LrgpV1, Main, Merge, bibRecord, 000565

Thermal reactions between alkanes and H2S or thiols at high pressure

Identifieur interne : 000565 ( Main/Merge ); précédent : 000564; suivant : 000566

Thermal reactions between alkanes and H2S or thiols at high pressure

Auteurs : V. P. Nguyen ; V. Burklé-Vitzthum [France] ; Paul-Marie Marquaire [France] ; Raymond Michels [France]

Source :

Journal of Analytical and Applied Pyrolysis [ 0165-2370 ] ; 2013-09.

RBID : Hal:hal-01282099

Abstract

Confined pyrolysis in gold cells of n-octane/H2S mixtures was carried out between 310 degrees C and 350 degrees C under 700 bar for durations of 3-13 days. The main products were thiophene, alkylthiophenes, octanethiols and alkyl-thiacycloalkanes and their quantities were measured. Some experiments were also carried out at 350 degrees C on n-octane/thiol mixtures and the results were compared to those obtained with H2S. The formation pathways of the main products, which are similar for both reactant mixtures, are proposed.

Url:

https://hal.univ-lorraine.fr/hal-01282099

DOI: 10.1016/j.jaap.2012.11.018

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to stream Hal, to step Corpus: 000B58
to stream Hal, to step Curation: 000B58
to stream Hal, to step Checkpoint: 000505

Links to Exploration step

Hal:hal-01282099

Le document en format XML

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<front><div type="abstract" xml:lang="en">Confined pyrolysis in gold cells of n-octane/H2S mixtures was carried out between 310 degrees C and 350 degrees C under 700 bar for durations of 3-13 days. The main products were thiophene, alkylthiophenes, octanethiols and alkyl-thiacycloalkanes and their quantities were measured. Some experiments were also carried out at 350 degrees C on n-octane/thiol mixtures and the results were compared to those obtained with H2S. The formation pathways of the main products, which are similar for both reactant mixtures, are proposed.</div>
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   |texte=   Thermal reactions between alkanes and H2S or thiols at high pressure
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Thermal reactions between alkanes and H2S or thiols at high pressure

Thermal reactions between alkanes and H2S or thiols at high pressure

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Abstract

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