LrgpV1, Main, Merge, bibRecord, 000C25

Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

Identifieur interne : 000C25 ( Main/Merge ); précédent : 000C24; suivant : 000C26

Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

Auteurs : Jean-Charles Moise [France] ; Fabrice Mutelet [France] ; Jean-Noël Jaubert [France] ; Laura Grubbs [États-Unis] ; William E. Jr. Acree [États-Unis] ; Gary Baker [États-Unis]

Source :

Journal of Chemical and Engineering Data [ 0021-9568 ] ; 2011.

RBID : Hal:hal-00776975

English descriptors

mix :
- CARBON-DIOXIDE, EQUATION COEFFICIENTS, FREE-ENERGY RELATIONSHIP, INVERSE GAS-CHROMATOGRAPHY, MIXTURES, SOLUBILITY, SOLUTES, SOLVATION, THERMODYNAMIC PROPERTIES, WATER.

Abstract

Activity coefficients of 42 to 54 organic compounds in the four ionic liquids (ILs) 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate, 1-butyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 1,3-didecyl-2-methylimidazolium bis(trifluoromethylsulfonyl)imide, and 1-ethyl-3-methylimidazolium methanesulfonate were measured using inverse gas chromatography from (312 to 353) K. The retention data were also converted to gas-to-IL and water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the modified Abraham solvation parameter model. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within average standard deviations of 0.113 and 0.143 log units, respectively.

Url:

https://hal.archives-ouvertes.fr/hal-00776975

DOI: 10.1021/je200195q

Links toward previous steps (curation, corpus...)

to stream Hal, to step Corpus: 000070
to stream Hal, to step Curation: 000070
to stream Hal, to step Checkpoint: 000A44

