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Rapid Production of Biodiesel in Mesoscale Oscillatory Baffled Reactors

Identifieur interne : 000118 ( PascalFrancis/Corpus ); précédent : 000117; suivant : 000119

Rapid Production of Biodiesel in Mesoscale Oscillatory Baffled Reactors

Auteurs : Anh N. Phan ; Adam P. Harvey ; Valentine Eze

Source :

RBID : Pascal:12-0330309

Descripteurs français

English descriptors

Abstract

Continuous alkali-catalyzed transesterification of rapeseed oil with methanol was carried out in three mesoreactor designs. The induction time decreased with oscillatory Reynolds number for all three reactors. Stable steady states were achieved within induction times of 1.5, 2.5, and 4.0 residence times for the integral, wire wool, and helical baffle designs, respectively. Both experimental and simulated results indicated that under the given conditions there is an optimal residence time for homogeneous transesterification. Higher residence times resulted in reduced fatty acid methyl ester content due to the saponification side reaction. The results demonstrate that biodiesel can be produced at an industrially acceptable level of conversion (> 95 %) in < 5 min residence time. This requires a combination of high catalyst concentration and good mixing.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0930-7516
A02 01      @0 CETEER
A03   1    @0 Chem. eng. technol.
A05       @2 35
A06       @2 7
A08 01  1  ENG  @1 Rapid Production of Biodiesel in Mesoscale Oscillatory Baffled Reactors
A09 01  1  ENG  @1 Reactor Design & Process Intensification
A11 01  1    @1 PHAN (Anh N.)
A11 02  1    @1 HARVEY (Adam P.)
A11 03  1    @1 EZE (Valentine)
A12 01  1    @1 CHARPENTIER (Jean-Claude) @9 ed.
A14 01      @1 School of Chemical Engineering & Advanced Materials @2 Newcastle Upon Tyne @3 GBR @Z 1 aut. @Z 2 aut. @Z 3 aut.
A15 01      @1 Laboratoire Réactions et Génie des Procédés, CNRS/ENSIC Université de Lorraine @2 Nancy @3 FRA @Z 1 aut.
A20       @1 1214-1220
A21       @1 2012
A23 01      @0 ENG
A43 01      @1 INIST @2 20728 @5 354000500864540080
A44       @0 0000 @1 © 2012 INIST-CNRS. All rights reserved.
A45       @0 16 ref.
A47 01  1    @0 12-0330309
A60       @1 P
A61       @0 A
A64 01  1    @0 Chemical engineering & technology
A66 01      @0 DEU
C01 01    ENG  @0 Continuous alkali-catalyzed transesterification of rapeseed oil with methanol was carried out in three mesoreactor designs. The induction time decreased with oscillatory Reynolds number for all three reactors. Stable steady states were achieved within induction times of 1.5, 2.5, and 4.0 residence times for the integral, wire wool, and helical baffle designs, respectively. Both experimental and simulated results indicated that under the given conditions there is an optimal residence time for homogeneous transesterification. Higher residence times resulted in reduced fatty acid methyl ester content due to the saponification side reaction. The results demonstrate that biodiesel can be produced at an industrially acceptable level of conversion (> 95 %) in < 5 min residence time. This requires a combination of high catalyst concentration and good mixing.
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C03 01  X  ENG  @0 Production @5 01
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C03 02  X  ENG  @0 Reactor @5 02
C03 02  X  SPA  @0 Reactor @5 02
C03 03  X  FRE  @0 Réaction catalytique @5 03
C03 03  X  ENG  @0 Catalytic reaction @5 03
C03 03  X  SPA  @0 Reacción catalítica @5 03
C03 04  X  FRE  @0 Transestérification @5 04
C03 04  X  ENG  @0 Transesterification @5 04
C03 04  X  SPA  @0 Transesterificación @5 04
C03 05  X  FRE  @0 Conception @5 05
C03 05  X  ENG  @0 Design @5 05
C03 05  X  SPA  @0 Diseño @5 05
C03 06  X  FRE  @0 Induction @5 06
C03 06  X  ENG  @0 Induction @5 06
C03 06  X  SPA  @0 Inducción @5 06
C03 07  X  FRE  @0 Nombre Reynolds @5 07
C03 07  X  ENG  @0 Reynolds number @5 07
C03 07  X  SPA  @0 Número Reynolds @5 07
C03 08  X  FRE  @0 Régime permanent @5 08
C03 08  X  ENG  @0 Steady state @5 08
C03 08  X  SPA  @0 Régimen permanente @5 08
C03 09  X  FRE  @0 Fil métallique @5 09
C03 09  X  ENG  @0 Wire @5 09
C03 09  X  SPA  @0 Hilo metálico @5 09
C03 10  X  FRE  @0 Chicane @5 10
C03 10  X  ENG  @0 Baffle @5 10
C03 10  X  SPA  @0 Tabique @5 10
C03 11  X  FRE  @0 Saponification @5 11
C03 11  X  ENG  @0 Saponification @5 11
C03 11  X  SPA  @0 Saponificación @5 11
C03 12  X  FRE  @0 Catalyseur @5 12
C03 12  X  ENG  @0 Catalyst @5 12
C03 12  X  SPA  @0 Catalizador @5 12
C03 13  X  FRE  @0 Mélangeage @5 13
C03 13  X  ENG  @0 Mixing @5 13
C03 13  X  SPA  @0 Mezclado @5 13
N21       @1 254
N44 01      @1 OTO
N82       @1 OTO

Format Inist (serveur)

NO : PASCAL 12-0330309 INIST
ET : Rapid Production of Biodiesel in Mesoscale Oscillatory Baffled Reactors
AU : PHAN (Anh N.); HARVEY (Adam P.); EZE (Valentine); CHARPENTIER (Jean-Claude)
AF : School of Chemical Engineering & Advanced Materials/Newcastle Upon Tyne/Royaume-Uni (1 aut., 2 aut., 3 aut.); Laboratoire Réactions et Génie des Procédés, CNRS/ENSIC Université de Lorraine/Nancy/France (1 aut.)
DT : Publication en série; Niveau analytique
SO : Chemical engineering & technology; ISSN 0930-7516; Coden CETEER; Allemagne; Da. 2012; Vol. 35; No. 7; Pp. 1214-1220; Bibl. 16 ref.
LA : Anglais
EA : Continuous alkali-catalyzed transesterification of rapeseed oil with methanol was carried out in three mesoreactor designs. The induction time decreased with oscillatory Reynolds number for all three reactors. Stable steady states were achieved within induction times of 1.5, 2.5, and 4.0 residence times for the integral, wire wool, and helical baffle designs, respectively. Both experimental and simulated results indicated that under the given conditions there is an optimal residence time for homogeneous transesterification. Higher residence times resulted in reduced fatty acid methyl ester content due to the saponification side reaction. The results demonstrate that biodiesel can be produced at an industrially acceptable level of conversion (> 95 %) in < 5 min residence time. This requires a combination of high catalyst concentration and good mixing.
CC : 001D07H; 001C01A03B
FD : Production; Réacteur; Réaction catalytique; Transestérification; Conception; Induction; Nombre Reynolds; Régime permanent; Fil métallique; Chicane; Saponification; Catalyseur; Mélangeage
ED : Production; Reactor; Catalytic reaction; Transesterification; Design; Induction; Reynolds number; Steady state; Wire; Baffle; Saponification; Catalyst; Mixing
SD : Producción; Reactor; Reacción catalítica; Transesterificación; Diseño; Inducción; Número Reynolds; Régimen permanente; Hilo metálico; Tabique; Saponificación; Catalizador; Mezclado
LO : INIST-20728.354000500864540080
ID : 12-0330309

Links to Exploration step

Pascal:12-0330309

Le document en format XML

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<ET>Rapid Production of Biodiesel in Mesoscale Oscillatory Baffled Reactors</ET>
<AU>PHAN (Anh N.); HARVEY (Adam P.); EZE (Valentine); CHARPENTIER (Jean-Claude)</AU>
<AF>School of Chemical Engineering & Advanced Materials/Newcastle Upon Tyne/Royaume-Uni (1 aut., 2 aut., 3 aut.); Laboratoire Réactions et Génie des Procédés, CNRS/ENSIC Université de Lorraine/Nancy/France (1 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Chemical engineering & technology; ISSN 0930-7516; Coden CETEER; Allemagne; Da. 2012; Vol. 35; No. 7; Pp. 1214-1220; Bibl. 16 ref.</SO>
<LA>Anglais</LA>
<EA>Continuous alkali-catalyzed transesterification of rapeseed oil with methanol was carried out in three mesoreactor designs. The induction time decreased with oscillatory Reynolds number for all three reactors. Stable steady states were achieved within induction times of 1.5, 2.5, and 4.0 residence times for the integral, wire wool, and helical baffle designs, respectively. Both experimental and simulated results indicated that under the given conditions there is an optimal residence time for homogeneous transesterification. Higher residence times resulted in reduced fatty acid methyl ester content due to the saponification side reaction. The results demonstrate that biodiesel can be produced at an industrially acceptable level of conversion (> 95 %) in < 5 min residence time. This requires a combination of high catalyst concentration and good mixing.</EA>
<CC>001D07H; 001C01A03B</CC>
<FD>Production; Réacteur; Réaction catalytique; Transestérification; Conception; Induction; Nombre Reynolds; Régime permanent; Fil métallique; Chicane; Saponification; Catalyseur; Mélangeage</FD>
<ED>Production; Reactor; Catalytic reaction; Transesterification; Design; Induction; Reynolds number; Steady state; Wire; Baffle; Saponification; Catalyst; Mixing</ED>
<SD>Producción; Reactor; Reacción catalítica; Transesterificación; Diseño; Inducción; Número Reynolds; Régimen permanente; Hilo metálico; Tabique; Saponificación; Catalizador; Mezclado</SD>
<LO>INIST-20728.354000500864540080</LO>
<ID>12-0330309</ID>
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