LrgpV1, Ncbi, Merge, bibRecord, 000027

Chirality transfer during alkylation of chiral amides.

Identifieur interne : 000027 ( Ncbi/Merge ); précédent : 000026; suivant : 000028

Chirality transfer during alkylation of chiral amides.

Auteurs : Takeo Kawabata [Japon] ; Orhan Oztürk ; Jianyong Chen ; Kaoru Fuji

Source :

Chemical communications (Cambridge, England) [ 1359-7345 ] ; 2003.

RBID : pubmed:12611016

Abstract

Chiral amides derived from O-methyl mandelic acid and achiral amines underwent enantioselective alpha-methylation on treatment with LTMP followed by addition of methyl iodide; chirality transfer from an undeprotonated chiral amide into an achiral enolate in a mixed aggregate is supposed to be responsible for the asymmetric induction.

PubMed: 12611016

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pubmed:12611016

Le document en format XML

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<front><div type="abstract" xml:lang="en">Chiral amides derived from O-methyl mandelic acid and achiral amines underwent enantioselective alpha-methylation on treatment with LTMP followed by addition of methyl iodide; chirality transfer from an undeprotonated chiral amide into an achiral enolate in a mixed aggregate is supposed to be responsible for the asymmetric induction.</div>
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<Abstract><AbstractText>Chiral amides derived from O-methyl mandelic acid and achiral amines underwent enantioselective alpha-methylation on treatment with LTMP followed by addition of methyl iodide; chirality transfer from an undeprotonated chiral amide into an achiral enolate in a mixed aggregate is supposed to be responsible for the asymmetric induction.</AbstractText>
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Chirality transfer during alkylation of chiral amides.

Chirality transfer during alkylation of chiral amides.

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki