LrgpV1, PascalFrancis, Corpus, bibRecord, 000634

Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate

Identifieur interne : 000634 ( PascalFrancis/Corpus ); précédent : 000633; suivant : 000635

Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate

Auteurs : Sandrine Hoppe ; Cornélius Schrauwen ; Christian Fonteix ; Fernand Pla

Source :

Macromolecular materials and engineering : (Print) [ 1438-7492 ] ; 2005.

RBID : Pascal:05-0267658

Descripteurs français

Pascal (Inist)
- Styrène copolymère, Styrène(alpha-méthyl) copolymère, Méthacrylate de méthyle copolymère, Terpolymère, Terpolymérisation radicalaire, Copolymérisation émulsion, Agent surface anionique, Sulfate(lauryl), Inhibiteur réaction, Distribution masse moléculaire, Nombre particule, Dimension particule, Modélisation, Modèle cinétique, Etude expérimentale.

English descriptors

KwdEn :
- Anionic surfactant, Emulsion copolymerization, Experimental study, Kinetic model, Lauryl sulfate, Methyl methacrylate copolymer, Modeling, Molecular weight distribution, Particle number, Particle size, Radical terpolymerization, Reaction inhibitor, Styrene copolymer, Styrene(alpha-methyl) copolymer, Terpolymer.

Abstract

This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

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A03		`1`		`@0 Macromol. mater. eng. : (Print)`
A05				`@2 290`
A06				`@2 4`
A08	`01`	`1`	`ENG`	`@1 Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate`
A11	`01`	`1`		`@1 HOPPE (Sandrine)`
A11	`02`	`1`		`@1 SCHRAUWEN (Cornélius)`
A11	`03`	`1`		`@1 FONTEIX (Christian)`
A11	`04`	`1`		`@1 PLA (Fernand)`
A14	`01`			`@1 Laboratoire des Sciences du Génie Chimique, UPR 6811 CNRS, ENSIC-INPL, 1, Rue Grandville, BP451 @2 54001 Nancy @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.`
A20				`@1 384-403`
A21				`@1 2005`
A23	`01`			`@0 ENG`
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A44				`@0 0000 @1 © 2005 INIST-CNRS. All rights reserved.`
A45				`@0 34 ref.`
A47	`01`	`1`		`@0 05-0267658`
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A64	`01`	`1`		`@0 Macromolecular materials and engineering : (Print)`
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C01	`01`		`ENG`	@0 This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.
C02	`01`	`X`		`@0 001D09D02C`
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C03	`01`	`X`	`ENG`	`@0 Styrene copolymer @2 NK @5 01`
C03	`01`	`X`	`SPA`	`@0 Estireno copolímero @2 NK @5 01`
C03	`02`	`X`	`FRE`	`@0 Styrène(alpha-méthyl) copolymère @2 NK @5 02`
C03	`02`	`X`	`ENG`	`@0 Styrene(alpha-methyl) copolymer @2 NK @5 02`
C03	`02`	`X`	`SPA`	`@0 Estireno(alfa-metil) copolímero @2 NK @5 02`
C03	`03`	`X`	`FRE`	`@0 Méthacrylate de méthyle copolymère @2 NK @5 03`
C03	`03`	`X`	`ENG`	`@0 Methyl methacrylate copolymer @2 NK @5 03`
C03	`03`	`X`	`SPA`	`@0 Metacrilato de metilo copolímero @2 NK @5 03`
C03	`04`	`X`	`FRE`	`@0 Terpolymère @5 04`
C03	`04`	`X`	`ENG`	`@0 Terpolymer @5 04`
C03	`04`	`X`	`SPA`	`@0 Terpolímero @5 04`
C03	`05`	`X`	`FRE`	`@0 Terpolymérisation radicalaire @5 05`
C03	`05`	`X`	`ENG`	`@0 Radical terpolymerization @5 05`
C03	`05`	`X`	`SPA`	`@0 Terpolimerización radicalaria @5 05`
C03	`06`	`X`	`FRE`	`@0 Copolymérisation émulsion @5 06`
C03	`06`	`X`	`ENG`	`@0 Emulsion copolymerization @5 06`
C03	`06`	`X`	`SPA`	`@0 Copolimerización emulsión @5 06`
C03	`07`	`X`	`FRE`	`@0 Agent surface anionique @5 07`
C03	`07`	`X`	`ENG`	`@0 Anionic surfactant @5 07`
C03	`07`	`X`	`SPA`	`@0 Agente superficie aniónico @5 07`
C03	`08`	`X`	`FRE`	`@0 Sulfate(lauryl) @1 ACT @2 NK @5 08`
C03	`08`	`X`	`ENG`	`@0 Lauryl sulfate @1 ACT @2 NK @5 08`
C03	`08`	`X`	`SPA`	`@0 Lauril sulfato @1 ACT @2 NK @5 08`
C03	`09`	`X`	`FRE`	`@0 Inhibiteur réaction @5 09`
C03	`09`	`X`	`ENG`	`@0 Reaction inhibitor @5 09`
C03	`09`	`X`	`SPA`	`@0 Inhibidor reacción @5 09`
C03	`10`	`X`	`FRE`	`@0 Distribution masse moléculaire @5 10`
C03	`10`	`X`	`ENG`	`@0 Molecular weight distribution @5 10`
C03	`10`	`X`	`SPA`	`@0 Distribución masa molecular @5 10`
C03	`11`	`X`	`FRE`	`@0 Nombre particule @5 11`
C03	`11`	`X`	`ENG`	`@0 Particle number @5 11`
C03	`11`	`X`	`SPA`	`@0 Número partícula @5 11`
C03	`12`	`X`	`FRE`	`@0 Dimension particule @5 12`
C03	`12`	`X`	`ENG`	`@0 Particle size @5 12`
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C03	`13`	`X`	`ENG`	`@0 Modeling @5 13`
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C03	`15`	`X`	`ENG`	`@0 Experimental study @5 15`
C03	`15`	`X`	`SPA`	`@0 Estudio experimental @5 15`
N21				`@1 185`