Links to Exploration step

Hal:hal-00776975

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids</title>
<author><name sortKey="Moise, Jean Charles" sort="Moise, Jean Charles" uniqKey="Moise J" first="Jean-Charles" last="Moise">Jean-Charles Moise</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Mutelet, Fabrice" sort="Mutelet, Fabrice" uniqKey="Mutelet F" first="Fabrice" last="Mutelet">Fabrice Mutelet</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Jaubert, Jean Noel" sort="Jaubert, Jean Noel" uniqKey="Jaubert J" first="Jean-Noël" last="Jaubert">Jean-Noël Jaubert</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Grubbs, Laura" sort="Grubbs, Laura" uniqKey="Grubbs L" first="Laura" last="Grubbs">Laura Grubbs</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211833" status="INCOMING"><orgName>Department of Chemistry, Univ N Texas</orgName>
<desc><address><addrLine>Univ N Texas, Dept Chem, Denton, TX 76203</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-300834" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300834" type="direct"><org type="institution" xml:id="struct-300834" status="VALID"><orgName>University of North Texas</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
<author><name sortKey="Acree, William E Jr" sort="Acree, William E Jr" uniqKey="Acree W" first="William E. Jr." last="Acree">William E. Jr. Acree</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211834" status="INCOMING"><orgName>Department of Chemistry, Univ N. Texas</orgName>
<desc><address><addrLine>Univ N Texas, Dept Chem, Denton, TX 76203</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-300834" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300834" type="direct"><org type="institution" xml:id="struct-300834" status="VALID"><orgName>University of North Texas</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
<author><name sortKey="Baker, Gary" sort="Baker, Gary" uniqKey="Baker G" first="Gary" last="Baker">Gary Baker</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211835" status="INCOMING"><orgName>Department of Chemistry, University of Missouri</orgName>
<desc><address><addrLine>Univ Missouri, Dept Chem, Columbia, MO 65211</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-364580" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-364580" type="direct"><org type="institution" xml:id="struct-364580" status="INCOMING"><orgName>UNIVERSITY OF MISSOURI</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">HAL</idno>
<idno type="RBID">Hal:hal-00776975</idno>
<idno type="halId">hal-00776975</idno>
<idno type="halUri">https://hal.archives-ouvertes.fr/hal-00776975</idno>
<idno type="url">https://hal.archives-ouvertes.fr/hal-00776975</idno>
<idno type="doi">10.1021/je200195q</idno>
<date when="2011">2011</date>
<idno type="wicri:Area/Hal/Corpus">000070</idno>
<idno type="wicri:Area/Hal/Curation">000070</idno>
<idno type="wicri:Area/Hal/Checkpoint">000A44</idno>
<idno type="wicri:explorRef" wicri:stream="Hal" wicri:step="Checkpoint">000A44</idno>
<idno type="wicri:doubleKey">0021-9568:2011:Moise J:activity:coefficients:at</idno>
<idno type="wicri:Area/Main/Merge">000C25</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids</title>
<author><name sortKey="Moise, Jean Charles" sort="Moise, Jean Charles" uniqKey="Moise J" first="Jean-Charles" last="Moise">Jean-Charles Moise</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Mutelet, Fabrice" sort="Mutelet, Fabrice" uniqKey="Mutelet F" first="Fabrice" last="Mutelet">Fabrice Mutelet</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Jaubert, Jean Noel" sort="Jaubert, Jean Noel" uniqKey="Jaubert J" first="Jean-Noël" last="Jaubert">Jean-Noël Jaubert</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Grubbs, Laura" sort="Grubbs, Laura" uniqKey="Grubbs L" first="Laura" last="Grubbs">Laura Grubbs</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211833" status="INCOMING"><orgName>Department of Chemistry, Univ N Texas</orgName>
<desc><address><addrLine>Univ N Texas, Dept Chem, Denton, TX 76203</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-300834" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300834" type="direct"><org type="institution" xml:id="struct-300834" status="VALID"><orgName>University of North Texas</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
<author><name sortKey="Acree, William E Jr" sort="Acree, William E Jr" uniqKey="Acree W" first="William E. Jr." last="Acree">William E. Jr. Acree</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211834" status="INCOMING"><orgName>Department of Chemistry, Univ N. Texas</orgName>
<desc><address><addrLine>Univ N Texas, Dept Chem, Denton, TX 76203</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-300834" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300834" type="direct"><org type="institution" xml:id="struct-300834" status="VALID"><orgName>University of North Texas</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
<author><name sortKey="Baker, Gary" sort="Baker, Gary" uniqKey="Baker G" first="Gary" last="Baker">Gary Baker</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211835" status="INCOMING"><orgName>Department of Chemistry, University of Missouri</orgName>
<desc><address><addrLine>Univ Missouri, Dept Chem, Columbia, MO 65211</addrLine>
<country key="US"></country>
</address>
</desc>
<listRelation><relation active="#struct-364580" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-364580" type="direct"><org type="institution" xml:id="struct-364580" status="INCOMING"><orgName>UNIVERSITY OF MISSOURI</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
</analytic>
<idno type="DOI">10.1021/je200195q</idno>
<series><title level="j">Journal of Chemical and Engineering Data</title>
<idno type="ISSN">0021-9568</idno>
<imprint><date type="datePub">2011</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass><keywords scheme="mix" xml:lang="en"><term>CARBON-DIOXIDE</term>
<term>EQUATION COEFFICIENTS</term>
<term>FREE-ENERGY RELATIONSHIP</term>
<term>INVERSE GAS-CHROMATOGRAPHY</term>
<term>MIXTURES</term>
<term>SOLUBILITY</term>
<term>SOLUTES</term>
<term>SOLVATION</term>
<term>THERMODYNAMIC PROPERTIES</term>
<term>WATER</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Activity coefficients of 42 to 54 organic compounds in the four ionic liquids (ILs) 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate, 1-butyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 1,3-didecyl-2-methylimidazolium bis(trifluoromethylsulfonyl)imide, and 1-ethyl-3-methylimidazolium methanesulfonate were measured using inverse gas chromatography from (312 to 353) K. The retention data were also converted to gas-to-IL and water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the modified Abraham solvation parameter model. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within average standard deviations of 0.113 and 0.143 log units, respectively.</div>
</front>
</TEI>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Main/Merge

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000C25 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Merge/biblio.hfd -nk 000C25 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Lorraine
   |area=    LrgpV1
   |flux=    Main
   |étape=   Merge
   |type=    RBID
   |clé=     Hal:hal-00776975
   |texte=   Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids
}}

This area was generated with Dilib version V0.6.32.
Data generation: Sat Nov 11 15:47:48 2017. Site generation: Wed Mar 6 23:31:34 2024

	Serveur d'exploration sur le LRGP
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le LRGP

Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri