LrgpV1, Main, Curation, bibRecord, 001A59

Influence of the alkyl-chain size on the amphiphilic behaviour of poly(3-alkyl-1-vinylimidazolium) bromide in aqueous medium

Identifieur interne : 001A59 ( Main/Curation ); précédent : 001A58; suivant : 001A60

Influence of the alkyl-chain size on the amphiphilic behaviour of poly(3-alkyl-1-vinylimidazolium) bromide in aqueous medium

Auteurs : C. Leddet [France] ; A. Fischer [France] ; A. Brembilla [France] ; P. Lochon [France]

Source :

Polymer bulletin : (Berlin. Print) [ 0170-0839 ] ; 2001.

RBID : Pascal:01-0185745

Descripteurs français

Pascal (Inist)
- Imidazolium(vinyl) sel polymère, Polyélectrolyte, Polymère amphiphile, Solution aqueuse, Agrégation moléculaire, Effet structure, Longueur chaîne, Méthode étude, Tension superficielle, Viscosimétrie, Spectrométrie fluorescence, Etude expérimentale, Imidazolium(3-alkyl-1-vinyl) sel polymère.

English descriptors

KwdEn :
- Amphiphilic polymer, Aqueous solution, Chain length, Experimental study, Fluorescence spectrometry, Imidazolium(vinyl) salt polymer, Investigation method, Molecular aggregation, Polyelectrolyte, Structure effect, Surface tension, Viscosimetry.

Abstract

Several 3-alkyl-1-vinylimidazolium bromides differing by the length of the alkyl chain were prepared and polymerized using a free radical route. The behaviour of the obtained homopolymers in aqueous medium was investigated by several physico-chemical methods including viscosimetry, surface tension measurements and fluorescence spectroscopy. These experiments highlighted a strong influence of the length of the pendent alkyl chain on the side-chain aggregation tendency which is a property of such amphiphilic comb polymers. Fluorescence experiments were also conducted on the surface active analogues, in order to compare their behaviour to that of the polymers.

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Le document en format XML

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<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie-Physique Macromoléculaire, UMR CNRS-INPL 7568, Groupe ENSIC, 1, rue Grandville, BP 451</s1>
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<series><title level="j" type="main">Polymer bulletin : (Berlin. Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Amphiphilic polymer</term>
<term>Aqueous solution</term>
<term>Chain length</term>
<term>Experimental study</term>
<term>Fluorescence spectrometry</term>
<term>Imidazolium(vinyl) salt polymer</term>
<term>Investigation method</term>
<term>Molecular aggregation</term>
<term>Polyelectrolyte</term>
<term>Structure effect</term>
<term>Surface tension</term>
<term>Viscosimetry</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Imidazolium(vinyl) sel polymère</term>
<term>Polyélectrolyte</term>
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<term>Agrégation moléculaire</term>
<term>Effet structure</term>
<term>Longueur chaîne</term>
<term>Méthode étude</term>
<term>Tension superficielle</term>
<term>Viscosimétrie</term>
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<front><div type="abstract" xml:lang="en">Several 3-alkyl-1-vinylimidazolium bromides differing by the length of the alkyl chain were prepared and polymerized using a free radical route. The behaviour of the obtained homopolymers in aqueous medium was investigated by several physico-chemical methods including viscosimetry, surface tension measurements and fluorescence spectroscopy. These experiments highlighted a strong influence of the length of the pendent alkyl chain on the side-chain aggregation tendency which is a property of such amphiphilic comb polymers. Fluorescence experiments were also conducted on the surface active analogues, in order to compare their behaviour to that of the polymers.</div>
</front>
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Influence of the alkyl-chain size on the amphiphilic behaviour of poly(3-alkyl-1-vinylimidazolium) bromide in aqueous medium

Influence of the alkyl-chain size on the amphiphilic behaviour of poly(3-alkyl-1-vinylimidazolium) bromide in aqueous medium

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri