LrgpV1, Istex, Corpus, bibRecord, 000C75

The low temperature limit of the application of solid electrolyte potentiometry in heterogeneous catalysis

Identifieur interne : 000C75 ( Istex/Corpus ); précédent : 000C74; suivant : 000C76

The low temperature limit of the application of solid electrolyte potentiometry in heterogeneous catalysis

Auteurs : J. Brück ; H.-G. Lintz ; G. Valentin

Source :

Solid State Ionics [ 0167-2738 ] ; 1998.

RBID : ISTEX:5B47EF170D584633503A5C1DAD581F5518C257AF

English descriptors

KwdEn :
- Appl, Bruck, Catal, Catalyst, Catalyst electrode, Catalytic interest, Electrochemical, Electrochemical cell, Electrolyte, Elsevier science, Equilibrium conditions, Hildenbrand, Karlsruhe, Limit temperature, Lintz, Lower temperature limit, Nernst equation, Oxidic, Oxidic catalysts, Oxygen activity, Phase border line, Polarization effects, Potentiometric, Potentiometric measurements, Reactive, Reactive conditions, Reference electrode, Reference side, Solid electrolyte, Solid electrolyte electrochemical cells, Solid electrolyte potentiometry, Solid state ionics, Stable values, Temperature dependence, Temperature limit, Typical results, Vayenas.
Teeft :
- Appl, Bruck, Catal, Catalyst, Catalyst electrode, Catalytic interest, Electrochemical, Electrochemical cell, Electrolyte, Elsevier science, Equilibrium conditions, Hildenbrand, Karlsruhe, Limit temperature, Lintz, Lower temperature limit, Nernst equation, Oxidic, Oxidic catalysts, Oxygen activity, Phase border line, Polarization effects, Potentiometric, Potentiometric measurements, Reactive, Reactive conditions, Reference electrode, Reference side, Solid electrolyte, Solid electrolyte electrochemical cells, Solid electrolyte potentiometry, Solid state ionics, Stable values, Temperature dependence, Temperature limit, Typical results, Vayenas.

Abstract

Abstract: Solid Electrolyte Potentiometry is an electrochemical method to characterise the state of solid catalysts under working conditions. Its application is temperature limited due to polarization effects at the catalyst electrode. A new operational definition of this temperature limit is proposed which is based on the measurements of exchange current densities.

Url:

https://api.istex.fr/document/5B47EF170D584633503A5C1DAD581F5518C257AF/fulltext/pdf

DOI: 10.1016/S0167-2738(98)00201-X

Links to Exploration step

ISTEX:5B47EF170D584633503A5C1DAD581F5518C257AF

Le document en format XML

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<notesStmt><note type="content">Fig. 1: Temperature dependence of the equilibrium potential ΔE*; (catalyst electrode: Pt, reference electrode: Pt).</note>
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<abstract lang="en">Abstract: Solid Electrolyte Potentiometry is an electrochemical method to characterise the state of solid catalysts under working conditions. Its application is temperature limited due to polarization effects at the catalyst electrode. A new operational definition of this temperature limit is proposed which is based on the measurements of exchange current densities.</abstract>
<note type="content">Fig. 1: Temperature dependence of the equilibrium potential ΔE*; (catalyst electrode: Pt, reference electrode: Pt).</note>
<note type="content">Fig. 2: Temperature dependence of the equilibrium potential ΔE*; (catalyst electrode: V2O5/TiO2, reference electrode: Pt).</note>
<note type="content">Table 1: Experimentally determined values of the low temperature limit, ϑL, for the use of solid electrolyte electrochemical cells under equilibrium conditions</note>
<note type="content">Table 2: Exchange current densities at different temperatures and gas phase compositions (catalyst electrode: vanadia–titania, reference electrode: Pt)</note>
<subject><genre>Keywords</genre>
<topic>SEP</topic>
<topic>Electrochemical cell</topic>
<topic>Catalytic electrode</topic>
<topic>Oxidic catalyst</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Solid State Ionics</title>
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<titleInfo type="abbreviated"><title>SOSI</title>
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<genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre>
<originInfo><publisher>ELSEVIER</publisher>
<dateIssued encoding="w3cdtf">19980902</dateIssued>
</originInfo>
<identifier type="ISSN">0167-2738</identifier>
<identifier type="PII">S0167-2738(00)X0053-7</identifier>
<part><date>19980902</date>
<detail type="volume"><number>112</number>
<caption>vol.</caption>
</detail>
<detail type="issue"><number>1–2</number>
<caption>no.</caption>
</detail>
<extent unit="issue-pages"><start>1</start>
<end>172</end>
</extent>
<extent unit="pages"><start>75</start>
<end>78</end>
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<identifier type="istex">5B47EF170D584633503A5C1DAD581F5518C257AF</identifier>
<identifier type="ark">ark:/67375/6H6-PR39DPHL-S</identifier>
<identifier type="DOI">10.1016/S0167-2738(98)00201-X</identifier>
<identifier type="PII">S0167-2738(98)00201-X</identifier>
<accessCondition type="use and reproduction" contentType="copyright">©1998 Elsevier Science B.V.</accessCondition>
<recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource>
<recordOrigin>Elsevier Science B.V., ©1998</recordOrigin>
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The low temperature limit of the application of solid electrolyte potentiometry in heterogeneous catalysis

The low temperature limit of the application of solid electrolyte potentiometry in heterogeneous catalysis

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