Stereocontrolled synthesis of spirocyclics

Identifieur interne : 001C59 ( Main/Exploration ); précédent : 001C58; suivant : 001C60

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Stereocontrolled synthesis of spirocyclics

Auteurs : Mousumi Sannigrahi [Canada]

Source :

• Tetrahedron [ 0040-4020 ] ; 1999.

RBID : ISTEX:AD4759685480EF45228106BB36A443E5EA68FE03

English descriptors

• KwdEn :
  • Acetic, Acetic acid, Acorenone, Aldehyde, Aldol, Aldol condensation, Alkaloid, Alkylation, Ally1, Ally1 silanes, Allylic, Amide, Asymmetric, Asymmetric centers, Bridged, Bridged systems, Bromide, Bumell, Carbonyl, Chem, Chim, Chiral, Cleavage, Closure, Commun, Compound, Conjugate addition, Core structure, Cossy, Cyclization, Cycloaddition, Cyclopropane, Decarboxylation, Derivative, Diastereomeric, Diastereomeric mixture, Diastereomers, Dieckmann, Dieckmann condensation, Double bond, Enamine, Enantiomer, Enantioselectivity, Enolate, Enone, Equiv, Ester, Etoh, Formal synthesis, Gelsemine, Grob fragmentation, Heck reaction, Hmpa, Intermolecular, Intramolecular, Intramolecular aldol condensation, Intramolecular alkylation, Intramolecular michael addition, Isomer, Isonitramine, Isopropyl group, Ketone, Lett, Lewis acid, Ligand, Major isomer, Major product, Meli, Meoh, Methodology, Methyl, Methyl group, Methyl vinyl ketone, Methyllithium, Michael addition, Natural product, Oxindole, Perkin trans, Radical cyclization, Reagent, Rearrangement, Reflux, Relative configuration, Relative stereochemistry, Ring closure, Ring expansion, Ring opening, Sakai, Sannigrahi, Sannigrahi tetrahedron, Scheme, Sequential, Sesquiterpenes, Several steps, Sibirine, Spiro, Spiro compound, Spiro compounds, Spiro skeleton, Spiro system, Spiro systems, Spirocenter, Spirocycles, Spiroketone, Stereochemical, Stereochemical outcome, Stereochemistry, Stereoselective, Stereoselective synthesis, Stereoselectively, Stereoselectivity, Suemune, Sulfoxide, Tetrahedron, Tetrahedron lett, Transition state, Transition states, Triple bond, Trost, Tsoh, Wittig, Wittig reaction.
• Teeft :
  • Acetic, Acetic acid, Acorenone, Aldehyde, Aldol, Aldol condensation, Alkaloid, Alkylation, Ally1, Ally1 silanes, Allylic, Amide, Asymmetric, Asymmetric centers, Bridged, Bridged systems, Bromide, Bumell, Carbonyl, Chem, Chim, Chiral, Cleavage, Closure, Commun, Compound, Conjugate addition, Core structure, Cossy, Cyclization, Cycloaddition, Cyclopropane, Decarboxylation, Derivative, Diastereomeric, Diastereomeric mixture, Diastereomers, Dieckmann, Dieckmann condensation, Double bond, Enamine, Enantiomer, Enantioselectivity, Enolate, Enone, Equiv, Ester, Etoh, Formal synthesis, Gelsemine, Grob fragmentation, Heck reaction, Hmpa, Intermolecular, Intramolecular, Intramolecular aldol condensation, Intramolecular alkylation, Intramolecular michael addition, Isomer, Isonitramine, Isopropyl group, Ketone, Lett, Lewis acid, Ligand, Major isomer, Major product, Meli, Meoh, Methodology, Methyl, Methyl group, Methyl vinyl ketone, Methyllithium, Michael addition, Natural product, Oxindole, Perkin trans, Radical cyclization, Reagent, Rearrangement, Reflux, Relative configuration, Relative stereochemistry, Ring closure, Ring expansion, Ring opening, Sakai, Sannigrahi, Sannigrahi tetrahedron, Scheme, Sequential, Sesquiterpenes, Several steps, Sibirine, Spiro, Spiro compound, Spiro compounds, Spiro skeleton, Spiro system, Spiro systems, Spirocenter, Spirocycles, Spiroketone, Stereochemical, Stereochemical outcome, Stereochemistry, Stereoselective, Stereoselective synthesis, Stereoselectively, Stereoselectivity, Suemune, Sulfoxide, Tetrahedron, Tetrahedron lett, Transition state, Transition states, Triple bond, Trost, Tsoh, Wittig, Wittig reaction.

Abstract

Url:

• https://api.istex.fr/document/AD4759685480EF45228106BB36A443E5EA68FE03/fulltext/pdf

DOI: 10.1016/S0040-4020(99)00482-2

Affiliations:

• Canada

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