Fluorescent molecular rotors as probes for polymers
Identifieur interne : 000D95 ( Istex/Corpus ); précédent : 000D94; suivant : 000D96Fluorescent molecular rotors as probes for polymers
Auteurs : Marie-Christiane Carré ; Catherine Dorion ; Richard Rebizak ; Fernand Pla ; Alain Brembilla ; Marie-Laure ViriotSource :
- Macromolecular Symposia [ 1022-1360 ] ; 1998-02.
English descriptors
- KwdEn :
- Amphiphilic polymers, Bromide, Bulk polymerization, Cationic polymers, Chimie physique, Cinnamylidene, Cinnamylidene rotor, Emulsion polymerization, Final plateau value, Fluorescence efficiency, Fluorescence emission, Fluorescence emission wavelength, Fluorescence intensity, Fluorescence quantum, Fluorescent, Fluorescent probe, Fluorescent pyrene probe, Fluorescent rotor, Fluorescent rotors, Free volume, Glass effect, Good agreement, Hmibr, Hydrophobic, Hydrophobic microdomains, Long alkyl chain polymers, Methyl polymers pviclbr, Microdomains, Molecular rotor, Polarity, Polarity probe, Polymer, Polymer beads, Polymers beads, Polyvinylimidazolium bromides, Polyvinylpyridinium bromides, Pviclbr, Pyrene, Radiative deactivation processes, Rotor, Surfactant, Viriot, Viscosity change, Viscosity probe.
- Teeft :
- Amphiphilic polymers, Bromide, Bulk polymerization, Cationic polymers, Chimie physique, Cinnamylidene, Cinnamylidene rotor, Emulsion polymerization, Final plateau value, Fluorescence efficiency, Fluorescence emission, Fluorescence emission wavelength, Fluorescence intensity, Fluorescence quantum, Fluorescent, Fluorescent probe, Fluorescent pyrene probe, Fluorescent rotor, Fluorescent rotors, Free volume, Glass effect, Good agreement, Hmibr, Hydrophobic, Hydrophobic microdomains, Long alkyl chain polymers, Methyl polymers pviclbr, Microdomains, Molecular rotor, Polarity, Polarity probe, Polymer, Polymer beads, Polymers beads, Polyvinylimidazolium bromides, Polyvinylpyridinium bromides, Pviclbr, Pyrene, Radiative deactivation processes, Rotor, Surfactant, Viriot, Viscosity change, Viscosity probe.
Abstract
The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.
Url:
DOI: 10.1002/masy.19981270123
Links to Exploration step
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<front><div type="abstract" xml:lang="en">The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.</div>
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<p>The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.</p>
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