LrgpV1, Main, Merge, bibRecord, 001F57

Piv-Proψ[CH2-NH-O]Gly-NH'Pr

Identifieur interne : 001F57 ( Main/Merge ); précédent : 001F56; suivant : 001F58

Piv-Proψ[CH2-NH-O]Gly-NH'Pr

Auteurs : C. Corbier [France] ; C. Didierjean [France] ; L. Thevenet [France] ; R. Vanderesse [France] ; Michel Marraud (chimiste) [France]

Source :

Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 2000.

RBID : Pascal:00-0452853

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Structure moléculaire, Peptide, Dipeptide, Pseudopeptide, Hydroxylamine organique, Conformation, Liaison hydrogène intramoléculaire, 6166H, Acétamide(N-isopropyl-[(1-pivaloylpyrrolidin-2-ylméthyl)aminooxy]).

English descriptors

KwdEn :
- Conformation, Crystal structure, Dipeptides, Experimental study, Intramolecular hydrogen bond, Molecular structure, Organic hydroxylamine, Peptides, Pseudopeptide, XRD.

Abstract

The pseudodipeptide, (S)-N-isopropyl {[N-(pivaloyl)pyrrolidin-2-yl]methylaminooxy]acetamide, C₁₅H₂₉N₃O₃, adopts a global extended conformation with the hydroxylamine group in the g⁺/g^- structure. The C-terminal amide NH interacts intramolecularly with the hydroxylamine O atom. Both NH bonds of each molecule are hydrogen bonded to the C-terminal amide carbonyl of a neighbouring molecule.

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to stream PascalFrancis, to step Curation: 000063
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Pascal:00-0452853

