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Optimal temperature-time programming in a batch copolymerization reactor

Identifieur interne : 000671 ( PascalFrancis/Corpus ); précédent : 000670; suivant : 000672

Optimal temperature-time programming in a batch copolymerization reactor

Auteurs : D. Salhi ; M. Daroux ; C. Gentric ; J. P. Corriou ; F. Pla ; M. A. Latifi

Source :

RBID : Pascal:05-0125858

Descripteurs français

English descriptors

Abstract

This paper addresses the optimization of a batch copolymerization reactor of styrene and α-methylstyrene. The reactor is equipped with a jacket for heat exchange and, thus, for temperature control. The performance index is the batch period, and the decision variable is the jacket inlet temperature. The constraints involved include the process model, the polymer quality, the final monomer conversion rate, the heating/cooling rate of the reactor and upper and lower bounds of the variables. The optimization method is a direct method with a sequential strategy known as control vector parametrization method. The optimal profiles are determined with great care in terms of treatment and fulfilment of constraints. The results show a substantial improvement with respect to the complete discretization method previously used.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
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A02 01      @0 IECRED
A03   1    @0 Ind. eng. chem. res.
A05       @2 43
A06       @2 23
A08 01  1  ENG  @1 Optimal temperature-time programming in a batch copolymerization reactor
A09 01  1  ENG  @1 Polymer reaction engineering: modeling, optimization and control
A11 01  1    @1 SALHI (D.)
A11 02  1    @1 DAROUX (M.)
A11 03  1    @1 GENTRIC (C.)
A11 04  1    @1 CORRIOU (J. P.)
A11 05  1    @1 PLA (F.)
A11 06  1    @1 LATIFI (M. A.)
A12 01  1    @1 SHEIBAT-OTHMAN (Nida) @9 préf.
A12 02  1    @1 MCKENNA (Timothy F.) @9 préf.
A14 01      @1 Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, B.P. 451, 1 rue Grandville @2 54001 Nancy @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut. @Z 6 aut.
A15 01      @1 LAGEP, Université Claude Bernard Lyon I, CNRS @2 69616 Villeurbanne @3 FRA @Z 1 aut.
A15 02      @1 LCPP-CNRS / ESCPE-Lyon @2 69616 Villeurbanne @3 FRA @Z 2 aut.
A20       @1 7392-7400
A21       @1 2004
A23 01      @0 ENG
A43 01      @1 INIST @2 120F @5 354000122584230190
A44       @0 0000 @1 © 2005 INIST-CNRS. All rights reserved.
A45       @0 31 ref.
A47 01  1    @0 05-0125858
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Industrial & engineering chemistry research
A66 01      @0 USA
C01 01    ENG  @0 This paper addresses the optimization of a batch copolymerization reactor of styrene and α-methylstyrene. The reactor is equipped with a jacket for heat exchange and, thus, for temperature control. The performance index is the batch period, and the decision variable is the jacket inlet temperature. The constraints involved include the process model, the polymer quality, the final monomer conversion rate, the heating/cooling rate of the reactor and upper and lower bounds of the variables. The optimization method is a direct method with a sequential strategy known as control vector parametrization method. The optimal profiles are determined with great care in terms of treatment and fulfilment of constraints. The results show a substantial improvement with respect to the complete discretization method previously used.
C02 01  X    @0 001D07H
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C03 01  X  FRE  @0 En discontinu @5 01
C03 01  X  ENG  @0 Batchwise @5 01
C03 01  X  SPA  @0 En discontinuo @5 01
C03 02  X  FRE  @0 Copolymérisation @5 02
C03 02  X  ENG  @0 Copolymerization @5 02
C03 02  X  SPA  @0 Copolimerización @5 02
C03 03  X  FRE  @0 Réacteur @5 03
C03 03  X  ENG  @0 Reactor @5 03
C03 03  X  SPA  @0 Reactor @5 03
N21       @1 087
N44 01      @1 OTO
N82       @1 OTO
pR  
A30 01  1  ENG  @1 Polymer Reaction Engineering: Modeling, Optimization and Control. Meeting @3 Lyons FRA @4 2003-12-01

Format Inist (serveur)

NO : PASCAL 05-0125858 INIST
ET : Optimal temperature-time programming in a batch copolymerization reactor
AU : SALHI (D.); DAROUX (M.); GENTRIC (C.); CORRIOU (J. P.); PLA (F.); LATIFI (M. A.); SHEIBAT-OTHMAN (Nida); MCKENNA (Timothy F.)
AF : Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC, B.P. 451, 1 rue Grandville/54001 Nancy/France (1 aut., 2 aut., 3 aut., 4 aut., 5 aut., 6 aut.); LAGEP, Université Claude Bernard Lyon I, CNRS/69616 Villeurbanne/France (1 aut.); LCPP-CNRS / ESCPE-Lyon/69616 Villeurbanne/France (2 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Industrial & engineering chemistry research; ISSN 0888-5885; Coden IECRED; Etats-Unis; Da. 2004; Vol. 43; No. 23; Pp. 7392-7400; Bibl. 31 ref.
LA : Anglais
EA : This paper addresses the optimization of a batch copolymerization reactor of styrene and α-methylstyrene. The reactor is equipped with a jacket for heat exchange and, thus, for temperature control. The performance index is the batch period, and the decision variable is the jacket inlet temperature. The constraints involved include the process model, the polymer quality, the final monomer conversion rate, the heating/cooling rate of the reactor and upper and lower bounds of the variables. The optimization method is a direct method with a sequential strategy known as control vector parametrization method. The optimal profiles are determined with great care in terms of treatment and fulfilment of constraints. The results show a substantial improvement with respect to the complete discretization method previously used.
CC : 001D07H; 001D09D02C
FD : En discontinu; Copolymérisation; Réacteur
ED : Batchwise; Copolymerization; Reactor
SD : En discontinuo; Copolimerización; Reactor
LO : INIST-120F.354000122584230190
ID : 05-0125858

Links to Exploration step

Pascal:05-0125858

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<SO>Industrial & engineering chemistry research; ISSN 0888-5885; Coden IECRED; Etats-Unis; Da. 2004; Vol. 43; No. 23; Pp. 7392-7400; Bibl. 31 ref.</SO>
<LA>Anglais</LA>
<EA>This paper addresses the optimization of a batch copolymerization reactor of styrene and α-methylstyrene. The reactor is equipped with a jacket for heat exchange and, thus, for temperature control. The performance index is the batch period, and the decision variable is the jacket inlet temperature. The constraints involved include the process model, the polymer quality, the final monomer conversion rate, the heating/cooling rate of the reactor and upper and lower bounds of the variables. The optimization method is a direct method with a sequential strategy known as control vector parametrization method. The optimal profiles are determined with great care in terms of treatment and fulfilment of constraints. The results show a substantial improvement with respect to the complete discretization method previously used.</EA>
<CC>001D07H; 001D09D02C</CC>
<FD>En discontinu; Copolymérisation; Réacteur</FD>
<ED>Batchwise; Copolymerization; Reactor</ED>
<SD>En discontinuo; Copolimerización; Reactor</SD>
<LO>INIST-120F.354000122584230190</LO>
<ID>05-0125858</ID>
</server>
</inist>
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