Fluorescent molecular rotors as probes for polymers
Identifieur interne : 000D95 ( Istex/Corpus ); précédent : 000D94; suivant : 000D96Fluorescent molecular rotors as probes for polymers
Auteurs : Marie-Christiane Carré ; Catherine Dorion ; Richard Rebizak ; Fernand Pla ; Alain Brembilla ; Marie-Laure ViriotSource :
- Macromolecular Symposia [ 1022-1360 ] ; 1998-02.
English descriptors
- KwdEn :
- Amphiphilic polymers, Bromide, Bulk polymerization, Cationic polymers, Chimie physique, Cinnamylidene, Cinnamylidene rotor, Emulsion polymerization, Final plateau value, Fluorescence efficiency, Fluorescence emission, Fluorescence emission wavelength, Fluorescence intensity, Fluorescence quantum, Fluorescent, Fluorescent probe, Fluorescent pyrene probe, Fluorescent rotor, Fluorescent rotors, Free volume, Glass effect, Good agreement, Hmibr, Hydrophobic, Hydrophobic microdomains, Long alkyl chain polymers, Methyl polymers pviclbr, Microdomains, Molecular rotor, Polarity, Polarity probe, Polymer, Polymer beads, Polymers beads, Polyvinylimidazolium bromides, Polyvinylpyridinium bromides, Pviclbr, Pyrene, Radiative deactivation processes, Rotor, Surfactant, Viriot, Viscosity change, Viscosity probe.
- Teeft :
- Amphiphilic polymers, Bromide, Bulk polymerization, Cationic polymers, Chimie physique, Cinnamylidene, Cinnamylidene rotor, Emulsion polymerization, Final plateau value, Fluorescence efficiency, Fluorescence emission, Fluorescence emission wavelength, Fluorescence intensity, Fluorescence quantum, Fluorescent, Fluorescent probe, Fluorescent pyrene probe, Fluorescent rotor, Fluorescent rotors, Free volume, Glass effect, Good agreement, Hmibr, Hydrophobic, Hydrophobic microdomains, Long alkyl chain polymers, Methyl polymers pviclbr, Microdomains, Molecular rotor, Polarity, Polarity probe, Polymer, Polymer beads, Polymers beads, Polyvinylimidazolium bromides, Polyvinylpyridinium bromides, Pviclbr, Pyrene, Radiative deactivation processes, Rotor, Surfactant, Viriot, Viscosity change, Viscosity probe.
Abstract
The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.
Url:
DOI: 10.1002/masy.19981270123
Links to Exploration step
ISTEX:30089C3D5976FCEA36CF89DB719A42A949605DB6Le document en format XML
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type="first">Catherine</forename><surname>Dorion</surname></persName><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Richard</forename><surname>Rebizak</surname></persName><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Fernand</forename><surname>Pla</surname></persName><affiliation>Laboratoire des Sciences du Génie Chimique (GRC) ‐ UPR 6811 CNRS<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0004"><persName><forename type="first">Alain</forename><surname>Brembilla</surname></persName><affiliation>Laboratoire de Chimie Physique Macromoléculaire ‐ URA 494 CNRS, ENSIC‐INPL, 1, rue Grandville BP 451 F‐54001 Nancy Cedex ‐ 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First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. 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Symp.</title></titleGroup></publicationMeta><publicationMeta level="part" position="10"><doi origin="wiley" registered="no">10.1002/masy.v127.1</doi><numberingGroup><numbering type="journalVolume" number="127">127</numbering><numbering type="journalIssue">1</numbering></numberingGroup><coverDate startDate="1998-02">February 1998</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="23" status="forIssue"><doi origin="wiley" registered="no">10.1002/masy.19981270123</doi><idGroup><id type="unit" value="MASY19981270123"></id></idGroup><countGroup><count type="pageTotal" number="8"></count></countGroup><titleGroup><title type="articleCategory">Article</title><title type="tocHeading1">Articles</title></titleGroup><copyright ownership="publisher">Copyright © 1998 Hüthig & Wepf Verlag</copyright><eventGroup><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.4.7 mode:FullText" date="2011-03-04"></event><event type="firstOnline" date="2011-03-04"></event><event type="publishedOnlineFinalForm" date="2011-03-04"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-02"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-31"></event></eventGroup><numberingGroup><numbering type="pageFirst">173</numbering><numbering type="pageLast">180</numbering></numberingGroup><correspondenceTo>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:MASY.MASY19981270123.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="9"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="15"></count></countGroup><titleGroup><title type="main" xml:lang="en">Fluorescent molecular rotors as probes for polymers</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Marie‐Christiane</givenNames><familyName>Carré</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Catherine</givenNames><familyName>Dorion</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Richard</givenNames><familyName>Rebizak</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Fernand</givenNames><familyName>Pla</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Alain</givenNames><familyName>Brembilla</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><givenNames>Marie‐Laure</givenNames><familyName>Viriot</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>Laboratoire des Sciences du Génie Chimique (GRC) ‐ UPR 6811 CNRS</unparsedAffiliation></affiliation><affiliation xml:id="af3" countryCode="FR" type="organization"><unparsedAffiliation>Laboratoire de Chimie Physique Macromoléculaire ‐ URA 494 CNRS, ENSIC‐INPL, 1, rue Grandville BP 451 F‐54001 Nancy Cedex ‐ France</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Fluorescent molecular rotors as probes for polymers</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Fluorescent molecular rotors as probes for polymers</title></titleInfo><name type="personal"><namePart type="given">Marie‐Christiane</namePart><namePart type="family">Carré</namePart><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Catherine</namePart><namePart type="family">Dorion</namePart><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Richard</namePart><namePart type="family">Rebizak</namePart><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Fernand</namePart><namePart type="family">Pla</namePart><affiliation>Laboratoire des Sciences du Génie Chimique (GRC) ‐ UPR 6811 CNRS</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Alain</namePart><namePart type="family">Brembilla</namePart><affiliation>Laboratoire de Chimie Physique Macromoléculaire ‐ URA 494 CNRS, ENSIC‐INPL, 1, rue Grandville BP 451 F‐54001 Nancy Cedex ‐ France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Marie‐Laure</namePart><namePart type="family">Viriot</namePart><affiliation>Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</affiliation><affiliation>Correspondence address: Département de Chimie Physique des Réactions (GRAPP) ‐ URA 328 CNRS</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Hüthig & Wepf Verlag</publisher><place><placeTerm type="text">Basel</placeTerm></place><dateIssued encoding="w3cdtf">1998-02</dateIssued><copyrightDate encoding="w3cdtf">1998</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">9</extent><extent unit="tables">1</extent><extent unit="references">15</extent></physicalDescription><abstract lang="en">The use of a molecular rotor (1,1‐dicyano‐4‐(4'‐dimethylaminophenyl)‐1,3‐butadiene) as a fluorescent probe was proved to be of great interest for the study of polymers. First, the rotor can detect the critical time of the glass effect in the bulk polymerization of MMA into PMMA due to viscosity change, this will allow a better control of the process and is complementary to the information issued from the use of the fluorescent pyrene probe which is sensitive to the gel effect. Second, the cinnamylidene rotor was able to detect the formation of hydrophobic microdomains for cationic amphiphilic polymers in their aggregation modes when they were solubilized in water, both polarity and viscosity changes are playing a role. The possibility of incorporation of various molecular fluorescent rotors in polymers beads was also studied.</abstract><relatedItem type="host"><titleInfo><title>Macromolecular Symposia</title></titleInfo><titleInfo type="abbreviated"><title>Macromol. Symp.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Article</topic></subject><identifier type="ISSN">1022-1360</identifier><identifier type="eISSN">1521-3900</identifier><identifier type="DOI">10.1002/(ISSN)1521-3900</identifier><identifier type="PublisherID">MASY</identifier><part><date>1998</date><detail type="volume"><caption>vol.</caption><number>127</number></detail><detail type="issue"><caption>no.</caption><number>1</number></detail><extent unit="pages"><start>173</start><end>180</end><total>8</total></extent></part></relatedItem><identifier type="istex">30089C3D5976FCEA36CF89DB719A42A949605DB6</identifier><identifier type="ark">ark:/67375/WNG-2XCLX0BC-P</identifier><identifier type="DOI">10.1002/masy.19981270123</identifier><identifier type="ArticleID">MASY19981270123</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 1998 Hüthig & Wepf Verlag</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Hüthig & Wepf Verlag</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/30089C3D5976FCEA36CF89DB719A42A949605DB6/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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