Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis
Identifieur interne : 001443 ( Istex/Corpus ); précédent : 001442; suivant : 001444Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis
Auteurs : Masamichi Ogasawara ; Sachie Arae ; Susumu Watanabe ; Kiyohiko Nakajima ; Tamotsu TakahashiSource :
- Chemistry – A European Journal [ 0947-6539 ] ; 2013-03-25.
English descriptors
- KwdEn :
- Teeft :
Abstract
Planar chirality: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).
Url:
DOI: 10.1002/chem.201300116
Links to Exploration step
ISTEX:E0A090A8048CB4F4E80B94F07DF3A1F9274918FCLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title><author><name sortKey="Ogasawara, Masamichi" sort="Ogasawara, Masamichi" uniqKey="Ogasawara M" first="Masamichi" last="Ogasawara">Masamichi Ogasawara</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: ogasawar@cat.hokudai.ac.jp</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Arae, Sachie" sort="Arae, Sachie" uniqKey="Arae S" first="Sachie" last="Arae">Sachie Arae</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Watanabe, Susumu" sort="Watanabe, Susumu" uniqKey="Watanabe S" first="Susumu" last="Watanabe">Susumu Watanabe</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Nakajima, Kiyohiko" sort="Nakajima, Kiyohiko" uniqKey="Nakajima K" first="Kiyohiko" last="Nakajima">Kiyohiko Nakajima</name><affiliation><mods:affiliation>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)</mods:affiliation></affiliation></author><author><name sortKey="Takahashi, Tamotsu" sort="Takahashi, Tamotsu" uniqKey="Takahashi T" first="Tamotsu" last="Takahashi">Tamotsu Takahashi</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: tamotsu@cat.hokudai.ac.jp</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:E0A090A8048CB4F4E80B94F07DF3A1F9274918FC</idno><date when="2013" year="2013">2013</date><idno type="doi">10.1002/chem.201300116</idno><idno type="url">https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001443</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001443</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title><author><name sortKey="Ogasawara, Masamichi" sort="Ogasawara, Masamichi" uniqKey="Ogasawara M" first="Masamichi" last="Ogasawara">Masamichi Ogasawara</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: ogasawar@cat.hokudai.ac.jp</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Arae, Sachie" sort="Arae, Sachie" uniqKey="Arae S" first="Sachie" last="Arae">Sachie Arae</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Watanabe, Susumu" sort="Watanabe, Susumu" uniqKey="Watanabe S" first="Susumu" last="Watanabe">Susumu Watanabe</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author><author><name sortKey="Nakajima, Kiyohiko" sort="Nakajima, Kiyohiko" uniqKey="Nakajima K" first="Kiyohiko" last="Nakajima">Kiyohiko Nakajima</name><affiliation><mods:affiliation>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)</mods:affiliation></affiliation></author><author><name sortKey="Takahashi, Tamotsu" sort="Takahashi, Tamotsu" uniqKey="Takahashi T" first="Tamotsu" last="Takahashi">Tamotsu Takahashi</name><affiliation><mods:affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: tamotsu@cat.hokudai.ac.jp</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Chemistry – A European Journal</title><title level="j" type="alt">CHEMISTRY - A EUROPEAN JOURNAL</title><idno type="ISSN">0947-6539</idno><idno type="eISSN">1521-3765</idno><imprint><biblScope unit="vol">19</biblScope><biblScope unit="issue">13</biblScope><biblScope unit="page" from="4151">4151</biblScope><biblScope unit="page" to="4154">4154</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2013-03-25">2013-03-25</date></imprint><idno type="ISSN">0947-6539</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0947-6539</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Angew</term><term>Arcm</term><term>Chem</term><term>Chiral</term><term>Enantioselectivity</term><term>Ferrocenes</term><term>Grubbs</term><term>Hayashi</term><term>Hoveyda</term><term>Kinetic resolution</term><term>Krel</term><term>Krel value</term><term>Metathesis</term><term>Ogasawara</term><term>Other hand</term><term>Schrock</term><term>Takahashi</term><term>Test tube</term><term>Verlag gmbh</term><term>Watanabe</term><term>Weinheim</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Angew</term><term>Arcm</term><term>Chem</term><term>Chiral</term><term>Enantioselectivity</term><term>Ferrocenes</term><term>Grubbs</term><term>Hayashi</term><term>Hoveyda</term><term>Kinetic resolution</term><term>Krel</term><term>Krel value</term><term>Metathesis</term><term>Ogasawara</term><term>Other hand</term><term>Schrock</term><term>Takahashi</term><term>Test tube</term><term>Verlag gmbh</term><term>Watanabe</term><term>Weinheim</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">Planar chirality: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>angew</json:string><json:string>chiral</json:string><json:string>weinheim</json:string><json:string>metathesis</json:string><json:string>ogasawara</json:string><json:string>schrock</json:string><json:string>hoveyda</json:string><json:string>krel</json:string><json:string>grubbs</json:string><json:string>ferrocenes</json:string><json:string>arcm</json:string><json:string>watanabe</json:string><json:string>enantioselectivity</json:string><json:string>kinetic resolution</json:string><json:string>takahashi</json:string><json:string>hayashi</json:string><json:string>verlag gmbh</json:string><json:string>krel value</json:string><json:string>test tube</json:string><json:string>other hand</json:string></teeft></keywords><author><json:item><name>Prof. Dr. Ogasawara</name><affiliations><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string></affiliations></json:item><json:item><name>Sachie Arae</name><affiliations><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string></affiliations></json:item><json:item><name>Dr. Watanabe</name><affiliations><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string></affiliations></json:item><json:item><name>Prof. Dr. Nakajima</name><affiliations><json:string>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)</json:string></affiliations></json:item><json:item><name>Prof. Dr. Takahashi</name><affiliations><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string><json:string>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>asymmetric synthesis</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>chirality</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>kinetic resolution</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>metallocene</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>planar chirality</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>ring‐closing metathesis</value></json:item></subject><articleId><json:string>CHEM201300116</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>shortCommunication</json:string></originalGenre><abstract>Planar chirality: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).</abstract><qualityIndicators><score>3.488</score><pdfVersion>1.3</pdfVersion><pdfPageSize>595.276 x 841.89 pts (A4)</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>407</abstractCharCount><pdfWordCount>2960</pdfWordCount><pdfCharCount>17007</pdfCharCount><pdfPageCount>4</pdfPageCount><abstractWordCount>44</abstractWordCount></qualityIndicators><title>Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title><genre><json:string>brief-communication</json:string></genre><host><title>Chemistry – A European Journal</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-3765</json:string></doi><issn><json:string>0947-6539</json:string></issn><eissn><json:string>1521-3765</json:string></eissn><publisherId><json:string>CHEM</json:string></publisherId><volume>19</volume><issue>13</issue><pages><first>4151</first><last>4154</last><total>4</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Communication</value></json:item></subject></host><categories><wos><json:string>science</json:string><json:string>chemistry, multidisciplinary</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>chemistry</json:string><json:string>general chemistry</json:string></scienceMetrix></categories><publicationDate>2013</publicationDate><copyrightDate>2013</copyrightDate><doi><json:string>10.1002/chem.201300116</json:string></doi><id>E0A090A8048CB4F4E80B94F07DF3A1F9274918FC</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><licence>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</licence></availability><date type="published" when="2013-03-25"></date></publicationStmt><notesStmt><note type="content-type" subtype="brief-communication" source="shortCommunication" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="brief-communication"><analytic><title level="a" type="main" xml:lang="en">Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title><author xml:id="author-0000" role="corresp"><persName><addName>Prof. Dr.</addName><forename type="first">Masamichi</forename><surname>Ogasawara</surname></persName><email>ogasawar@cat.hokudai.ac.jp</email><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150<address><country key="JP"></country></address></affiliation><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation></author><author xml:id="author-0001"><persName><forename type="first">Sachie</forename><surname>Arae</surname></persName><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150<address><country key="JP"></country></address></affiliation></author><author xml:id="author-0002"><persName><addName>Dr.</addName><forename type="first">Susumu</forename><surname>Watanabe</surname></persName><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150<address><country key="JP"></country></address></affiliation></author><author xml:id="author-0003"><persName><addName>Prof. Dr.</addName><forename type="first">Kiyohiko</forename><surname>Nakajima</surname></persName><affiliation>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)<address><country key="JP"></country></address></affiliation></author><author xml:id="author-0004" role="corresp"><persName><addName>Prof. Dr.</addName><forename type="first">Tamotsu</forename><surname>Takahashi</surname></persName><email>tamotsu@cat.hokudai.ac.jp</email><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150<address><country key="JP"></country></address></affiliation><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation></author><idno type="istex">E0A090A8048CB4F4E80B94F07DF3A1F9274918FC</idno><idno type="ark">ark:/67375/WNG-2K7266M7-S</idno><idno type="DOI">10.1002/chem.201300116</idno><idno type="unit">CHEM201300116</idno><idno type="toTypesetVersion">file:CHEM.CHEM201300116.pdf</idno></analytic><monogr><title level="j" type="main">Chemistry – A European Journal</title><title level="j" type="alt">CHEMISTRY - A EUROPEAN JOURNAL</title><idno type="pISSN">0947-6539</idno><idno type="eISSN">1521-3765</idno><idno type="book-DOI">10.1002/(ISSN)1521-3765</idno><idno type="book-part-DOI">10.1002/chem.v19.13</idno><idno type="product">CHEM</idno><imprint><biblScope unit="vol">19</biblScope><biblScope unit="issue">13</biblScope><biblScope unit="page" from="4151">4151</biblScope><biblScope unit="page" to="4154">4154</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2013-03-25"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="graphical"><p><hi rend="bold">Planar chirality</hi>: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).<figure type="box"><media mimeType="image" url="urn:x-wiley:09476539:media:CHEM201300116:content"></media></figure></p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">asymmetric synthesis</term><term xml:id="kwd2">chirality</term><term xml:id="kwd3">kinetic resolution</term><term xml:id="kwd4">metallocene</term><term xml:id="kwd5">planar chirality</term><term xml:id="kwd6">ring‐closing metathesis</term></keywords><keywords rend="articleCategory"><term>Communication</term></keywords><keywords rend="tocHeading1"><term>Communications</term></keywords><keywords rend="tocHeading2"><term>Asymmetric Synthesis</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3765</doi><issn type="print">0947-6539</issn><issn type="electronic">1521-3765</issn><idGroup><id type="product" value="CHEM"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="CHEMISTRY - A EUROPEAN JOURNAL">Chemistry – A European Journal</title><title type="short">Chem. Eur. J.</title></titleGroup></publicationMeta><publicationMeta level="part" position="130"><doi origin="wiley" registered="yes">10.1002/chem.v19.13</doi><numberingGroup><numbering type="journalVolume" number="19">19</numbering><numbering type="journalIssue">13</numbering></numberingGroup><coverDate startDate="2013-03-25">March 25, 2013</coverDate></publicationMeta><publicationMeta level="unit" type="shortCommunication" position="14" status="forIssue"><doi origin="wiley" registered="yes">10.1002/chem.201300116</doi><idGroup><id type="unit" value="CHEM201300116"></id></idGroup><countGroup><count type="pageTotal" number="4"></count></countGroup><titleGroup><title type="articleCategory">Communication</title><title type="tocHeading1">Communications</title><title type="tocHeading2">Asymmetric Synthesis</title></titleGroup><copyright ownership="publisher">Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2013-01-13"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:3.4.6 mode:FullText mathml2tex" date="2015-06-10"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.4.6 mode:FullText" date="2015-06-10"></event><event type="publishedOnlineEarlyUnpaginated" date="2013-02-20"></event><event type="publishedOnlineFinalForm" date="2013-03-15"></event><event type="firstOnline" date="2013-02-20"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.6.4 mode:FullText" date="2015-10-04"></event></eventGroup><numberingGroup><numbering type="pageFirst">4151</numbering><numbering type="pageLast">4154</numbering></numberingGroup><correspondenceTo>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</correspondenceTo><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:CHEM.CHEM201300116.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="8"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="86"></count></countGroup><titleGroup><title type="main" xml:lang="en">Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa" corresponding="yes"><personName><honorifics>Prof. Dr.</honorifics><givenNames>Masamichi</givenNames><familyName>Ogasawara</familyName></personName><contactDetails><email>ogasawar@cat.hokudai.ac.jp</email></contactDetails></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Sachie</givenNames><familyName>Arae</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><honorifics>Dr.</honorifics><givenNames>Susumu</givenNames><familyName>Watanabe</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#ab"><personName><honorifics>Prof. Dr.</honorifics><givenNames>Kiyohiko</givenNames><familyName>Nakajima</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#aa" corresponding="yes"><personName><honorifics>Prof. Dr.</honorifics><givenNames>Tamotsu</givenNames><familyName>Takahashi</familyName></personName><contactDetails><email>tamotsu@cat.hokudai.ac.jp</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="JP" type="organization"><unparsedAffiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</unparsedAffiliation></affiliation><affiliation xml:id="ab" countryCode="JP" type="organization"><unparsedAffiliation>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">asymmetric synthesis</keyword><keyword xml:id="kwd2">chirality</keyword><keyword xml:id="kwd3">kinetic resolution</keyword><keyword xml:id="kwd4">metallocene</keyword><keyword xml:id="kwd5">planar chirality</keyword><keyword xml:id="kwd6">ring‐closing metathesis</keyword></keywordGroup><fundingInfo><fundingAgency>MEXT</fundingAgency><fundingNumber>24655039</fundingNumber></fundingInfo><supportingInformation><p>As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