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Piv-Proψ[CH<sub>2</sub>
-NH-O]Gly-NH'Pr</title>
<author><name sortKey="Corbier, C" sort="Corbier, C" uniqKey="Corbier C" first="C." last="Corbier">C. Corbier</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallographie et Modélisation des Matériaux Minéraux et Biologiques (LCM<sup>3</sup>
B), UPRESA n° 7036, Groupe Biocristallographie, Université Henri Poincaré, Nancy 1, Faculté des Sciences, BP 239</s1>
<s2>54506 Vandoeuvre lès Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Vandoeuvre lès Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Didierjean, C" sort="Didierjean, C" uniqKey="Didierjean C" first="C." last="Didierjean">C. Didierjean</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallographie et Modélisation des Matériaux Minéraux et Biologiques (LCM<sup>3</sup>
B), UPRESA n° 7036, Groupe Biocristallographie, Université Henri Poincaré, Nancy 1, Faculté des Sciences, BP 239</s1>
<s2>54506 Vandoeuvre lès Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Vandoeuvre lès Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Thevenet, L" sort="Thevenet, L" uniqKey="Thevenet L" first="L." last="Thevenet">L. Thevenet</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
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</author>
<author><name sortKey="Vanderesse, R" sort="Vanderesse, R" uniqKey="Vanderesse R" first="R." last="Vanderesse">R. Vanderesse</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
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<region type="old region" nuts="2">Lorraine (région)</region>
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</placeName>
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</author>
<author><name sortKey="Marraud, M" sort="Marraud, M" uniqKey="Marraud M" first="M." last="Marraud">Michel Marraud (chimiste)</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
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</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<placeName><settlement type="city">Nancy</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="laboratoire" n="5">Laboratoire de chimie physique macromoléculaire</orgName>
<orgName type="university">Université de Lorraine</orgName>
<orgName type="institution">Centre national de la recherche scientifique</orgName>
</affiliation>
</author>
</titleStmt>
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<idno type="inist">00-0452853</idno>
<date when="2000">2000</date>
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<idno type="RBID">Pascal:00-0452853</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Piv-Proψ[CH<sub>2</sub>
-NH-O]Gly-NH'Pr</title>
<author><name sortKey="Corbier, C" sort="Corbier, C" uniqKey="Corbier C" first="C." last="Corbier">C. Corbier</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallographie et Modélisation des Matériaux Minéraux et Biologiques (LCM<sup>3</sup>
B), UPRESA n° 7036, Groupe Biocristallographie, Université Henri Poincaré, Nancy 1, Faculté des Sciences, BP 239</s1>
<s2>54506 Vandoeuvre lès Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Vandoeuvre lès Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Didierjean, C" sort="Didierjean, C" uniqKey="Didierjean C" first="C." last="Didierjean">C. Didierjean</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Cristallographie et Modélisation des Matériaux Minéraux et Biologiques (LCM<sup>3</sup>
B), UPRESA n° 7036, Groupe Biocristallographie, Université Henri Poincaré, Nancy 1, Faculté des Sciences, BP 239</s1>
<s2>54506 Vandoeuvre lès Nancy</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Vandoeuvre lès Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Thevenet, L" sort="Thevenet, L" uniqKey="Thevenet L" first="L." last="Thevenet">L. Thevenet</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Vanderesse, R" sort="Vanderesse, R" uniqKey="Vanderesse R" first="R." last="Vanderesse">R. Vanderesse</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Marraud, M" sort="Marraud, M" uniqKey="Marraud M" first="M." last="Marraud">Michel Marraud (chimiste)</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Physique Macromoléculaire, UMR-CNRS-INPL n° 7568, ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<placeName><settlement type="city">Nancy</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="laboratoire" n="5">Laboratoire de chimie physique macromoléculaire</orgName>
<orgName type="university">Université de Lorraine</orgName>
<orgName type="institution">Centre national de la recherche scientifique</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="2000">2000</date>
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</series>
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<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Conformation</term>
<term>Crystal structure</term>
<term>Dipeptides</term>
<term>Experimental study</term>
<term>Intramolecular hydrogen bond</term>
<term>Molecular structure</term>
<term>Organic hydroxylamine</term>
<term>Peptides</term>
<term>Pseudopeptide</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Structure moléculaire</term>
<term>Peptide</term>
<term>Dipeptide</term>
<term>Pseudopeptide</term>
<term>Hydroxylamine organique</term>
<term>Conformation</term>
<term>Liaison hydrogène intramoléculaire</term>
<term>6166H</term>
<term>Acétamide(N-isopropyl-[(1-pivaloylpyrrolidin-2-ylméthyl)aminooxy])</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The pseudodipeptide, (S)-N-isopropyl {[N-(pivaloyl)pyrrolidin-2-yl]methylaminooxy]acetamide, C<sub>15</sub>
H<sub>29</sub>
N<sub>3</sub>
O<sub>3</sub>
, adopts a global extended conformation with the hydroxylamine group in the g<sup>+</sup>
/g<sup>-</sup>
 structure. The C-terminal amide NH interacts intramolecularly with the hydroxylamine O atom. Both NH bonds of each molecule are hydrogen bonded to the C-terminal amide carbonyl of a neighbouring molecule.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
<region><li>Grand Est</li>
<li>Lorraine (région)</li>
</region>
<settlement><li>Nancy</li>
<li>Vandoeuvre lès Nancy</li>
</settlement>
<orgName><li>Centre national de la recherche scientifique</li>
<li>Laboratoire de chimie physique macromoléculaire</li>
<li>Université de Lorraine</li>
</orgName>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Corbier, C" sort="Corbier, C" uniqKey="Corbier C" first="C." last="Corbier">C. Corbier</name>
</region>
<name sortKey="Didierjean, C" sort="Didierjean, C" uniqKey="Didierjean C" first="C." last="Didierjean">C. Didierjean</name>
<name sortKey="Marraud, M" sort="Marraud, M" uniqKey="Marraud M" first="M." last="Marraud">Michel Marraud (chimiste)</name>
<name sortKey="Thevenet, L" sort="Thevenet, L" uniqKey="Thevenet L" first="L." last="Thevenet">L. Thevenet</name>
<name sortKey="Vanderesse, R" sort="Vanderesse, R" uniqKey="Vanderesse R" first="R." last="Vanderesse">R. Vanderesse</name>
</country>
</tree>
</affiliations>
</record>

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Piv-Proψ[CH2-NH-O]Gly-NH'Pr

Piv-Proψ[CH2-NH-O]Gly-NH'Pr

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri