LrgpV1, Main, Exploration, bibRecord, 002033

Mechanism of "chloro-pyrolysis" of methane

Identifieur interne : 002033 ( Main/Exploration ); précédent : 002032; suivant : 002034

Mechanism of "chloro-pyrolysis" of methane

Auteurs : P.-M. Marquaire [France] ; M. Al Kazzaz [France]

Source :

Studies in surface science and catalysis [ 0167-2991 ] ; 1998.

RBID : Pascal:98-0498047

Descripteurs français

Pascal (Inist)
- Industrie pétrochimique, Gaz naturel, Méthane, Pyrolyse, Ethylène(chloro), Chloration, Cinétique chimique, Effet température.
Wicri :
- topic : Gaz naturel.

English descriptors

KwdEn :
- Chemical reaction kinetics, Chlorination, Ethylene(chloro), Methane, Natural gas, Petrochemical industry, Pyrolysis, Temperature effect.

Abstract

A detailed radical mechanism of "chloro-pyrolysis" of methane is proposed, it explains the formation of the vinyl chloride at high temperature (around 1000°C) in agreement with our experimental results and other kinetic studies. The analysis of mechanism allows to find the best operating conditions for increasing the vinyl chloride yield.

Affiliations:

France

Links toward previous steps (curation, corpus...)

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to stream PascalFrancis, to step Curation: 001295
to stream PascalFrancis, to step Checkpoint: 000C38
to stream Main, to step Merge: 002449
to stream Main, to step Curation: 002033

Le document en format XML

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<author><name sortKey="Marquaire, P M" sort="Marquaire, P M" uniqKey="Marquaire P" first="P.-M." last="Marquaire">P.-M. Marquaire</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Chimie Physique des Réactions, CNRS UMR 7630, ENSIC - INPL Université</s1>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>France</country>
<wicri:noRegion>ENSIC - INPL Université</wicri:noRegion>
<wicri:noRegion>Département de Chimie Physique des Réactions, CNRS UMR 7630, ENSIC - INPL Université</wicri:noRegion>
</affiliation>
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<author><name sortKey="Al Kazzaz, M" sort="Al Kazzaz, M" uniqKey="Al Kazzaz M" first="M." last="Al Kazzaz">M. Al Kazzaz</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Chimie Physique des Réactions, CNRS UMR 7630, ENSIC - INPL Université</s1>
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<country>France</country>
<wicri:noRegion>ENSIC - INPL Université</wicri:noRegion>
<wicri:noRegion>Département de Chimie Physique des Réactions, CNRS UMR 7630, ENSIC - INPL Université</wicri:noRegion>
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<author><name sortKey="Al Kazzaz, M" sort="Al Kazzaz, M" uniqKey="Al Kazzaz M" first="M." last="Al Kazzaz">M. Al Kazzaz</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chemical reaction kinetics</term>
<term>Chlorination</term>
<term>Ethylene(chloro)</term>
<term>Methane</term>
<term>Natural gas</term>
<term>Petrochemical industry</term>
<term>Pyrolysis</term>
<term>Temperature effect</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Industrie pétrochimique</term>
<term>Gaz naturel</term>
<term>Méthane</term>
<term>Pyrolyse</term>
<term>Ethylène(chloro)</term>
<term>Chloration</term>
<term>Cinétique chimique</term>
<term>Effet température</term>
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<front><div type="abstract" xml:lang="en">A detailed radical mechanism of "chloro-pyrolysis" of methane is proposed, it explains the formation of the vinyl chloride at high temperature (around 1000°C) in agreement with our experimental results and other kinetic studies. The analysis of mechanism allows to find the best operating conditions for increasing the vinyl chloride yield.</div>
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<name sortKey="Al Kazzaz, M" sort="Al Kazzaz, M" uniqKey="Al Kazzaz M" first="M." last="Al Kazzaz">M. Al Kazzaz</name>
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Mechanism of "chloro-pyrolysis" of methane

Mechanism of "chloro-pyrolysis" of methane

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri