Application of equilibrium theory to ternary moving bed configurations (four+four, five+four, eight and nine zones)
Identifieur interne : 001096 ( Istex/Corpus ); précédent : 001095; suivant : 001097Application of equilibrium theory to ternary moving bed configurations (four+four, five+four, eight and nine zones)
Auteurs : Alexandre Nicolaos ; Laurence Muhr ; Patrice Gotteland ; Roger-Marc Nicoud ; Michel BaillySource :
- Journal of Chromatography A [ 0021-9673 ] ; 2001.
English descriptors
- KwdEn :
- Adsorption, Adsorption isotherms, Axial dispersion, Binary mixture, Case feed, Chemical compounds, Chromatogr, Chromatographic column, Chromatographic columns, Compound, Concentration step, Cost function, Different devices, Different objective functions, Elsevier science, Eluent, Eluent compound, Entire process, Equilibrium theory, Flow rate ratio, Four1four zone, French patent, General hypotheses, Goal function, Highest value, Internal recycling, Isotherm, Kinetic resistance, Linear adsorption isotherm, Linear adsorption isotherms, Liquid phase, Mass balance equation, Maximum pressure drop constraint, Migration direction, Migration direction rules, Migration directions, Morbidelli, Multicomponent mixture, Nicolaos, Nicoud, Outlet streams, Performance comparison, Point rule, Point rules, Practical considerations, Pure compound, Pure compounds, Pure fractions, Pure products, Retention parameters, Same methodology, Single device, Solid phase, Solvent consumption, Solvent consumption point, Stationary phase, Steady state, Target compound, Ternary, Ternary mixture, Tmbs, Total eluent, Ve1four, Ve1four zone, Work frame, Zone, Zone migration direction, Zone tmbs, Zones1four zones.
- Teeft :
- Adsorption, Adsorption isotherms, Axial dispersion, Binary mixture, Case feed, Chemical compounds, Chromatogr, Chromatographic column, Chromatographic columns, Compound, Concentration step, Cost function, Different devices, Different objective functions, Elsevier science, Eluent, Eluent compound, Entire process, Equilibrium theory, Flow rate ratio, Four1four zone, French patent, General hypotheses, Goal function, Highest value, Internal recycling, Isotherm, Kinetic resistance, Linear adsorption isotherm, Linear adsorption isotherms, Liquid phase, Mass balance equation, Maximum pressure drop constraint, Migration direction, Migration direction rules, Migration directions, Morbidelli, Multicomponent mixture, Nicolaos, Nicoud, Outlet streams, Performance comparison, Point rule, Point rules, Practical considerations, Pure compound, Pure compounds, Pure fractions, Pure products, Retention parameters, Same methodology, Single device, Solid phase, Solvent consumption, Solvent consumption point, Stationary phase, Steady state, Target compound, Ternary, Ternary mixture, Tmbs, Total eluent, Ve1four, Ve1four zone, Work frame, Zone, Zone migration direction, Zone tmbs, Zones1four zones.
Abstract
Abstract: In this article, different ternary moving bed configurations are studied by determining the working flow-rates of the equivalent true moving bed at the low solvent consumption point using equilibrium theory. This method has been applied for linear adsorption isotherms. The simulated moving bed flow-rates can then be calculated and a final comparison between the performances of each process is given based upon two different objective functions.
Url:
DOI: 10.1016/S0021-9673(00)00937-7
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Abstract: In this article, different ternary moving bed configurations are studied by determining the working flow-rates of the equivalent true moving bed at the low solvent consumption point using equilibrium theory. This method has been applied for linear adsorption isotherms. The simulated moving bed flow-rates can then be calculated and a final comparison between the performances of each process is given based upon two different objective functions.</div>
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<title level="a" type="sub">I. Linear case</title>
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<notesStmt><note type="content">Fig. 1: Four zone true moving bed configuration.</note>
<note type="content">Fig. 2: Four zone simulated moving bed configuration.</note>
<note type="content">Fig. 3: Two four zone TMBs in a row.</note>
<note type="content">Fig. 4: One five zone TMB followed by a four zone TMB.</note>
<note type="content">Fig. 5: Eight zone TMB.</note>
<note type="content">Fig. 6: Nine zone TMB.</note>
<note type="content">Fig. 7: Counter-current chromatographic zone.</note>
<note type="content">Fig. 8: Working regions of a four zone TMB (binary mixture).</note>
<note type="content">Fig. 9: Working region for two TMBs in a row (case KEY=1).</note>
<note type="content">Fig. 10: Working region of a five zone TMB.</note>
<note type="content">Fig. 11: Working diagrams for the eight zone TMB.</note>
<note type="content">Fig. 12: Working diagrams for the eight zone TMB (case KEY=2).</note>
<note type="content">Fig. 13: Working diagrams for the nine zone TMB (KEY=1). Case: K3−K2≥K2−K1.</note>
<note type="content">Fig. 14: Working diagrams for the nine zone TMB (case KEY=1). Case: K3−K2≤K2−K1.</note>
<note type="content">Fig. 15: TMB performance comparison in terms of R.</note>
<note type="content">Fig. 16: Comparison of the five+four zone TMB performances.</note>
<note type="content">Table 1: Flow-rate ratio intervals for a classical four zone TMB</note>
<note type="content">Table 2: Flow-rates at the LSC point for a four zone TMB</note>
<note type="content">Table 3: First four zone TMB flow-rate ratios</note>
<note type="content">Table 4: Second four zone TMB flow-rate ratios</note>
<note type="content">Table 5: Flow-rates of the first five zone TMB</note>
<note type="content">Table 6: Flow-rate ratios m of a five zone TMB</note>
<note type="content">Table 7: Flow-rates of the eight zone TMB configuration (case KEY=1)</note>
<note type="content">Table 8: Nine zone TMB flow-rate configuration (case KEY=1)</note>
<note type="content">Table 9: Working flow-rates of the nine zone TMB (case KEY=1)</note>
<note type="content">Table 10: Flow-rates for the two device configurations</note>
<note type="content">Table 11: Flow-rates of the single device configurations</note>
<note type="content">Table 12: Performance comparison (two device configurations)</note>
<note type="content">Table 13: Performance comparison (one device configuration)</note>
<note type="content">Table 14: SMB feed flow-rates for a given maximum pressure drop</note>
<note type="content">Table 15: SMB feed flow-rates (best configuration)</note>
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<abstract xml:lang="en"><p>In this article, different ternary moving bed configurations are studied by determining the working flow-rates of the equivalent true moving bed at the low solvent consumption point using equilibrium theory. This method has been applied for linear adsorption isotherms. The simulated moving bed flow-rates can then be calculated and a final comparison between the performances of each process is given based upon two different objective functions.</p>
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<item><term>Simulated moving bed chromatography</term>
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<item><term>Adsorption isotherms</term>
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<head><ce:title>Application of equilibrium theory to ternary moving bed configurations (four+four, five+four, eight and nine zones)</ce:title>
<ce:subtitle>I. Linear case</ce:subtitle>
<ce:author-group><ce:author><ce:given-name>Alexandre</ce:given-name>
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<ce:abstract-sec><ce:simple-para>In this article, different ternary moving bed configurations are studied by determining the working flow-rates of the equivalent true moving bed at the low solvent consumption point using equilibrium theory. This method has been applied for linear adsorption isotherms. The simulated moving bed flow-rates can then be calculated and a final comparison between the performances of each process is given based upon two different objective functions.</ce:simple-para>
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<ce:keyword><ce:text>Low solvent consumption point</ce:text>
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<ce:keyword><ce:text>Equilibrium theory</ce:text>
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<abstract lang="en">Abstract: In this article, different ternary moving bed configurations are studied by determining the working flow-rates of the equivalent true moving bed at the low solvent consumption point using equilibrium theory. This method has been applied for linear adsorption isotherms. The simulated moving bed flow-rates can then be calculated and a final comparison between the performances of each process is given based upon two different objective functions.</abstract>
<note type="content">Fig. 1: Four zone true moving bed configuration.</note>
<note type="content">Fig. 2: Four zone simulated moving bed configuration.</note>
<note type="content">Fig. 3: Two four zone TMBs in a row.</note>
<note type="content">Fig. 4: One five zone TMB followed by a four zone TMB.</note>
<note type="content">Fig. 5: Eight zone TMB.</note>
<note type="content">Fig. 6: Nine zone TMB.</note>
<note type="content">Fig. 7: Counter-current chromatographic zone.</note>
<note type="content">Fig. 8: Working regions of a four zone TMB (binary mixture).</note>
<note type="content">Fig. 9: Working region for two TMBs in a row (case KEY=1).</note>
<note type="content">Fig. 10: Working region of a five zone TMB.</note>
<note type="content">Fig. 11: Working diagrams for the eight zone TMB.</note>
<note type="content">Fig. 12: Working diagrams for the eight zone TMB (case KEY=2).</note>
<note type="content">Fig. 13: Working diagrams for the nine zone TMB (KEY=1). Case: K3−K2≥K2−K1.</note>
<note type="content">Fig. 14: Working diagrams for the nine zone TMB (case KEY=1). Case: K3−K2≤K2−K1.</note>
<note type="content">Fig. 15: TMB performance comparison in terms of R.</note>
<note type="content">Fig. 16: Comparison of the five+four zone TMB performances.</note>
<note type="content">Table 1: Flow-rate ratio intervals for a classical four zone TMB</note>
<note type="content">Table 2: Flow-rates at the LSC point for a four zone TMB</note>
<note type="content">Table 3: First four zone TMB flow-rate ratios</note>
<note type="content">Table 4: Second four zone TMB flow-rate ratios</note>
<note type="content">Table 5: Flow-rates of the first five zone TMB</note>
<note type="content">Table 6: Flow-rate ratios m of a five zone TMB</note>
<note type="content">Table 7: Flow-rates of the eight zone TMB configuration (case KEY=1)</note>
<note type="content">Table 8: Nine zone TMB flow-rate configuration (case KEY=1)</note>
<note type="content">Table 9: Working flow-rates of the nine zone TMB (case KEY=1)</note>
<note type="content">Table 10: Flow-rates for the two device configurations</note>
<note type="content">Table 11: Flow-rates of the single device configurations</note>
<note type="content">Table 12: Performance comparison (two device configurations)</note>
<note type="content">Table 13: Performance comparison (one device configuration)</note>
<note type="content">Table 14: SMB feed flow-rates for a given maximum pressure drop</note>
<note type="content">Table 15: SMB feed flow-rates (best configuration)</note>
<subject><genre>Keywords</genre>
<topic>Simulated moving bed chromatography</topic>
<topic>Low solvent consumption point</topic>
<topic>Equilibrium theory</topic>
<topic>Adsorption isotherms</topic>
<topic>Ternary moving bed configurations</topic>
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