Format Inist (serveur)

NO :	PASCAL 05-0267658 INIST
ET :	Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate
AU :	HOPPE (Sandrine); SCHRAUWEN (Cornélius); FONTEIX (Christian); PLA (Fernand)
AF :	Laboratoire des Sciences du Génie Chimique, UPR 6811 CNRS, ENSIC-INPL, 1, Rue Grandville, BP451/54001 Nancy/France (1 aut., 2 aut., 3 aut., 4 aut.)
DT :	Publication en série; Niveau analytique
SO :	Macromolecular materials and engineering : (Print); ISSN 1438-7492; Allemagne; Da. 2005; Vol. 290; No. 4; Pp. 384-403; Bibl. 34 ref.
LA :	Anglais
EA :	This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.
CC :	001D09D02C
FD :	Styrène copolymère; Styrène(alpha-méthyl) copolymère; Méthacrylate de méthyle copolymère; Terpolymère; Terpolymérisation radicalaire; Copolymérisation émulsion; Agent surface anionique; Sulfate(lauryl); Inhibiteur réaction; Distribution masse moléculaire; Nombre particule; Dimension particule; Modélisation; Modèle cinétique; Etude expérimentale
ED :	Styrene copolymer; Styrene(alpha-methyl) copolymer; Methyl methacrylate copolymer; Terpolymer; Radical terpolymerization; Emulsion copolymerization; Anionic surfactant; Lauryl sulfate; Reaction inhibitor; Molecular weight distribution; Particle number; Particle size; Modeling; Kinetic model; Experimental study
SD :	Estireno copolímero; Estireno(alfa-metil) copolímero; Metacrilato de metilo copolímero; Terpolímero; Terpolimerización radicalaria; Copolimerización emulsión; Agente superficie aniónico; Lauril sulfato; Inhibidor reacción; Distribución masa molecular; Número partícula; Dimensión partícula; Modelización; Modelo cinético; Estudio experimental
LO :	INIST-13869.354000125505970160
ID :	05-0267658

Links to Exploration step

Pascal:05-0267658

Le document en format XML

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<term>Particle size</term>
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<front><div type="abstract" xml:lang="en">This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.</div>
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<fC01 i1="01" l="ENG"><s0>This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.</s0>
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Terpolymer</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Terpolímero</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Terpolymérisation radicalaire</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Radical terpolymerization</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Terpolimerización radicalaria</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Copolymérisation émulsion</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Emulsion copolymerization</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Copolimerización emulsión</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Agent surface anionique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Anionic surfactant</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Agente superficie aniónico</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Sulfate(lauryl)</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Lauryl sulfate</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Lauril sulfato</s0>
<s1>ACT</s1>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Inhibiteur réaction</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Reaction inhibitor</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Inhibidor reacción</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Distribution masse moléculaire</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Molecular weight distribution</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Distribución masa molecular</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Nombre particule</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Particle number</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Número partícula</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Dimension particule</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Particle size</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Dimensión partícula</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Modélisation</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Modeling</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Modelización</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Modèle cinétique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Kinetic model</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Modelo cinético</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>15</s5>
</fC03>
<fN21><s1>185</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 05-0267658 INIST</NO>
<ET>Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate</ET>
<AU>HOPPE (Sandrine); SCHRAUWEN (Cornélius); FONTEIX (Christian); PLA (Fernand)</AU>
<AF>Laboratoire des Sciences du Génie Chimique, UPR 6811 CNRS, ENSIC-INPL, 1, Rue Grandville, BP451/54001 Nancy/France (1 aut., 2 aut., 3 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Macromolecular materials and engineering : (Print); ISSN 1438-7492; Allemagne; Da. 2005; Vol. 290; No. 4; Pp. 384-403; Bibl. 34 ref.</SO>
<LA>Anglais</LA>
<EA>This work deals with modeling the terpolymerization of styrene, α-methylstyrene and methyl methacrylate in the presence of an inhibitor. The model used is a "tendency model" based on the kinetics of the complex elementary chemical reactions both in the aqueous phase and in the particles. It considers the reversible propagation of α-methylstyrene and the main physical phenomena occurring during the process, i.e., (i) partitioning of monomers, surfactant and inhibitor between the aqueous phase, polymer particles, monomer droplets and micelles; (ii) homogeneous and micellar nucleation; (iii) radical absorption and desorption; (iv) gel and glass effects. The main kinetic parameters of the model are estimated on the basis of batch experimental data in order to be able to describe the complete picture of this complex process. The model can be used to predict (with good precision) the global monomer conversion, number and weight-average molecular weight, the average diameter and number of polymer particles and the glass transition temperature, and consequently to study the effects of AMS on conversion and terpolymer and latex characteristics.</EA>
<CC>001D09D02C</CC>
<FD>Styrène copolymère; Styrène(alpha-méthyl) copolymère; Méthacrylate de méthyle copolymère; Terpolymère; Terpolymérisation radicalaire; Copolymérisation émulsion; Agent surface anionique; Sulfate(lauryl); Inhibiteur réaction; Distribution masse moléculaire; Nombre particule; Dimension particule; Modélisation; Modèle cinétique; Etude expérimentale</FD>
<ED>Styrene copolymer; Styrene(alpha-methyl) copolymer; Methyl methacrylate copolymer; Terpolymer; Radical terpolymerization; Emulsion copolymerization; Anionic surfactant; Lauryl sulfate; Reaction inhibitor; Molecular weight distribution; Particle number; Particle size; Modeling; Kinetic model; Experimental study</ED>
<SD>Estireno copolímero; Estireno(alfa-metil) copolímero; Metacrilato de metilo copolímero; Terpolímero; Terpolimerización radicalaria; Copolimerización emulsión; Agente superficie aniónico; Lauril sulfato; Inhibidor reacción; Distribución masa molecular; Número partícula; Dimensión partícula; Modelización; Modelo cinético; Estudio experimental</SD>
<LO>INIST-13869.354000125505970160</LO>
<ID>05-0267658</ID>
</server>
</inist>
</record>

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Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate

Modeling of the emulsion terpolymerization of styrene, α-methylstyrene and methyl methacrylate

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