LrgpV1, Istex, Corpus, bibRecord, 001074

Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants

Identifieur interne : 001074 ( Istex/Corpus ); précédent : 001073; suivant : 001075

Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants

Auteurs : Christine Damas ; Alain Brembilla ; Francis Baros ; Marie-Laure Viriot ; Pierre Lochon

Source :

European Polymer Journal [ 0014-3057 ] ; 1994.

RBID : ISTEX:916088A4B559C9CCF37962C3072A9131CBD82433

English descriptors

Abstract

Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.

Url:

https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/pdf

DOI: 10.1016/0014-3057(94)90129-5

Links to Exploration step

ISTEX:916088A4B559C9CCF37962C3072A9131CBD82433

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
<author><name sortKey="Damas, Christine" sort="Damas, Christine" uniqKey="Damas C" first="Christine" last="Damas">Christine Damas</name>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Brembilla, Alain" sort="Brembilla, Alain" uniqKey="Brembilla A" first="Alain" last="Brembilla">Alain Brembilla</name>
<affiliation><mods:affiliation>To whom all correspondence should be addressed.</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Baros, Francis" sort="Baros, Francis" uniqKey="Baros F" first="Francis" last="Baros">Francis Baros</name>
<affiliation><mods:affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Viriot, Marie Laure" sort="Viriot, Marie Laure" uniqKey="Viriot M" first="Marie-Laure" last="Viriot">Marie-Laure Viriot</name>
<affiliation><mods:affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Lochon, Pierre" sort="Lochon, Pierre" uniqKey="Lochon P" first="Pierre" last="Lochon">Pierre Lochon</name>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:916088A4B559C9CCF37962C3072A9131CBD82433</idno>
<date when="1994" year="1994">1994</date>
<idno type="doi">10.1016/0014-3057(94)90129-5</idno>
<idno type="url">https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001074</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001074</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a">Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
<author><name sortKey="Damas, Christine" sort="Damas, Christine" uniqKey="Damas C" first="Christine" last="Damas">Christine Damas</name>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Brembilla, Alain" sort="Brembilla, Alain" uniqKey="Brembilla A" first="Alain" last="Brembilla">Alain Brembilla</name>
<affiliation><mods:affiliation>To whom all correspondence should be addressed.</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Baros, Francis" sort="Baros, Francis" uniqKey="Baros F" first="Francis" last="Baros">Francis Baros</name>
<affiliation><mods:affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Viriot, Marie Laure" sort="Viriot, Marie Laure" uniqKey="Viriot M" first="Marie-Laure" last="Viriot">Marie-Laure Viriot</name>
<affiliation><mods:affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Lochon, Pierre" sort="Lochon, Pierre" uniqKey="Lochon P" first="Pierre" last="Lochon">Pierre Lochon</name>
<affiliation><mods:affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</mods:affiliation>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">European Polymer Journal</title>
<title level="j" type="abbrev">EPJ</title>
<idno type="ISSN">0014-3057</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1994">1994</date>
<biblScope unit="volume">30</biblScope>
<biblScope unit="issue">11</biblScope>
<biblScope unit="page" from="1215">1215</biblScope>
<biblScope unit="page" to="1222">1222</biblScope>
</imprint>
<idno type="ISSN">0014-3057</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0014-3057</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acceleration effect</term>
<term>Active esters</term>
<term>Amphiphilic</term>
<term>Amphiphilic polymers</term>
<term>Amphiphilic polyvinylimidazolium salts</term>
<term>Aqueous media</term>
<term>Aqueous solution</term>
<term>Aqueous solutions</term>
<term>Benzimidazole</term>
<term>Bimolecular reaction</term>
<term>Bromide</term>
<term>Buffer solution</term>
<term>Carbon atoms</term>
<term>Cationic micelles</term>
<term>Chain length</term>
<term>Chem</term>
<term>Chloroform</term>
<term>Christine damaset</term>
<term>Crude material</term>
<term>Diethyl ether</term>
<term>Ester</term>
<term>Ethyl acetate</term>
<term>Experimental conditions</term>
<term>General procedure</term>
<term>Hepes buffer</term>
<term>Hexadecyl bromide</term>
<term>High solubility</term>
<term>Hmib</term>
<term>Hydrolysis reaction</term>
<term>Hydrophobic</term>
<term>Hydrophobic interactions</term>
<term>Hydrophobic microdomains</term>
<term>Hydrophobic reactants</term>
<term>Imidazole ring</term>
<term>Initiator</term>
<term>Interesting point</term>
<term>Kinetic study</term>
<term>Linear plots</term>
<term>Microdomains</term>
<term>Monomer</term>
<term>Other hand</term>
<term>Pci6vib</term>
<term>Polymer</term>
<term>Polymer microdomains</term>
<term>Polymer solution</term>
<term>Polymer solutions</term>
<term>Polysoaps concentration</term>
<term>Pyrene</term>
<term>Pyrene solution</term>
<term>Quaternary salt</term>
<term>Reaction time</term>
<term>Recrystallized</term>
<term>Room temperature</term>
<term>Small amount</term>
<term>Sodium persulphate</term>
<term>Stock solution</term>
<term>Surface tension</term>
<term>Surfactant</term>
<term>Surfactant concentration</term>
<term>Surfactant micelles</term>
<term>Various concentrations</term>
<term>Viscosity index</term>
<term>Viscosity measurements</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Acceleration effect</term>
<term>Active esters</term>
<term>Amphiphilic</term>
<term>Amphiphilic polymers</term>
<term>Amphiphilic polyvinylimidazolium salts</term>
<term>Aqueous media</term>
<term>Aqueous solution</term>
<term>Aqueous solutions</term>
<term>Benzimidazole</term>
<term>Bimolecular reaction</term>
<term>Bromide</term>
<term>Buffer solution</term>
<term>Carbon atoms</term>
<term>Cationic micelles</term>
<term>Chain length</term>
<term>Chem</term>
<term>Chloroform</term>
<term>Christine damaset</term>
<term>Crude material</term>
<term>Diethyl ether</term>
<term>Ester</term>
<term>Ethyl acetate</term>
<term>Experimental conditions</term>
<term>General procedure</term>
<term>Hepes buffer</term>
<term>Hexadecyl bromide</term>
<term>High solubility</term>
<term>Hmib</term>
<term>Hydrolysis reaction</term>
<term>Hydrophobic</term>
<term>Hydrophobic interactions</term>
<term>Hydrophobic microdomains</term>
<term>Hydrophobic reactants</term>
<term>Imidazole ring</term>
<term>Initiator</term>
<term>Interesting point</term>
<term>Kinetic study</term>
<term>Linear plots</term>
<term>Microdomains</term>
<term>Monomer</term>
<term>Other hand</term>
<term>Pci6vib</term>
<term>Polymer</term>
<term>Polymer microdomains</term>
<term>Polymer solution</term>
<term>Polymer solutions</term>
<term>Polysoaps concentration</term>
<term>Pyrene</term>
<term>Pyrene solution</term>
<term>Quaternary salt</term>
<term>Reaction time</term>
<term>Recrystallized</term>
<term>Room temperature</term>
<term>Small amount</term>
<term>Sodium persulphate</term>
<term>Stock solution</term>
<term>Surface tension</term>
<term>Surfactant</term>
<term>Surfactant concentration</term>
<term>Surfactant micelles</term>
<term>Various concentrations</term>
<term>Viscosity index</term>
<term>Viscosity measurements</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</div>
</front>
</TEI>
<istex><corpusName>elsevier</corpusName>
<keywords><teeft><json:string>polymer</json:string>
<json:string>bromide</json:string>
<json:string>ester</json:string>
<json:string>hmib</json:string>
<json:string>microdomains</json:string>
<json:string>chem</json:string>
<json:string>pci6vib</json:string>
<json:string>pyrene</json:string>
<json:string>aqueous media</json:string>
<json:string>benzimidazole</json:string>
<json:string>chloroform</json:string>
<json:string>amphiphilic</json:string>
<json:string>recrystallized</json:string>
<json:string>surfactant</json:string>
<json:string>room temperature</json:string>
<json:string>surface tension</json:string>
<json:string>imidazole ring</json:string>
<json:string>hydrophobic</json:string>
<json:string>experimental conditions</json:string>
<json:string>bimolecular reaction</json:string>
<json:string>ethyl acetate</json:string>
<json:string>hydrophobic reactants</json:string>
<json:string>viscosity index</json:string>
<json:string>quaternary salt</json:string>
<json:string>hydrophobic interactions</json:string>
<json:string>amphiphilic polymers</json:string>
<json:string>reaction time</json:string>
<json:string>viscosity measurements</json:string>
<json:string>hydrophobic microdomains</json:string>
<json:string>buffer solution</json:string>
<json:string>crude material</json:string>
<json:string>amphiphilic polyvinylimidazolium salts</json:string>
<json:string>aqueous solution</json:string>
<json:string>carbon atoms</json:string>
<json:string>general procedure</json:string>
<json:string>cationic micelles</json:string>
<json:string>small amount</json:string>
<json:string>hydrolysis reaction</json:string>
<json:string>acceleration effect</json:string>
