LrgpV1, Main, Merge, bibRecord, 000F44

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Identifieur interne : 000F44 ( Main/Merge ); précédent : 000F43; suivant : 000F45

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Auteurs : Sarah Bax [France] ; Mohammed Hichem Hakka [France] ; Pierre-Alexandre Glaude [France] ; Olivier Herbinet [France] ; Frédérique Battin-Leclerc [France]

Source :

Combustion and flame [ 0010-2180 ] ; 2010.

RBID : PMC:3662212

Descripteurs français

Wicri :
- topic : Moteur.

English descriptors

mix :
- Biodiesel, Combustion, Engine, Jet stirred reactor, Kinetics, Methyl esters, Methyl oleate, Methyl palmitate, Oxidation.

Abstract

The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10⁻³ and 5.2 × 10⁻⁴) and under stoichiometric conditions.

The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO₂ radicals to the double bond.

Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.

Url:

DOI: 10.1016/j.combustflame.2009.12.008
PubMed: 23710077
PubMed Central: 3662212

Links to Exploration step

PMC:3662212

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p id="P1">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10<sup>−3</sup>
 and 5.2 × 10<sup>−4</sup>
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<p id="P2">The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO<sub>2</sub>
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<p id="P3">Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</p>
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<idno type="DOI">10.1016/j.combustflame.2009.12.008</idno>
<series><title level="j">Combustion and Flame</title>
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<profileDesc><textClass><keywords scheme="mix" xml:lang="en"><term>Biodiesel</term>
<term>Combustion</term>
<term>Engine</term>
<term>Jet stirred reactor</term>
<term>Kinetics</term>
<term>Methyl esters</term>
<term>Methyl oleate</term>
<term>Methyl palmitate</term>
<term>Oxidation</term>
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<front><div type="abstract" xml:lang="en">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550-1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10−3 and 5.2 × 10−4) and under stoichiometric conditions. The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO2 radicals to the double bond. Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</div>
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<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
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<author><name sortKey="Herbinet, Olivier" sort="Herbinet, Olivier" uniqKey="Herbinet O" first="Olivier" last="Herbinet">Olivier Herbinet</name>
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<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Experimental study of the oxidation of methyl oleate in a jet-stirred reactor</title>
<author><name sortKey="Bax, Sarah" sort="Bax, Sarah" uniqKey="Bax S" first="Sarah" last="Bax">Sarah Bax</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<orgName type="university">Nancy-Université</orgName>
</affiliation>
</author>
<author><name sortKey="Hakka, Mohammed Hichem" sort="Hakka, Mohammed Hichem" uniqKey="Hakka M" first="Mohammed Hichem" last="Hakka">Mohammed Hichem Hakka</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<orgName type="university">Nancy-Université</orgName>
</affiliation>
</author>
<author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<orgName type="university">Nancy-Université</orgName>
</affiliation>
</author>
<author><name sortKey="Herbinet, Olivier" sort="Herbinet, Olivier" uniqKey="Herbinet O" first="Olivier" last="Herbinet">Olivier Herbinet</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<orgName type="university">Nancy-Université</orgName>
</affiliation>
</author>
<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<affiliation wicri:level="4"><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
<settlement type="city">Nancy</settlement>
</placeName>
<orgName type="university">Nancy-Université</orgName>
<placeName><settlement type="city">Nancy</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName>
<orgName type="university">Université de Lorraine</orgName>
<orgName type="institution">Centre national de la recherche scientifique</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j">Combustion and flame</title>
<idno type="ISSN">0010-2180</idno>
<idno type="eISSN">1556-2921</idno>
<imprint><date when="2010">2010</date>
</imprint>
</series>
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<front><div type="abstract" xml:lang="en"><p id="P1">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10<sup>−3</sup>
 and 5.2 × 10<sup>−4</sup>
) and under stoichiometric conditions.</p>
<p id="P2">The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO<sub>2</sub>
 radicals to the double bond.</p>
<p id="P3">Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</p>
</div>
</front>
</TEI>
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Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

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