LrgpV1, Ncbi, Checkpoint, bibRecord, 000241

Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes

Identifieur interne : 000241 ( Ncbi/Checkpoint ); précédent : 000240; suivant : 000242

Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes

Auteurs : Chiheb Bahrini [France] ; Olivier Herbinet [France] ; Pierre-Alexandre Glaude [France] ; Coralie Schoemaecker [France] ; Christa Fittschen [France] ; Frédérique Battin-Leclerc [France]

Source :

Journal of the American Chemical Society [ 0002-7863 ] ; 2012.

RBID : PMC:3586669

Abstract

The first reliable quantification of hydrogen peroxide (H₂O₂) formed during the low temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was n-butane, the smallest alkane which has an oxidation behaviour close to that of the species present in gasoline and diesel fuels.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3586669

DOI: 10.1021/ja305200h
PubMed: 22746212
PubMed Central: 3586669

Affiliations:

Links to Exploration step

PMC:3586669

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p id="P1">The first reliable quantification of hydrogen peroxide (H<sub>2</sub>
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Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes

Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes

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