<json:string>diethyl ether</json:string>
<json:string>surfactant concentration</json:string>
<json:string>various concentrations</json:string>
<json:string>christine damaset</json:string>
<json:string>polymer microdomains</json:string>
<json:string>pyrene solution</json:string>
<json:string>polymer solution</json:string>
<json:string>hexadecyl bromide</json:string>
<json:string>stock solution</json:string>
<json:string>interesting point</json:string>
<json:string>other hand</json:string>
<json:string>active esters</json:string>
<json:string>sodium persulphate</json:string>
<json:string>high solubility</json:string>
<json:string>polysoaps concentration</json:string>
<json:string>hepes buffer</json:string>
<json:string>aqueous solutions</json:string>
<json:string>surfactant micelles</json:string>
<json:string>chain length</json:string>
<json:string>polymer solutions</json:string>
<json:string>kinetic study</json:string>
<json:string>linear plots</json:string>
<json:string>monomer</json:string>
<json:string>initiator</json:string>
</teeft>
</keywords>
<author><json:item><name>Christine Damas</name>
<affiliations><json:string>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</json:string>
</affiliations>
</json:item>
<json:item><name>Alain Brembilla</name>
<affiliations><json:string>To whom all correspondence should be addressed.</json:string>
<json:string>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</json:string>
</affiliations>
</json:item>
<json:item><name>Francis Baros</name>
<affiliations><json:string>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</json:string>
</affiliations>
</json:item>
<json:item><name>Marie-Laure Viriot</name>
<affiliations><json:string>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</json:string>
</affiliations>
</json:item>
<json:item><name>Pierre Lochon</name>
<affiliations><json:string>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</json:string>
</affiliations>
</json:item>
</author>
<language><json:string>eng</json:string>
</language>
<originalGenre><json:string>Full-length article</json:string>
</originalGenre>
<abstract>Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</abstract>
<qualityIndicators><score>6.039</score>
<pdfVersion>1.2</pdfVersion>
<pdfPageSize>526 x 778 pts</pdfPageSize>
<refBibsNative>true</refBibsNative>
<keywordCount>0</keywordCount>
<abstractCharCount>801</abstractCharCount>
<pdfWordCount>4743</pdfWordCount>
<pdfCharCount>28279</pdfCharCount>
<pdfPageCount>8</pdfPageCount>
<abstractWordCount>108</abstractWordCount>
</qualityIndicators>
<title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
<pii><json:string>0014-3057(94)90129-5</json:string>
</pii>
<genre><json:string>research-article</json:string>
</genre>
<host><title>European Polymer Journal</title>
<language><json:string>unknown</json:string>
</language>
<publicationDate>1994</publicationDate>
<issn><json:string>0014-3057</json:string>
</issn>
<pii><json:string>S0014-3057(00)X0255-8</json:string>
</pii>
<volume>30</volume>
<issue>11</issue>
<pages><first>1215</first>
<last>1222</last>
</pages>
<genre><json:string>journal</json:string>
</genre>
</host>
<categories><wos><json:string>science</json:string>
<json:string>polymer science</json:string>
</wos>
<scienceMetrix><json:string>natural sciences</json:string>
<json:string>chemistry</json:string>
<json:string>polymers</json:string>
</scienceMetrix>
<inist><json:string>sciences appliquees, technologies et medecines</json:string>
<json:string>sciences biologiques et medicales</json:string>
<json:string>sciences biologiques fondamentales et appliquees. psychologie</json:string>
</inist>
</categories>
<publicationDate>1994</publicationDate>
<copyrightDate>1994</copyrightDate>
<doi><json:string>10.1016/0014-3057(94)90129-5</json:string>
</doi>
<id>916088A4B559C9CCF37962C3072A9131CBD82433</id>
<score>1</score>
<fulltext><json:item><extension>pdf</extension>
<original>true</original>
<mimetype>application/pdf</mimetype>
<uri>https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/pdf</uri>
</json:item>
<json:item><extension>zip</extension>
<original>false</original>
<mimetype>application/zip</mimetype>
<uri>https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/zip</uri>
</json:item>
<istex:fulltextTEI uri="https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
</titleStmt>
<publicationStmt><authority>ISTEX</authority>
<publisher>ELSEVIER</publisher>
<availability><p>ELSEVIER</p>
</availability>
<date>1994</date>
</publicationStmt>
<sourceDesc><biblStruct type="inbook"><analytic><title level="a">Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
