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Covalent coupling of a short polyether on sodium alginate: Synthesis and characterization of the resulting amphiphilic derivative

Identifieur interne : 000A76 ( Istex/Corpus ); précédent : 000A75; suivant : 000A77

Covalent coupling of a short polyether on sodium alginate: Synthesis and characterization of the resulting amphiphilic derivative

Auteurs : Marie-Christiane Carré ; Christine Delestre ; Patrick Hubert ; Edith Dellacherie

Source :

RBID : ISTEX:298613BFAF7EE4AC6FFA49FBD95B1BEF1C53A485

English descriptors

Abstract

Abstract: A covalent sodium alginate-polyoxyethylene model derivative was prepared by reductive amination of aldehydic sodium alginate, in order to obtain a polymer with amphiphilic properties. Characterization of this derivative was carried out by NMR spectroscopy, viscosity measurements and low-angle laser light scattering. The data obtained suggest a limited capacity of the polymer structure to expand, resulting from intramolecular self-aggregation and formation of hydrophobic microdomains.

Url:
DOI: 10.1016/0144-8617(91)90055-H

Links to Exploration step

ISTEX:298613BFAF7EE4AC6FFA49FBD95B1BEF1C53A485

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<title>Covalent coupling of a short polyether on sodium alginate: Synthesis and characterization of the resulting amphiphilic derivative</title>
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<name type="personal">
<namePart type="given">Marie-Christiane</namePart>
<namePart type="family">Carré</namePart>
<affiliation>Laboratoire de Chimie Organique, URA CNRS 457, Université de Nancy I, BP 239, 54506 Vandoeuvre les Nancy Cedex, France</affiliation>
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<name type="personal">
<namePart type="given">Christine</namePart>
<namePart type="family">Delestre</namePart>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, URA CNRS 494, ENSIC, BP 451 54001 Nancy Cedex, France</affiliation>
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<name type="personal">
<namePart type="given">Patrick</namePart>
<namePart type="family">Hubert</namePart>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, URA CNRS 494, ENSIC, BP 451 54001 Nancy Cedex, France</affiliation>
<description>To whom correspondence should be addressed.</description>
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<roleTerm type="text">author</roleTerm>
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<name type="personal">
<namePart type="given">Edith</namePart>
<namePart type="family">Dellacherie</namePart>
<affiliation>Laboratoire de Chimie-Physique Macromoléculaire, URA CNRS 494, ENSIC, BP 451 54001 Nancy Cedex, France</affiliation>
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<dateIssued encoding="w3cdtf">1991</dateIssued>
<dateModified encoding="w3cdtf">1990-09-06</dateModified>
<copyrightDate encoding="w3cdtf">1991</copyrightDate>
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<abstract lang="en">Abstract: A covalent sodium alginate-polyoxyethylene model derivative was prepared by reductive amination of aldehydic sodium alginate, in order to obtain a polymer with amphiphilic properties. Characterization of this derivative was carried out by NMR spectroscopy, viscosity measurements and low-angle laser light scattering. The data obtained suggest a limited capacity of the polymer structure to expand, resulting from intramolecular self-aggregation and formation of hydrophobic microdomains.</abstract>
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<title>Carbohydrate Polymers</title>
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<dateIssued encoding="w3cdtf">1991</dateIssued>
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<identifier type="ISSN">0144-8617</identifier>
<identifier type="PII">S0144-8617(00)X0126-9</identifier>
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<date>1991</date>
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<number>16</number>
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<identifier type="DOI">10.1016/0144-8617(91)90055-H</identifier>
<identifier type="PII">0144-8617(91)90055-H</identifier>
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