</p><supportingInfoItem><mediaResource alt="supporting information" href="urn-x:wiley:09476539:media:chem201300116:chem_201300116_sm_miscellaneous_information"></mediaResource><caption>miscellaneous_information</caption></supportingInfoItem></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Planar chirality</b>: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:09476539:media:CHEM201300116:content"></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis</title></titleInfo><name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart><namePart type="given">Masamichi</namePart><namePart type="family">Ogasawara</namePart><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><affiliation>E-mail: ogasawar@cat.hokudai.ac.jp</affiliation><affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Sachie</namePart><namePart type="family">Arae</namePart><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Dr.</namePart><namePart type="given">Susumu</namePart><namePart type="family">Watanabe</namePart><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart><namePart type="given">Kiyohiko</namePart><namePart type="family">Nakajima</namePart><affiliation>Department of Chemistry, Aichi University of Education, Igaya, Kariya 448‐8542 (Japan)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart><namePart type="given">Tamotsu</namePart><namePart type="family">Takahashi</namePart><affiliation>Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><affiliation>E-mail: tamotsu@cat.hokudai.ac.jp</affiliation><affiliation>Correspondence address: Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita‐ku, Sapporo 001‐0021 (Japan), Fax: (+81) 11‐706‐9150</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2013-03-25</dateIssued><dateCaptured encoding="w3cdtf">2013-01-13</dateCaptured><copyrightDate encoding="w3cdtf">2013</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">8</extent><extent unit="tables">1</extent><extent unit="references">86</extent></physicalDescription><abstract>Planar chirality: Ring‐closing metathesis of 1,2‐diallylmetallocenes afforded the corresponding 4,7‐dihydroindenyl species in high yields. The metallocenes are planar chiral with two different allylic substituents, and kinetic resolution of the racemic 1,2‐diallylmetallocene derivatives was realized by molybdenum‐catalyzed asymmetric ring‐closing metathesis with excellent enantioselectivity (see scheme).</abstract><note type="funding">MEXT - No. 24655039; </note><subject lang="en"><genre>keywords</genre><topic>asymmetric synthesis</topic><topic>chirality</topic><topic>kinetic resolution</topic><topic>metallocene</topic><topic>planar chirality</topic><topic>ring‐closing metathesis</topic></subject><relatedItem type="host"><titleInfo><title>Chemistry – A European Journal</title></titleInfo><titleInfo type="abbreviated"><title>Chem. Eur. J.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><note type="content"> As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.Supporting Info Item: miscellaneous_information - </note><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">0947-6539</identifier><identifier type="eISSN">1521-3765</identifier><identifier type="DOI">10.1002/(ISSN)1521-3765</identifier><identifier type="PublisherID">CHEM</identifier><part><date>2013</date><detail type="volume"><caption>vol.</caption><number>19</number></detail><detail type="issue"><caption>no.</caption><number>13</number></detail><extent unit="pages"><start>4151</start><end>4154</end><total>4</total></extent></part></relatedItem><identifier type="istex">E0A090A8048CB4F4E80B94F07DF3A1F9274918FC</identifier><identifier type="ark">ark:/67375/WNG-2K7266M7-S</identifier><identifier type="DOI">10.1002/chem.201300116</identifier><identifier type="ArticleID">CHEM201300116</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>WILEY‐VCH Verlag</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/E0A090A8048CB4F4E80B94F07DF3A1F9274918FC/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001443 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 001443 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= LrgpV1
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:E0A090A8048CB4F4E80B94F07DF3A1F9274918FC
|texte= Kinetic Resolution of Planar‐Chiral 1,2‐Disubstituted Ferrocenes by Molybdenum‐Catalyzed Asymmetric Intraannular Ring‐Closing Metathesis
}}
| This area was generated with Dilib version V0.6.32. |  |