Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants
Identifieur interne : 001074 ( Istex/Corpus ); précédent : 001073; suivant : 001075Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants
Auteurs : Christine Damas ; Alain Brembilla ; Francis Baros ; Marie-Laure Viriot ; Pierre LochonSource :
- European Polymer Journal [ 0014-3057 ] ; 1994.
English descriptors
- KwdEn :
- Acceleration effect, Active esters, Amphiphilic, Amphiphilic polymers, Amphiphilic polyvinylimidazolium salts, Aqueous media, Aqueous solution, Aqueous solutions, Benzimidazole, Bimolecular reaction, Bromide, Buffer solution, Carbon atoms, Cationic micelles, Chain length, Chem, Chloroform, Christine damaset, Crude material, Diethyl ether, Ester, Ethyl acetate, Experimental conditions, General procedure, Hepes buffer, Hexadecyl bromide, High solubility, Hmib, Hydrolysis reaction, Hydrophobic, Hydrophobic interactions, Hydrophobic microdomains, Hydrophobic reactants, Imidazole ring, Initiator, Interesting point, Kinetic study, Linear plots, Microdomains, Monomer, Other hand, Pci6vib, Polymer, Polymer microdomains, Polymer solution, Polymer solutions, Polysoaps concentration, Pyrene, Pyrene solution, Quaternary salt, Reaction time, Recrystallized, Room temperature, Small amount, Sodium persulphate, Stock solution, Surface tension, Surfactant, Surfactant concentration, Surfactant micelles, Various concentrations, Viscosity index, Viscosity measurements.
- Teeft :
- Acceleration effect, Active esters, Amphiphilic, Amphiphilic polymers, Amphiphilic polyvinylimidazolium salts, Aqueous media, Aqueous solution, Aqueous solutions, Benzimidazole, Bimolecular reaction, Bromide, Buffer solution, Carbon atoms, Cationic micelles, Chain length, Chem, Chloroform, Christine damaset, Crude material, Diethyl ether, Ester, Ethyl acetate, Experimental conditions, General procedure, Hepes buffer, Hexadecyl bromide, High solubility, Hmib, Hydrolysis reaction, Hydrophobic, Hydrophobic interactions, Hydrophobic microdomains, Hydrophobic reactants, Imidazole ring, Initiator, Interesting point, Kinetic study, Linear plots, Microdomains, Monomer, Other hand, Pci6vib, Polymer, Polymer microdomains, Polymer solution, Polymer solutions, Polysoaps concentration, Pyrene, Pyrene solution, Quaternary salt, Reaction time, Recrystallized, Room temperature, Small amount, Sodium persulphate, Stock solution, Surface tension, Surfactant, Surfactant concentration, Surfactant micelles, Various concentrations, Viscosity index, Viscosity measurements.
Abstract
Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.
Url:
DOI: 10.1016/0014-3057(94)90129-5
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</div>
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<abstract xml:lang="en"><p>Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</p>
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<head><ce:title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</ce:title>
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<ce:author><ce:given-name>Alain</ce:given-name>
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<ce:author><ce:given-name>Francis</ce:given-name>
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<ce:author><ce:given-name>Marie-Laure</ce:given-name>
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<ce:abstract-sec><ce:simple-para>Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, <ce:italic>T</ce:italic>
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<abstract lang="en">Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</abstract>
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