Description of multicomponent adsorption and absorption phenomena from a single viewpoint
Identifieur interne : 001965 ( Main/Merge ); précédent : 001964; suivant : 001966Description of multicomponent adsorption and absorption phenomena from a single viewpoint
Auteurs : A. Tvardovski [Russie] ; Daniel Tondeur [France] ; Éric Favre (génie des procédés) [France]Source :
- Journal of colloid and interface science [ 0021-9797 ] ; 2003.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Thermodynamique.
English descriptors
- KwdEn :
Abstract
On the basis of phenomenological thermodynamics, an equation has been derived that represents one of the interphase equilibrium equations and provides a description of both multicomponent adsorption and absorption phenomena from a single point of view. The approach is based on a free-volume state equation for the adsorbed phase. It is shown that the well-known Henry, Langmuir, Fowler-Guggenheim, Temkin, and BET adsorption equations (generalized for gas mixtures) follow directly from the equation proposed with constants having a clear physical meaning.
Links toward previous steps (curation, corpus...)
- to stream PascalFrancis, to step Corpus: 000798
- to stream PascalFrancis, to step Curation: 000313
- to stream PascalFrancis, to step Checkpoint: 000732
Links to Exploration step
Pascal:03-0454263Le document en format XML
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<front><div type="abstract" xml:lang="en">On the basis of phenomenological thermodynamics, an equation has been derived that represents one of the interphase equilibrium equations and provides a description of both multicomponent adsorption and absorption phenomena from a single point of view. The approach is based on a free-volume state equation for the adsorbed phase. It is shown that the well-known Henry, Langmuir, Fowler-Guggenheim, Temkin, and BET adsorption equations (generalized for gas mixtures) follow directly from the equation proposed with constants having a clear physical meaning.</div>
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