Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes
Identifieur interne : 001665 ( Istex/Corpus ); précédent : 001664; suivant : 001666Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes
Auteurs : P. M. Ghogomu ; M. Bouroukba ; J. Dellacherie ; D. Balesdent ; M. DirandSource :
- Thermochimica Acta [ 0040-6031 ] ; 1997.
English descriptors
- KwdEn :
- Acta, Analytical expression, Balesdent, Bouroukba, Carbon atom, Carbon atoms, Constant composition, Diaz pena, Different temperatures, Dirand, Enthalpy, Ethylbenzene, Excess enthalpies, Experimental cell, Fluid phase equilibria, Ghogomu, Infinite dilution, Literature values, Molar, Mole fraction, Paraffin, Partial molar, Reference cell, Relative deviation, Simple expression, Solution chemistry, Thermochimica acta.
- Teeft :
- Acta, Analytical expression, Balesdent, Bouroukba, Carbon atom, Carbon atoms, Constant composition, Diaz pena, Different temperatures, Dirand, Enthalpy, Ethylbenzene, Excess enthalpies, Experimental cell, Fluid phase equilibria, Ghogomu, Infinite dilution, Literature values, Molar, Mole fraction, Paraffin, Partial molar, Reference cell, Relative deviation, Simple expression, Solution chemistry, Thermochimica acta.
Abstract
Abstract: Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher n-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, hE increases with the number of carbon atoms in the n-alkane molecule. Also, for each alkane, hE decreases with increasing temperature, at constant composition. A simple analytical expression is used to represent the variation of hE with carbon number n, composition x, and temperature T in the domain (16 ≤ n ≤ 25; x ≤ 0.15; 298.15 ≤ T ≤ 330.00).
Url:
DOI: 10.1016/S0040-6031(97)00235-9
Links to Exploration step
ISTEX:DAB664797475C99B7C420EE99E6A8D8F98BAD705Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title><author><name sortKey="Ghogomu, P M" sort="Ghogomu, P M" uniqKey="Ghogomu P" first="P. M." last="Ghogomu">P. M. Ghogomu</name><affiliation><mods:affiliation>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</mods:affiliation></affiliation></author><author><name sortKey="Bouroukba, M" sort="Bouroukba, M" uniqKey="Bouroukba M" first="M." last="Bouroukba">M. Bouroukba</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Dellacherie, J" sort="Dellacherie, J" uniqKey="Dellacherie J" first="J." last="Dellacherie">J. Dellacherie</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Balesdent, D" sort="Balesdent, D" uniqKey="Balesdent D" first="D." last="Balesdent">D. Balesdent</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Dirand, M" sort="Dirand, M" uniqKey="Dirand M" first="M." last="Dirand">M. Dirand</name><affiliation><mods:affiliation>Corresponding author. Fax: (33) 03 83.35.08.11</mods:affiliation></affiliation><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: mdirand@ensic.u-nancy.fr</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:DAB664797475C99B7C420EE99E6A8D8F98BAD705</idno><date when="1997" year="1997">1997</date><idno type="doi">10.1016/S0040-6031(97)00235-9</idno><idno type="url">https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001665</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001665</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title><author><name sortKey="Ghogomu, P M" sort="Ghogomu, P M" uniqKey="Ghogomu P" first="P. M." last="Ghogomu">P. M. Ghogomu</name><affiliation><mods:affiliation>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</mods:affiliation></affiliation></author><author><name sortKey="Bouroukba, M" sort="Bouroukba, M" uniqKey="Bouroukba M" first="M." last="Bouroukba">M. Bouroukba</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Dellacherie, J" sort="Dellacherie, J" uniqKey="Dellacherie J" first="J." last="Dellacherie">J. Dellacherie</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Balesdent, D" sort="Balesdent, D" uniqKey="Balesdent D" first="D." last="Balesdent">D. Balesdent</name><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation></author><author><name sortKey="Dirand, M" sort="Dirand, M" uniqKey="Dirand M" first="M." last="Dirand">M. Dirand</name><affiliation><mods:affiliation>Corresponding author. Fax: (33) 03 83.35.08.11</mods:affiliation></affiliation><affiliation><mods:affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: mdirand@ensic.u-nancy.fr</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Thermochimica Acta</title><title level="j" type="abbrev">TCA</title><idno type="ISSN">0040-6031</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997">1997</date><biblScope unit="volume">302</biblScope><biblScope unit="issue">1–2</biblScope><biblScope unit="page" from="159">159</biblScope><biblScope unit="page" to="164">164</biblScope></imprint><idno type="ISSN">0040-6031</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0040-6031</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acta</term><term>Analytical expression</term><term>Balesdent</term><term>Bouroukba</term><term>Carbon atom</term><term>Carbon atoms</term><term>Constant composition</term><term>Diaz pena</term><term>Different temperatures</term><term>Dirand</term><term>Enthalpy</term><term>Ethylbenzene</term><term>Excess enthalpies</term><term>Experimental cell</term><term>Fluid phase equilibria</term><term>Ghogomu</term><term>Infinite dilution</term><term>Literature values</term><term>Molar</term><term>Mole fraction</term><term>Paraffin</term><term>Partial molar</term><term>Reference cell</term><term>Relative deviation</term><term>Simple expression</term><term>Solution chemistry</term><term>Thermochimica acta</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Acta</term><term>Analytical expression</term><term>Balesdent</term><term>Bouroukba</term><term>Carbon atom</term><term>Carbon atoms</term><term>Constant composition</term><term>Diaz pena</term><term>Different temperatures</term><term>Dirand</term><term>Enthalpy</term><term>Ethylbenzene</term><term>Excess enthalpies</term><term>Experimental cell</term><term>Fluid phase equilibria</term><term>Ghogomu</term><term>Infinite dilution</term><term>Literature values</term><term>Molar</term><term>Mole fraction</term><term>Paraffin</term><term>Partial molar</term><term>Reference cell</term><term>Relative deviation</term><term>Simple expression</term><term>Solution chemistry</term><term>Thermochimica acta</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher n-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, hE increases with the number of carbon atoms in the n-alkane molecule. Also, for each alkane, hE decreases with increasing temperature, at constant composition. A simple analytical expression is used to represent the variation of hE with carbon number n, composition x, and temperature T in the domain (16 ≤ n ≤ 25; x ≤ 0.15; 298.15 ≤ T ≤ 330.00).</div></front></TEI><istex><corpusName>elsevier</corpusName><keywords><teeft><json:string>acta</json:string><json:string>dirand</json:string><json:string>ghogomu</json:string><json:string>ethylbenzene</json:string><json:string>bouroukba</json:string><json:string>balesdent</json:string><json:string>paraffin</json:string><json:string>thermochimica acta</json:string><json:string>carbon atoms</json:string><json:string>molar</json:string><json:string>infinite dilution</json:string><json:string>constant composition</json:string><json:string>carbon atom</json:string><json:string>analytical expression</json:string><json:string>mole fraction</json:string><json:string>reference cell</json:string><json:string>partial molar</json:string><json:string>excess enthalpies</json:string><json:string>enthalpy</json:string><json:string>literature values</json:string><json:string>experimental cell</json:string><json:string>relative deviation</json:string><json:string>simple expression</json:string><json:string>diaz pena</json:string><json:string>solution chemistry</json:string><json:string>fluid phase equilibria</json:string><json:string>different temperatures</json:string></teeft></keywords><author><json:item><name>P.M. Ghogomu</name><affiliations><json:string>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</json:string></affiliations></json:item><json:item><name>M. Bouroukba</name><affiliations><json:string>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</json:string></affiliations></json:item><json:item><name>J. Dellacherie</name><affiliations><json:string>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</json:string></affiliations></json:item><json:item><name>D. Balesdent</name><affiliations><json:string>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</json:string></affiliations></json:item><json:item><name>M. Dirand</name><affiliations><json:string>Corresponding author. Fax: (33) 03 83.35.08.11</json:string><json:string>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</json:string><json:string>E-mail: mdirand@ensic.u-nancy.fr</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Excess thermodynamic properties</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>n-alkanes</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Solvent</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Crystallization</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Wax</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Petroleum</value></json:item></subject><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher n-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, hE increases with the number of carbon atoms in the n-alkane molecule. Also, for each alkane, hE decreases with increasing temperature, at constant composition. A simple analytical expression is used to represent the variation of hE with carbon number n, composition x, and temperature T in the domain (16 ≤ n ≤ 25; x ≤ 0.15; 298.15 ≤ T ≤ 330.00).</abstract><qualityIndicators><score>3.721</score><pdfVersion>1.2</pdfVersion><pdfPageSize>548 x 756 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>6</keywordCount><abstractCharCount>577</abstractCharCount><pdfWordCount>2593</pdfWordCount><pdfCharCount>12822</pdfCharCount><pdfPageCount>6</pdfPageCount><abstractWordCount>94</abstractWordCount></qualityIndicators><title>Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title><pii><json:string>S0040-6031(97)00235-9</json:string></pii><genre><json:string>research-article</json:string></genre><host><title>Thermochimica Acta</title><language><json:string>unknown</json:string></language><publicationDate>1997</publicationDate><issn><json:string>0040-6031</json:string></issn><pii><json:string>S0040-6031(00)X0045-7</json:string></pii><volume>302</volume><issue>1–2</issue><pages><first>159</first><last>164</last></pages><genre><json:string>journal</json:string></genre></host><categories><wos><json:string>science</json:string><json:string>chemistry, physical</json:string><json:string>chemistry, analytical</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>chemistry</json:string><json:string>physical chemistry</json:string></scienceMetrix><inist><json:string>sciences appliquees, technologies et medecines</json:string><json:string>sciences biologiques et medicales</json:string><json:string>sciences biologiques fondamentales et appliquees. psychologie</json:string><json:string>vecteurs d'importance medicale, nuisances, depredateurs des denrees et materiaux: surveillance des populations et lutte</json:string></inist></categories><publicationDate>1997</publicationDate><copyrightDate>1997</copyrightDate><doi><json:string>10.1016/S0040-6031(97)00235-9</json:string></doi><id>DAB664797475C99B7C420EE99E6A8D8F98BAD705</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>ELSEVIER</p></availability><date>1997</date></publicationStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a">Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title><author xml:id="author-0000"><persName><forename type="first">P.M.</forename><surname>Ghogomu</surname></persName><affiliation>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</affiliation></author><author xml:id="author-0001"><persName><forename type="first">M.</forename><surname>Bouroukba</surname></persName><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation></author><author xml:id="author-0002"><persName><forename type="first">J.</forename><surname>Dellacherie</surname></persName><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation></author><author xml:id="author-0003"><persName><forename type="first">D.</forename><surname>Balesdent</surname></persName><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation></author><author xml:id="author-0004"><persName><forename type="first">M.</forename><surname>Dirand</surname></persName><email>mdirand@ensic.u-nancy.fr</email><affiliation>Corresponding author. Fax: (33) 03 83.35.08.11</affiliation><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation></author><idno type="istex">DAB664797475C99B7C420EE99E6A8D8F98BAD705</idno><idno type="DOI">10.1016/S0040-6031(97)00235-9</idno><idno type="PII">S0040-6031(97)00235-9</idno></analytic><monogr><title level="j">Thermochimica Acta</title><title level="j" type="abbrev">TCA</title><idno type="pISSN">0040-6031</idno><idno type="PII">S0040-6031(00)X0045-7</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997"></date><biblScope unit="volume">302</biblScope><biblScope unit="issue">1–2</biblScope><biblScope unit="page" from="159">159</biblScope><biblScope unit="page" to="164">164</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1997</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher n-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, hE increases with the number of carbon atoms in the n-alkane molecule. Also, for each alkane, hE decreases with increasing temperature, at constant composition. A simple analytical expression is used to represent the variation of hE with carbon number n, composition x, and temperature T in the domain (16 ≤ n ≤ 25; x ≤ 0.15; 298.15 ≤ T ≤ 330.00).</p></abstract><textClass><keywords scheme="keyword"><list><head>Keywords</head><item><term>Excess thermodynamic properties</term></item><item><term>n-alkanes</term></item><item><term>Solvent</term></item><item><term>Crystallization</term></item><item><term>Wax</term></item><item><term>Petroleum</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1997">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>TCA</jid><aid>97002359</aid><ce:pii>S0040-6031(97)00235-9</ce:pii><ce:doi>10.1016/S0040-6031(97)00235-9</ce:doi><ce:copyright type="unknown" year="1997"></ce:copyright></item-info><head><ce:title>Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher <ce:italic>n</ce:italic>-alkanes</ce:title><ce:author-group><ce:author><ce:given-name>P.M.</ce:given-name><ce:surname>Ghogomu</ce:surname><ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Bouroukba</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>J.</ce:given-name><ce:surname>Dellacherie</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>D.</ce:given-name><ce:surname>Balesdent</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Dirand</ce:surname><ce:cross-ref refid="COR1"><ce:sup>∗</ce:sup></ce:cross-ref><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref><ce:e-address>mdirand@ensic.u-nancy.fr</ce:e-address></ce:author><ce:affiliation id="AFF1"><ce:label>a</ce:label><ce:textfn>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</ce:textfn></ce:affiliation><ce:affiliation id="AFF2"><ce:label>b</ce:label><ce:textfn>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</ce:textfn></ce:affiliation><ce:correspondence id="COR1"><ce:label>∗</ce:label><ce:text>Corresponding author. Fax: (33) 03 83.35.08.11</ce:text></ce:correspondence></ce:author-group><ce:date-received day="7" month="11" year="1996"></ce:date-received><ce:date-accepted day="29" month="5" year="1997"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher <ce:italic>n</ce:italic>-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, <ce:italic>h</ce:italic><ce:sup>E</ce:sup> increases with the number of carbon atoms in the <ce:italic>n</ce:italic>-alkane molecule. Also, for each alkane, <ce:italic>h</ce:italic><ce:sup>E</ce:sup> decreases with increasing temperature, at constant composition.</ce:simple-para><ce:simple-para>A simple analytical expression is used to represent the variation of <ce:italic>h</ce:italic><ce:sup>E</ce:sup> with carbon number <ce:italic>n</ce:italic>, composition <ce:italic>x</ce:italic>, and temperature <ce:italic>T</ce:italic> in the domain (16 ≤ <ce:italic>n</ce:italic> ≤ 25; <ce:italic>x</ce:italic> ≤ 0.15; 298.15 ≤ <ce:italic>T</ce:italic> ≤ 330.00).</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Excess thermodynamic properties</ce:text></ce:keyword><ce:keyword><ce:text><ce:italic>n</ce:italic>-alkanes</ce:text></ce:keyword><ce:keyword><ce:text>Solvent</ce:text></ce:keyword><ce:keyword><ce:text>Crystallization</ce:text></ce:keyword><ce:keyword><ce:text>Wax</ce:text></ce:keyword><ce:keyword><ce:text>Petroleum</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher</title></titleInfo><name type="personal"><namePart type="given">P.M.</namePart><namePart type="family">Ghogomu</namePart><affiliation>Department of Inorganic Chemistry, Faculty of Science, University of Yaounde I, P.O. Box 812, Yaounde, Cameroon</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Bouroukba</namePart><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J.</namePart><namePart type="family">Dellacherie</namePart><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D.</namePart><namePart type="family">Balesdent</namePart><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Dirand</namePart><affiliation>Corresponding author. Fax: (33) 03 83.35.08.11</affiliation><affiliation>Ecole Nationale Supérieure des Industries Chimiques (INPL), Laboratoire de Thermodynamique des Séparations I Rue Grandville, B.P. 451, 54001 Nancy, France</affiliation><affiliation>E-mail: mdirand@ensic.u-nancy.fr</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1997</dateIssued><copyrightDate encoding="w3cdtf">1997</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: Flow calorimetry has been used to measure the excess enthalpies (heats of mixing) of dilute solutions of higher n-alkanes (hexadecane to pentacosane) in ethylbenzene. The results show that at constant temperature and composition, hE increases with the number of carbon atoms in the n-alkane molecule. Also, for each alkane, hE decreases with increasing temperature, at constant composition. A simple analytical expression is used to represent the variation of hE with carbon number n, composition x, and temperature T in the domain (16 ≤ n ≤ 25; x ≤ 0.15; 298.15 ≤ T ≤ 330.00).</abstract><subject><genre>Keywords</genre><topic>Excess thermodynamic properties</topic><topic>n-alkanes</topic><topic>Solvent</topic><topic>Crystallization</topic><topic>Wax</topic><topic>Petroleum</topic></subject><relatedItem type="host"><titleInfo><title>Thermochimica Acta</title></titleInfo><titleInfo type="abbreviated"><title>TCA</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">19971022</dateIssued></originInfo><identifier type="ISSN">0040-6031</identifier><identifier type="PII">S0040-6031(00)X0045-7</identifier><part><date>19971022</date><detail type="volume"><number>302</number><caption>vol.</caption></detail><detail type="issue"><number>1–2</number><caption>no.</caption></detail><extent unit="issue-pages"><start>1</start><end>226</end></extent><extent unit="pages"><start>159</start><end>164</end></extent></part></relatedItem><identifier type="istex">DAB664797475C99B7C420EE99E6A8D8F98BAD705</identifier><identifier type="ark">ark:/67375/6H6-RH164S42-P</identifier><identifier type="DOI">10.1016/S0040-6031(97)00235-9</identifier><identifier type="PII">S0040-6031(97)00235-9</identifier><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/DAB664797475C99B7C420EE99E6A8D8F98BAD705/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001665 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 001665 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= LrgpV1
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:DAB664797475C99B7C420EE99E6A8D8F98BAD705
|texte= Calorimetric measurement of molar excess enthalpies of dilute solutions of ethylbenzene + higher n -alkanes
}}
| This area was generated with Dilib version V0.6.32. |  |