Effect of (Sr, Ba) substitution in La3Ga5SiO14 and La3M0.5Ga5.5O14(M=Nb5+, Ta5+) crystals on their synthesis, structure and piezoelectricity
Identifieur interne : 001527 ( Istex/Corpus ); précédent : 001526; suivant : 001528Effect of (Sr, Ba) substitution in La3Ga5SiO14 and La3M0.5Ga5.5O14(M=Nb5+, Ta5+) crystals on their synthesis, structure and piezoelectricity
Auteurs : H. Takeda ; T. Kato ; V. I. Chani ; H. Morikoshi ; K. Shimamura ; T. FukudaSource :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1999.
English descriptors
- KwdEn :
- Cation, Cation distribution, Chemical composition, Chemical composition analysis, Crystal growth, Crystallographic parameters, Elsevier science, Fukuda, Growth axis, Growth direction, Ieee intern, Initial part, Lattice, Lattice parameter, Lattice parameters, Materials research, Modulus, Piezoelectric, Piezoelectric modulus, Piezoelectric properties, Shimamura, Single crystal, Single crystals, Solid state reaction, Structural features, Structure analysis, Substitution, Takeda, Tetrahedral sites, Tohoku university, Transparent part, Type compounds, Type crystals, Type structure.
- Teeft :
- Cation, Cation distribution, Chemical composition, Chemical composition analysis, Crystal growth, Crystallographic parameters, Elsevier science, Fukuda, Growth axis, Growth direction, Ieee intern, Initial part, Lattice, Lattice parameter, Lattice parameters, Materials research, Modulus, Piezoelectric, Piezoelectric modulus, Piezoelectric properties, Shimamura, Single crystal, Single crystals, Solid state reaction, Structural features, Structure analysis, Substitution, Takeda, Tetrahedral sites, Tohoku university, Transparent part, Type compounds, Type crystals, Type structure.
Abstract
Abstract: Alkali-earth ion (Sr, Ba) substituted La3Ga5SiO14 and La3M0.5G5.5O14 (M=Nb5+,Ta5+) compounds were synthesized by solid state reaction. Sr-substituted La3Ta0.5Ga5.5O14 (Sr-LTG) single crystals were grown by the micro-pulling down and Czochralski techniques. The cation distribution in Sr-LTG has been determined by X-ray structure analysis. Some piezoelectric properties of Sr-LTG crystal are reported and compared with those of pure La3Ta0.5Ga5.5O14.
Url:
DOI: 10.1016/S0925-8388(99)00203-0
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Abstract: Alkali-earth ion (Sr, Ba) substituted La3Ga5SiO14 and La3M0.5G5.5O14 (M=Nb5+,Ta5+) compounds were synthesized by solid state reaction. Sr-substituted La3Ta0.5Ga5.5O14 (Sr-LTG) single crystals were grown by the micro-pulling down and Czochralski techniques. The cation distribution in Sr-LTG has been determined by X-ray structure analysis. Some piezoelectric properties of Sr-LTG crystal are reported and compared with those of pure La3Ta0.5Ga5.5O14.</div>
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<notesStmt><note type="content">Fig. 1: An illustration of the Ca3Ga2Ge4O14-type structure viewed along (a) [010] and (b) [001] directions.</note>
<note type="content">Fig. 2: Piezoelectric modulus ∣d11∣ versus the lattice parameter, a in Ca3Ga2Ge4O14-type crystals. After Fukuda et al. [8].</note>
<note type="content">Fig. 3: Dependence of lattice parameters on Sr-content (x) in Sr-LTG crystals grown by the μ-PD method.</note>
<note type="content">Fig. 4: Sr-LTG crystals grown under conditions given in experiment (a) No.1 and (b) No. 4 of Table 2. The scales are in mm.</note>
<note type="content">Fig. 5: Sr concentration distribution along the growth axis, analyzed for the Sr-LTG crystal No. 4 (see Fig. 4b), where C0 and Cs are the Sr concentrations in the initial melt and resulting crystal, respectively.</note>
<note type="content">Table 1: Results of (a) the solid state reaction and (b) the μ-PD growtha</note>
<note type="content">Table 2: Experimental growth conditions and characteristics of Sr-LTG crystals grown by the Cz technique</note>
<note type="content">Table 3: Atomic parameters of the Sr-LTG crystal No. 1 with estimated standard deviations in parentheses (R=4.0%, Rw=4.4%)a</note>
<note type="content">Table 4: Mean cation–oxygen distances in Å for the Sr-LTG crystal No. 1 compared with those for LTG</note>
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<abstract xml:lang="en"><p>Alkali-earth ion (Sr, Ba) substituted La3Ga5SiO14 and La3M0.5G5.5O14 (M=Nb5+,Ta5+) compounds were synthesized by solid state reaction. Sr-substituted La3Ta0.5Ga5.5O14 (Sr-LTG) single crystals were grown by the micro-pulling down and Czochralski techniques. The cation distribution in Sr-LTG has been determined by X-ray structure analysis. Some piezoelectric properties of Sr-LTG crystal are reported and compared with those of pure La3Ta0.5Ga5.5O14.</p>
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<head><ce:title>Effect of (Sr, Ba) substitution in La<ce:inf>3</ce:inf>
Ga<ce:inf>5</ce:inf>
SiO<ce:inf>14</ce:inf>
and La<ce:inf>3</ce:inf>
M<ce:inf>0.5</ce:inf>
Ga<ce:inf>5.5</ce:inf>
O<ce:inf>14</ce:inf>
(M=Nb<ce:sup>5+</ce:sup>
, Ta<ce:sup>5+</ce:sup>
) crystals on their synthesis, structure and piezoelectricity</ce:title>
<ce:author-group><ce:author><ce:given-name>H.</ce:given-name>
<ce:surname>Takeda</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup>
</ce:cross-ref>
<ce:cross-ref refid="CORR1">*</ce:cross-ref>
<ce:e-address>hirodx@lexus.imr.tohoku.ac.jp</ce:e-address>
</ce:author>
<ce:author><ce:given-name>T.</ce:given-name>
<ce:surname>Kato</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>V.I.</ce:given-name>
<ce:surname>Chani</ce:surname>
<ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>H.</ce:given-name>
<ce:surname>Morikoshi</ce:surname>
<ce:cross-ref refid="AFF3"><ce:sup>c</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>K.</ce:given-name>
<ce:surname>Shimamura</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>T.</ce:given-name>
<ce:surname>Fukuda</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:affiliation id="AFF1"><ce:label>a</ce:label>
<ce:textfn>Institute for Materials Research, Tohoku University, 980-8577, Sendai, Japan</ce:textfn>
</ce:affiliation>
<ce:affiliation id="AFF2"><ce:label>b</ce:label>
<ce:textfn>Center for Interdisciplinary Research, Tohoku University, 980-8578 Sendai, Japan</ce:textfn>
</ce:affiliation>
<ce:affiliation id="AFF3"><ce:label>c</ce:label>
<ce:textfn>Material Research Center, TDK Corporation, 272-8558, Ichikawa, Chiba, Japan</ce:textfn>
</ce:affiliation>
<ce:correspondence id="CORR1"><ce:label>*</ce:label>
<ce:text>Corresponding author. Fax: +81-22-215-2104</ce:text>
</ce:correspondence>
</ce:author-group>
<ce:date-received day="15" month="4" year="1999"></ce:date-received>
<ce:abstract><ce:section-title>Abstract</ce:section-title>
<ce:abstract-sec><ce:simple-para>Alkali-earth ion (Sr, Ba) substituted La<ce:inf>3</ce:inf>
Ga<ce:inf>5</ce:inf>
SiO<ce:inf>14</ce:inf>
and La<ce:inf>3</ce:inf>
M<ce:inf>0.5</ce:inf>
G<ce:inf>5.5</ce:inf>
O<ce:inf>14</ce:inf>
(M=Nb<ce:sup>5+</ce:sup>
,Ta<ce:sup>5+</ce:sup>
) compounds were synthesized by solid state reaction. Sr-substituted La<ce:inf>3</ce:inf>
Ta<ce:inf>0.5</ce:inf>
Ga<ce:inf>5.5</ce:inf>
O<ce:inf>14</ce:inf>
(Sr-LTG) single crystals were grown by the micro-pulling down and Czochralski techniques. The cation distribution in Sr-LTG has been determined by X-ray structure analysis. Some piezoelectric properties of Sr-LTG crystal are reported and compared with those of pure La<ce:inf>3</ce:inf>
Ta<ce:inf>0.5</ce:inf>
Ga<ce:inf>5.5</ce:inf>
O<ce:inf>14</ce:inf>
.</ce:simple-para>
</ce:abstract-sec>
</ce:abstract>
<ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title>
<ce:keyword><ce:text>Lanthanum gallates</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Alkali-earth substitution</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Single crystal growth</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Cation distribution</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Piezoelectric</ce:text>
</ce:keyword>
</ce:keywords>
<ce:keywords class="pacs"><ce:section-title>PACS</ce:section-title>
<ce:keyword><ce:text>81.05.Zx</ce:text>
</ce:keyword>
<ce:keyword><ce:text>81.10.Fq</ce:text>
</ce:keyword>
<ce:keyword><ce:text>77.65.Dq</ce:text>
</ce:keyword>
</ce:keywords>
</head>
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<mods version="3.6"><titleInfo><title>Effect of (Sr, Ba) substitution in La3Ga5SiO14 and La3M0.5Ga5.5O14(M=Nb5+, Ta5+) crystals on their synthesis, structure and piezoelectricity</title>
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<titleInfo type="alternative" contentType="CDATA"><title>Effect of (Sr, Ba) substitution in La</title>
</titleInfo>
<name type="personal"><namePart type="given">H.</namePart>
<namePart type="family">Takeda</namePart>
<affiliation>E-mail: hirodx@lexus.imr.tohoku.ac.jp</affiliation>
<affiliation>Institute for Materials Research, Tohoku University, 980-8577, Sendai, Japan</affiliation>
<description>Corresponding author. Fax: +81-22-215-2104</description>
<role><roleTerm type="text">author</roleTerm>
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</name>
<name type="personal"><namePart type="given">T.</namePart>
<namePart type="family">Kato</namePart>
<affiliation>Institute for Materials Research, Tohoku University, 980-8577, Sendai, Japan</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">V.I.</namePart>
<namePart type="family">Chani</namePart>
<affiliation>Center for Interdisciplinary Research, Tohoku University, 980-8578 Sendai, Japan</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">H.</namePart>
<namePart type="family">Morikoshi</namePart>
<affiliation>Material Research Center, TDK Corporation, 272-8558, Ichikawa, Chiba, Japan</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">K.</namePart>
<namePart type="family">Shimamura</namePart>
<affiliation>Institute for Materials Research, Tohoku University, 980-8577, Sendai, Japan</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">T.</namePart>
<namePart type="family">Fukuda</namePart>
<affiliation>Institute for Materials Research, Tohoku University, 980-8577, Sendai, Japan</affiliation>
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<abstract lang="en">Abstract: Alkali-earth ion (Sr, Ba) substituted La3Ga5SiO14 and La3M0.5G5.5O14 (M=Nb5+,Ta5+) compounds were synthesized by solid state reaction. Sr-substituted La3Ta0.5Ga5.5O14 (Sr-LTG) single crystals were grown by the micro-pulling down and Czochralski techniques. The cation distribution in Sr-LTG has been determined by X-ray structure analysis. Some piezoelectric properties of Sr-LTG crystal are reported and compared with those of pure La3Ta0.5Ga5.5O14.</abstract>
<note type="content">Fig. 1: An illustration of the Ca3Ga2Ge4O14-type structure viewed along (a) [010] and (b) [001] directions.</note>
<note type="content">Fig. 2: Piezoelectric modulus ∣d11∣ versus the lattice parameter, a in Ca3Ga2Ge4O14-type crystals. After Fukuda et al. [8].</note>
<note type="content">Fig. 3: Dependence of lattice parameters on Sr-content (x) in Sr-LTG crystals grown by the μ-PD method.</note>
<note type="content">Fig. 4: Sr-LTG crystals grown under conditions given in experiment (a) No.1 and (b) No. 4 of Table 2. The scales are in mm.</note>
<note type="content">Fig. 5: Sr concentration distribution along the growth axis, analyzed for the Sr-LTG crystal No. 4 (see Fig. 4b), where C0 and Cs are the Sr concentrations in the initial melt and resulting crystal, respectively.</note>
<note type="content">Table 1: Results of (a) the solid state reaction and (b) the μ-PD growtha</note>
<note type="content">Table 2: Experimental growth conditions and characteristics of Sr-LTG crystals grown by the Cz technique</note>
<note type="content">Table 3: Atomic parameters of the Sr-LTG crystal No. 1 with estimated standard deviations in parentheses (R=4.0%, Rw=4.4%)a</note>
<note type="content">Table 4: Mean cation–oxygen distances in Å for the Sr-LTG crystal No. 1 compared with those for LTG</note>
<subject><genre>Keywords</genre>
<topic>Lanthanum gallates</topic>
<topic>Alkali-earth substitution</topic>
<topic>Single crystal growth</topic>
<topic>Cation distribution</topic>
<topic>Piezoelectric</topic>
</subject>
<subject><genre>PACS</genre>
<topic>81.05.Zx</topic>
<topic>81.10.Fq</topic>
<topic>77.65.Dq</topic>
</subject>
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