Experimental and modeling study of the oxidation of isobutene
Identifieur interne : 001F40 ( Main/Exploration ); précédent : 001F39; suivant : 001F41Experimental and modeling study of the oxidation of isobutene
Auteurs : J. C. Bauge [France] ; Frédérique Battin-Leclerc [France] ; F. Baronnet [France]Source :
- International Journal of Chemical Kinetics [ 0538-8066 ] ; 1998.
English descriptors
- KwdEn :
- Allene, Baronnet, Baronnet table, Batch bauge, Bauge, Carbon atoms, Carbon dioxide, Carbon monoxide, Ch2co, Ch2o, Chem, Equivalence ratio, Exgas, Exgas exgas exgas, Experimental data, Fuel equivalence ratios, Helium oxygen isobutene, Ignition delays, Isba, Isobutene, Isobutenyl, Isobutenyl radicals, Isobutyl radicals, Isobutyraldehyde, Ispr, Kinetic data, Kingas, Long right batch oxidation, Macr, Metathesis, Partial pressures, Phys, Primary mechanism, Propene, Richest mixtures, Risb, Secondary mechanism, Secondary reactions, Shock tube, Shock wave, Shock waves, Space time, Tted, Unimolecular.
- Teeft :
- Allene, Baronnet, Baronnet table, Batch bauge, Bauge, Carbon atoms, Carbon dioxide, Carbon monoxide, Ch2co, Ch2o, Chem, Equivalence ratio, Exgas, Exgas exgas exgas, Experimental data, Fuel equivalence ratios, Helium oxygen isobutene, Ignition delays, Isba, Isobutene, Isobutenyl, Isobutenyl radicals, Isobutyl radicals, Isobutyraldehyde, Ispr, Kinetic data, Kingas, Long right batch oxidation, Macr, Metathesis, Partial pressures, Phys, Primary mechanism, Propene, Richest mixtures, Risb, Secondary mechanism, Secondary reactions, Shock tube, Shock wave, Shock waves, Space time, Tted, Unimolecular.
Abstract
This article describes an experimental and modeling study of the oxidation of isobutene. The low‐temperature oxidation was studied in a continuous‐flow stirred‐tank reactor operated at constant temperature (from 833 to 913 K) and pressure (1 atm), with fuel equivalence ratios from 3 to 6 and space times ranging from 1 to 10 s corresponding to isobutene conversion yields from 1 to 50%. The main carbon containing products were analyzed by gas chromatography. The ignition delays of isobutene‐oxygen‐argon mixtures with fuel equivalence ratios from 1 to 3 were measured behind shock waves. Reflected shock waves permitted to obtain temperatures from 1230 to 1930 K and pressures from 9.5 to 10.5 atm. A mechanism has been proposed to reproduce the profiles obtained for the reactants consumption and the products formation during the slow oxidation and to compute the ignition delays in the shock tube. Simulations were performed using CHEMKIN II. A correct agreement between the simulated values and the experimental data has been obtained in both apparatuses. The main reaction paths have been determined for both series of measurements by a sensitivity and rate of production analysis. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 629–640, 1998
Url:
DOI: 10.1002/(SICI)1097-4601(1998)30:9<629::AID-KIN4>3.0.CO;2-U
Affiliations:
- France
- Grand Est, Lorraine (région)
- Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000167
- to stream Istex, to step Curation: 000167
- to stream Istex, to step Checkpoint: 000960
- to stream Main, to step Merge: 002341
- to stream Main, to step Curation: 001F40
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Experimental and modeling study of the oxidation of isobutene</title><author><name sortKey="Bauge, J C" sort="Bauge, J C" uniqKey="Bauge J" first="J. C." last="Bauge">J. C. Bauge</name></author><author><name sortKey="Battin Eclerc, F" sort="Battin Eclerc, F" uniqKey="Battin Eclerc F" first="F." last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation><country>France</country><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation></author><author><name sortKey="Baronnet, F" sort="Baronnet, F" uniqKey="Baronnet F" first="F." last="Baronnet">F. Baronnet</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:F6C8E3A5769D12A6FDADB84E8107783AA985FE15</idno><date when="1998" year="1998">1998</date><idno type="doi">10.1002/(SICI)1097-4601(1998)30:9<629::AID-KIN4>3.0.CO;2-U</idno><idno type="url">https://api.istex.fr/document/F6C8E3A5769D12A6FDADB84E8107783AA985FE15/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000167</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000167</idno><idno type="wicri:Area/Istex/Curation">000167</idno><idno type="wicri:Area/Istex/Checkpoint">000960</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000960</idno><idno type="wicri:doubleKey">0538-8066:1998:Bauge J:experimental:and:modeling</idno><idno type="wicri:Area/Main/Merge">002341</idno><idno type="wicri:Area/Main/Curation">001F40</idno><idno type="wicri:Area/Main/Exploration">001F40</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Experimental and modeling study of the oxidation of isobutene</title><author><name sortKey="Bauge, J C" sort="Bauge, J C" uniqKey="Bauge J" first="J. C." last="Bauge">J. C. Bauge</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Département de Chimie Physique des Réactions, UMR 7630 CNRS, INPL‐ENSIC, 1 rue Grandville‐BP 451‐54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author><author><name sortKey="Battin Eclerc, F" sort="Battin Eclerc, F" uniqKey="Battin Eclerc F" first="F." last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Département de Chimie Physique des Réactions, UMR 7630 CNRS, INPL‐ENSIC, 1 rue Grandville‐BP 451‐54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Correspondence address: Département de Chimie Physique des Réactions, UMR 7630 CNRS, INPL‐ENSIC, 1 rue Grandville‐BP 451‐54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation></author><author><name sortKey="Baronnet, F" sort="Baronnet, F" uniqKey="Baronnet F" first="F." last="Baronnet">F. Baronnet</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Département de Chimie Physique des Réactions, UMR 7630 CNRS, INPL‐ENSIC, 1 rue Grandville‐BP 451‐54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">International Journal of Chemical Kinetics</title><title level="j" type="alt">INTERNATIONAL JOURNAL OF CHEMICAL KINETICS</title><idno type="ISSN">0538-8066</idno><idno type="eISSN">1097-4601</idno><imprint><biblScope unit="vol">30</biblScope><biblScope unit="issue">9</biblScope><biblScope unit="page" from="629">629</biblScope><biblScope unit="page" to="640">640</biblScope><biblScope unit="page-count">12</biblScope><publisher>John Wiley & Sons, Inc.</publisher><pubPlace>New York</pubPlace><date type="published" when="1998">1998</date></imprint><idno type="ISSN">0538-8066</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0538-8066</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Allene</term><term>Baronnet</term><term>Baronnet table</term><term>Batch bauge</term><term>Bauge</term><term>Carbon atoms</term><term>Carbon dioxide</term><term>Carbon monoxide</term><term>Ch2co</term><term>Ch2o</term><term>Chem</term><term>Equivalence ratio</term><term>Exgas</term><term>Exgas exgas exgas</term><term>Experimental data</term><term>Fuel equivalence ratios</term><term>Helium oxygen isobutene</term><term>Ignition delays</term><term>Isba</term><term>Isobutene</term><term>Isobutenyl</term><term>Isobutenyl radicals</term><term>Isobutyl radicals</term><term>Isobutyraldehyde</term><term>Ispr</term><term>Kinetic data</term><term>Kingas</term><term>Long right batch oxidation</term><term>Macr</term><term>Metathesis</term><term>Partial pressures</term><term>Phys</term><term>Primary mechanism</term><term>Propene</term><term>Richest mixtures</term><term>Risb</term><term>Secondary mechanism</term><term>Secondary reactions</term><term>Shock tube</term><term>Shock wave</term><term>Shock waves</term><term>Space time</term><term>Tted</term><term>Unimolecular</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Allene</term><term>Baronnet</term><term>Baronnet table</term><term>Batch bauge</term><term>Bauge</term><term>Carbon atoms</term><term>Carbon dioxide</term><term>Carbon monoxide</term><term>Ch2co</term><term>Ch2o</term><term>Chem</term><term>Equivalence ratio</term><term>Exgas</term><term>Exgas exgas exgas</term><term>Experimental data</term><term>Fuel equivalence ratios</term><term>Helium oxygen isobutene</term><term>Ignition delays</term><term>Isba</term><term>Isobutene</term><term>Isobutenyl</term><term>Isobutenyl radicals</term><term>Isobutyl radicals</term><term>Isobutyraldehyde</term><term>Ispr</term><term>Kinetic data</term><term>Kingas</term><term>Long right batch oxidation</term><term>Macr</term><term>Metathesis</term><term>Partial pressures</term><term>Phys</term><term>Primary mechanism</term><term>Propene</term><term>Richest mixtures</term><term>Risb</term><term>Secondary mechanism</term><term>Secondary reactions</term><term>Shock tube</term><term>Shock wave</term><term>Shock waves</term><term>Space time</term><term>Tted</term><term>Unimolecular</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This article describes an experimental and modeling study of the oxidation of isobutene. The low‐temperature oxidation was studied in a continuous‐flow stirred‐tank reactor operated at constant temperature (from 833 to 913 K) and pressure (1 atm), with fuel equivalence ratios from 3 to 6 and space times ranging from 1 to 10 s corresponding to isobutene conversion yields from 1 to 50%. The main carbon containing products were analyzed by gas chromatography. The ignition delays of isobutene‐oxygen‐argon mixtures with fuel equivalence ratios from 1 to 3 were measured behind shock waves. Reflected shock waves permitted to obtain temperatures from 1230 to 1930 K and pressures from 9.5 to 10.5 atm. A mechanism has been proposed to reproduce the profiles obtained for the reactants consumption and the products formation during the slow oxidation and to compute the ignition delays in the shock tube. Simulations were performed using CHEMKIN II. A correct agreement between the simulated values and the experimental data has been obtained in both apparatuses. The main reaction paths have been determined for both series of measurements by a sensitivity and rate of production analysis. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 629–640, 1998</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Université de Lorraine</li></orgName></list><tree><country name="France"><region name="Grand Est"><name sortKey="Bauge, J C" sort="Bauge, J C" uniqKey="Bauge J" first="J. C." last="Bauge">J. C. Bauge</name></region><name sortKey="Baronnet, F" sort="Baronnet, F" uniqKey="Baronnet F" first="F." last="Baronnet">F. Baronnet</name><name sortKey="Battin Eclerc, F" sort="Battin Eclerc, F" uniqKey="Battin Eclerc F" first="F." last="Battin-Leclerc">Frédérique Battin-Leclerc</name><name sortKey="Battin Eclerc, F" sort="Battin Eclerc, F" uniqKey="Battin Eclerc F" first="F." last="Battin-Leclerc">Frédérique Battin-Leclerc</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001F40 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001F40 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= LrgpV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:F6C8E3A5769D12A6FDADB84E8107783AA985FE15
|texte= Experimental and modeling study of the oxidation of isobutene
}}
| This area was generated with Dilib version V0.6.32. |  |