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Gelation in carbon nanotube/polymer composites

Identifieur interne : 000795 ( PascalFrancis/Corpus ); précédent : 000794; suivant : 000796

Gelation in carbon nanotube/polymer composites

Auteurs : CHENYANG LIU ; JUN ZHANG ; JIASONG HE ; GUOHUA HU

Source :

RBID : Pascal:03-0507562

Descripteurs français

English descriptors

Abstract

The physical gelation in carbon nanotubes (CNTs)/polycarbonate composites was revealed by rheological analysis (Winter-Chambon method), based on the data reported by Paul [Polymer 43 (2002) 3247]. The gelation concentration cg, the relaxation exponent n and the gel strength Sg characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa sn, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0032-3861
A02 01      @0 POLMAG
A03   1    @0 Polymer : (Guildf.)
A05       @2 44
A06       @2 24
A08 01  1  ENG  @1 Gelation in carbon nanotube/polymer composites
A11 01  1    @1 CHENYANG LIU
A11 02  1    @1 JUN ZHANG
A11 03  1    @1 JIASONG HE
A11 04  1    @1 GUOHUA HU
A14 01      @1 State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Zhongguancun @2 Beijing 100080 @3 CHN @Z 1 aut. @Z 2 aut. @Z 3 aut.
A14 02      @1 Laboratory of Chemical Engineering Sciences, CNRS-ENSIC-INPL @2 54001 Nancy @3 FRA @Z 4 aut.
A20       @1 7529-7532
A21       @1 2003
A23 01      @0 ENG
A43 01      @1 INIST @2 11463 @5 354000114761660300
A44       @0 0000 @1 © 2003 INIST-CNRS. All rights reserved.
A45       @0 18 ref.
A47 01  1    @0 03-0507562
A60       @1 P
A61       @0 A
A64 01  1    @0 Polymer : (Guildford)
A66 01      @0 GBR
C01 01    ENG  @0 The physical gelation in carbon nanotubes (CNTs)/polycarbonate composites was revealed by rheological analysis (Winter-Chambon method), based on the data reported by Paul [Polymer 43 (2002) 3247]. The gelation concentration cg, the relaxation exponent n and the gel strength Sg characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa sn, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.
C02 01  X    @0 001D10A06H
C03 01  X  FRE  @0 Nanocomposite @5 01
C03 01  X  ENG  @0 Nanocomposite @5 01
C03 01  X  SPA  @0 Nanocompuesto @5 01
C03 02  X  FRE  @0 Carbonate polymère @2 NK @5 02
C03 02  X  ENG  @0 Polycarbonate @2 NK @5 02
C03 02  X  SPA  @0 Carbonato polímero @2 NK @5 02
C03 03  1  FRE  @0 Nanotube carbone @1 SEC @5 04
C03 03  1  ENG  @0 Carbon nanotubes @1 SEC @5 04
C03 04  X  FRE  @0 Etat fondu @5 07
C03 04  X  ENG  @0 Molten state @5 07
C03 04  X  SPA  @0 Estado fundido @5 07
C03 05  X  FRE  @0 Propriété rhéologique @5 09
C03 05  X  ENG  @0 Rheological properties @5 09
C03 05  X  SPA  @0 Propiedad rheológica @5 09
C03 06  X  FRE  @0 Gélification @5 11
C03 06  X  ENG  @0 Gelation @5 11
C03 06  X  SPA  @0 Gelificación @5 11
C03 07  X  FRE  @0 Gel physique @5 12
C03 07  X  ENG  @0 Physical gel @5 12
C03 07  X  SPA  @0 Gel físico @5 12
C03 08  X  FRE  @0 Effet concentration @5 14
C03 08  X  ENG  @0 Concentration effect @5 14
C03 08  X  SPA  @0 Efecto concentración @5 14
C03 09  X  FRE  @0 Etude expérimentale @5 15
C03 09  X  ENG  @0 Experimental study @5 15
C03 09  X  SPA  @0 Estudio experimental @5 15
N21       @1 335
N82       @1 PSI

Format Inist (serveur)

NO : PASCAL 03-0507562 INIST
ET : Gelation in carbon nanotube/polymer composites
AU : CHENYANG LIU; JUN ZHANG; JIASONG HE; GUOHUA HU
AF : State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Zhongguancun/Beijing 100080/Chine (1 aut., 2 aut., 3 aut.); Laboratory of Chemical Engineering Sciences, CNRS-ENSIC-INPL/54001 Nancy/France (4 aut.)
DT : Publication en série; Niveau analytique
SO : Polymer : (Guildford); ISSN 0032-3861; Coden POLMAG; Royaume-Uni; Da. 2003; Vol. 44; No. 24; Pp. 7529-7532; Bibl. 18 ref.
LA : Anglais
EA : The physical gelation in carbon nanotubes (CNTs)/polycarbonate composites was revealed by rheological analysis (Winter-Chambon method), based on the data reported by Paul [Polymer 43 (2002) 3247]. The gelation concentration cg, the relaxation exponent n and the gel strength Sg characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa sn, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.
CC : 001D10A06H
FD : Nanocomposite; Carbonate polymère; Nanotube carbone; Etat fondu; Propriété rhéologique; Gélification; Gel physique; Effet concentration; Etude expérimentale
ED : Nanocomposite; Polycarbonate; Carbon nanotubes; Molten state; Rheological properties; Gelation; Physical gel; Concentration effect; Experimental study
SD : Nanocompuesto; Carbonato polímero; Estado fundido; Propiedad rheológica; Gelificación; Gel físico; Efecto concentración; Estudio experimental
LO : INIST-11463.354000114761660300
ID : 03-0507562

Links to Exploration step

Pascal:03-0507562

Le document en format XML

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<div type="abstract" xml:lang="en">The physical gelation in carbon nanotubes (CNTs)/polycarbonate composites was revealed by rheological analysis (Winter-Chambon method), based on the data reported by Paul [Polymer 43 (2002) 3247]. The gelation concentration c
<sub>g</sub>
, the relaxation exponent n and the gel strength S
<sub>g</sub>
characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa s
<sup>n</sup>
, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.</div>
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<sub>g</sub>
, the relaxation exponent n and the gel strength S
<sub>g</sub>
characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa s
<sup>n</sup>
, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.</s0>
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<sub>g</sub>
, the relaxation exponent n and the gel strength S
<sub>g</sub>
characterizing the critical gel point for the composites are 1.6 wt%, 0.75 and 770 Pa s
<sup>n</sup>
, respectively, which are comparable with those found for polymer gels. In fact, the gel points coincide with the percolation threshold of the electrical conductivity and the high strength in CNT/polymer composite applications. The new kind of physical gel originates from a combination of entanglement of CNTs and interactions between CNTs and polymer chains, instead of the chemical bonding or physical interactions in previous polymer gels.</EA>
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   |clé=     Pascal:03-0507562
   |texte=   Gelation in carbon nanotube/polymer composites
}}

Wicri

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