<author xml:id="author-0000"><persName><forename type="first">Christine</forename>
<surname>Damas</surname>
</persName>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
</author>
<author xml:id="author-0001"><persName><forename type="first">Alain</forename>
<surname>Brembilla</surname>
</persName>
<affiliation>To whom all correspondence should be addressed.</affiliation>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
</author>
<author xml:id="author-0002"><persName><forename type="first">Francis</forename>
<surname>Baros</surname>
</persName>
<affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</affiliation>
</author>
<author xml:id="author-0003"><persName><forename type="first">Marie-Laure</forename>
<surname>Viriot</surname>
</persName>
<affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</affiliation>
</author>
<author xml:id="author-0004"><persName><forename type="first">Pierre</forename>
<surname>Lochon</surname>
</persName>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
</author>
<idno type="istex">916088A4B559C9CCF37962C3072A9131CBD82433</idno>
<idno type="DOI">10.1016/0014-3057(94)90129-5</idno>
<idno type="PII">0014-3057(94)90129-5</idno>
</analytic>
<monogr><title level="j">European Polymer Journal</title>
<title level="j" type="abbrev">EPJ</title>
<idno type="pISSN">0014-3057</idno>
<idno type="PII">S0014-3057(00)X0255-8</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1994"></date>
<biblScope unit="volume">30</biblScope>
<biblScope unit="issue">11</biblScope>
<biblScope unit="page" from="1215">1215</biblScope>
<biblScope unit="page" to="1222">1222</biblScope>
</imprint>
</monogr>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><creation><date>1994</date>
</creation>
<langUsage><language ident="en">en</language>
</langUsage>
<abstract xml:lang="en"><p>Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</p>
</abstract>
</profileDesc>
<revisionDesc><change when="1994">Published</change>
</revisionDesc>
</teiHeader>
</istex:fulltextTEI>
<json:item><extension>txt</extension>
<original>false</original>
<mimetype>text/plain</mimetype>
<uri>https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/fulltext/txt</uri>
</json:item>
</fulltext>
<metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration>
<istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType>
<istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>EPJ</jid>
<aid>94901295</aid>
<ce:pii>0014-3057(94)90129-5</ce:pii>
<ce:doi>10.1016/0014-3057(94)90129-5</ce:doi>
<ce:copyright type="unknown" year="1994"></ce:copyright>
</item-info>
<head><ce:title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</ce:title>
<ce:author-group><ce:author><ce:given-name>Christine</ce:given-name>
<ce:surname>Damas</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>1</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>Alain</ce:given-name>
<ce:surname>Brembilla</ce:surname>
<ce:cross-ref refid="COR1"><ce:sup>∗</ce:sup>
</ce:cross-ref>
<ce:cross-ref refid="AFF1"><ce:sup>1</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>Francis</ce:given-name>
<ce:surname>Baros</ce:surname>
<ce:cross-ref refid="AFF2"><ce:sup>2</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>Marie-Laure</ce:given-name>
<ce:surname>Viriot</ce:surname>
<ce:cross-ref refid="AFF2"><ce:sup>2</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author><ce:given-name>Pierre</ce:given-name>
<ce:surname>Lochon</ce:surname>
<ce:cross-ref refid="AFF1"><ce:sup>1</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:affiliation id="AFF1"><ce:label>a</ce:label>
<ce:textfn>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</ce:textfn>
</ce:affiliation>
<ce:affiliation id="AFF2"><ce:label>b</ce:label>
<ce:textfn>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</ce:textfn>
</ce:affiliation>
<ce:correspondence id="COR1"><ce:label>∗</ce:label>
<ce:text>To whom all correspondence should be addressed.</ce:text>
</ce:correspondence>
</ce:author-group>
<ce:date-received day="6" month="12" year="1993"></ce:date-received>
<ce:date-accepted day="5" month="1" year="1994"></ce:date-accepted>
<ce:abstract><ce:section-title>Abstract</ce:section-title>
<ce:abstract-sec><ce:simple-para>Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, <ce:italic>T</ce:italic>
 = 30°<ce:italic>C</ce:italic>
 were estimated and compared.</ce:simple-para>
</ce:abstract-sec>
</ce:abstract>
</head>
</converted-article>
</istex:document>
</istex:metadataXml>
<mods version="3.6"><titleInfo><title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA"><title>Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants</title>
