  SPA  @0 Mezcla binaria @5 04
C03 05  X  FRE  @0 Chlorure @2 NA @5 05
C03 05  X  ENG  @0 Chlorides @2 NA @5 05
C03 05  X  SPA  @0 Cloruro @2 NA @5 05
C03 06  X  FRE  @0 Hydrogénocarbonate @2 NA @5 06
C03 06  X  ENG  @0 Hydrogencarbonates @2 NA @5 06
C03 06  X  SPA  @0 Hidrógenocarbonato @2 NA @5 06
C03 07  X  FRE  @0 Anion minéral @5 07
C03 07  X  ENG  @0 Inorganic anion @5 07
C03 07  X  SPA  @0 Anión inorgánico @5 07
C03 08  X  FRE  @0 Equilibre local @5 09
C03 08  X  ENG  @0 Local equilibrium @5 09
C03 08  X  SPA  @0 Equilibrio local @5 09
C03 09  X  FRE  @0 Distribution concentration @5 10
C03 09  X  ENG  @0 Concentration distribution @5 10
C03 09  X  SPA  @0 Distribución concentración @5 10
C03 10  3  FRE  @0 Bilan masse @5 12
C03 10  3  ENG  @0 Mass balance @5 12
C03 11  X  FRE  @0 Chromatographie échange ion @5 17
C03 11  X  ENG  @0 Ion exchange chromatography @5 17
C03 11  X  SPA  @0 Cromatografía cambio iónico @5 17
C03 12  X  FRE  @0 Résine échangeuse anion @5 18
C03 12  X  ENG  @0 Anionic resin @5 18
C03 12  X  SPA  @0 Resina de cambio aniónico @5 18
C03 13  X  FRE  @0 Méthode cyclique @5 20
C03 13  X  ENG  @0 Cyclic method @5 20
C03 13  X  SPA  @0 Método cíclico @5 20
N21       @1 126
N82       @1 PSI

Format Inist (serveur)

NO : PASCAL 02-0221531 INIST
ET : Analytical resolution of a cyclic two-way chromatographic binary system
AU : CASTEL (C.); SARDIN (M.); SIMNNNOT (M. O.)
AF : LSGC-CNRS-INPL/54001 Nancy/France (1 aut., 2 aut.); LSGC and EEIGM/54000 Nancy/France (3 aut.)
DT : Publication en série; Niveau analytique
SO : AIChE journal; ISSN 0001-1541; Coden AICEAC; Etats-Unis; Da. 2002; Vol. 48; No. 2; Pp. 245-251; Bibl. 18 ref.
LA : Anglais
EA : The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.
CC : 001D17
FD : Etude théorique; Simulation numérique; Elution; Mélange binaire; Chlorure; Hydrogénocarbonate; Anion minéral; Equilibre local; Distribution concentration; Bilan masse; Chromatographie échange ion; Résine échangeuse anion; Méthode cyclique
ED : Theoretical study; Numerical simulation; Elution; Binary mixture; Chlorides; Hydrogencarbonates; Inorganic anion; Local equilibrium; Concentration distribution; Mass balance; Ion exchange chromatography; Anionic resin; Cyclic method
SD : Estudio teórico; Simulación numérica; Elución; Mezcla binaria; Cloruro; Hidrógenocarbonato; Anión inorgánico; Equilibrio local; Distribución concentración; Cromatografía cambio iónico; Resina de cambio aniónico; Método cíclico
LO : INIST-7678.354000100234310070
ID : 02-0221531

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Pascal:02-0221531

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<div type="abstract" xml:lang="en">The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</div>
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<EA>The focus is on analytical resolution of the mass-balance relation in the case of a binary ion-exchange system containing chloride and hydrocarbonate anions involved in a two-way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</EA>
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