</titleInfo>
<name type="personal"><namePart type="given">Christine</namePart>
<namePart type="family">Damas</namePart>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Alain</namePart>
<namePart type="family">Brembilla</namePart>
<affiliation>To whom all correspondence should be addressed.</affiliation>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Francis</namePart>
<namePart type="family">Baros</namePart>
<affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Marie-Laure</namePart>
<namePart type="family">Viriot</namePart>
<affiliation>Département de Chimie-Physique des Réactions, CNRS-URA-328, ENSIC-INPL, 1 rue Grandville, BP 451, 54001 Nancy Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Pierre</namePart>
<namePart type="family">Lochon</namePart>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494 Nancy Cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<typeOfResource>text</typeOfResource>
<genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre>
<originInfo><publisher>ELSEVIER</publisher>
<dateIssued encoding="w3cdtf">1994</dateIssued>
<copyrightDate encoding="w3cdtf">1994</copyrightDate>
</originInfo>
<language><languageTerm type="code" authority="iso639-2b">eng</languageTerm>
<languageTerm type="code" authority="rfc3066">en</languageTerm>
</language>
<abstract lang="en">Abstract: Homopolymers of 3-alkyl-1-vinylimidazolium bromides series have been prepared by free radical polymerization in aqueous solution or in benzene. The tendency of aggregation of these water soluble polymers was studied by viscosity measurements and fluorescence probes which have revealed the formation of hydrophobic microdomains. These polymers were tested in water media as a macromolecular matrix for the introduction of a microenvironment able to induce an acceleration effect for a bimolecular reaction involving two hydrophobic reactants. The reaction rates of 5(6)-decylbenzimidazole on the hydrolysis of 4′-nitrophenyl-5-alkoxypicolinates in the presence of the poly(3-hexadecyl-l-vinylimidazolium bromide) or its low molecular weight analogue at pH = 7.09, T = 30°C were estimated and compared.</abstract>
<relatedItem type="host"><titleInfo><title>European Polymer Journal</title>
</titleInfo>
<titleInfo type="abbreviated"><title>EPJ</title>
</titleInfo>
<genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre>
<originInfo><publisher>ELSEVIER</publisher>
<dateIssued encoding="w3cdtf">199411</dateIssued>
</originInfo>
<identifier type="ISSN">0014-3057</identifier>
<identifier type="PII">S0014-3057(00)X0255-8</identifier>
<part><date>199411</date>
<detail type="volume"><number>30</number>
<caption>vol.</caption>
</detail>
<detail type="issue"><number>11</number>
<caption>no.</caption>
</detail>
<extent unit="issue-pages"><start>1201</start>
<end>1346</end>
</extent>
<extent unit="pages"><start>1215</start>
<end>1222</end>
</extent>
</part>
</relatedItem>
<identifier type="istex">916088A4B559C9CCF37962C3072A9131CBD82433</identifier>
<identifier type="ark">ark:/67375/6H6-DHM3NSPL-R</identifier>
<identifier type="DOI">10.1016/0014-3057(94)90129-5</identifier>
<identifier type="PII">0014-3057(94)90129-5</identifier>
<recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource>
</recordInfo>
</mods>
<json:item><extension>json</extension>
<original>false</original>
<mimetype>application/json</mimetype>
<uri>https://api.istex.fr/document/916088A4B559C9CCF37962C3072A9131CBD82433/metadata/json</uri>
</json:item>
</metadata>
<serie></serie>
</istex>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Istex/Corpus

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001074 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 001074 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Lorraine
   |area=    LrgpV1
   |flux=    Istex
   |étape=   Corpus
   |type=    RBID
   |clé=     ISTEX:916088A4B559C9CCF37962C3072A9131CBD82433
   |texte=   Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants
}}

This area was generated with Dilib version V0.6.32.
Data generation: Sat Nov 11 15:47:48 2017. Site generation: Wed Mar 6 23:31:34 2024

	Serveur d'exploration sur le LRGP
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le LRGP

Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants

Synthesis and behaviour study of amphiphilic polyvinylimidazolium salts in aqueous media: Effects of the microdomains on a bimolecular reaction involving hydrophobic reactants

Source :

English descriptors

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri