CphenylH ċ O and CphenylH ċ N Interactions: Crystal Structure of (Z)‐4‐Benzylidene‐2‐methyl‐5(4H)‐oxazolone, an Intermediate for Dehydropeptide Synthesis
Identifieur interne : 000552 ( Istex/Corpus ); précédent : 000551; suivant : 000553CphenylH ċ O and CphenylH ċ N Interactions: Crystal Structure of (Z)‐4‐Benzylidene‐2‐methyl‐5(4H)‐oxazolone, an Intermediate for Dehydropeptide Synthesis
Auteurs : Mohamed Souhassou ; André Aubry ; Guy Boussard ; Michel MarraudSource :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1986-05.
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Abstract
A phenyl ring as proton‐donor to carbonyl oxygen atoms and doubly bonded nitrogen atoms is present in the crystal of the title compound 1. Compound 1 forms almost completely planar “dimers”. These findings are of interest, inter alia, in connection with the conformation of aromatic side chains in peptides.
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DOI: 10.1002/anie.198604471
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<mods version="3.6"><titleInfo lang="en"><title>CphenylH ċ O and CphenylH ċ N Interactions: Crystal Structure of (Z)‐4‐Benzylidene‐2‐methyl‐5(4H)‐oxazolone, an Intermediate for Dehydropeptide Synthesis</title>
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<name type="personal"><namePart type="given">Mohamed</namePart>
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<affiliation>Laboratoire de Minéralogie et Cristallographie, C.N.R.S.‐UA‐809, Université de Nancy I, BP 239, F‐54 506 Vandœuvre (France)</affiliation>
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<affiliation>Correspondence address: Laboratoire de Chimie Physique Macromoléculaire, C.N.R.S.‐UA‐494, ENSIC‐INPL, 1 rue Grandville, F‐54042 Nancy (France)</affiliation>
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<abstract>A phenyl ring as proton‐donor to carbonyl oxygen atoms and doubly bonded nitrogen atoms is present in the crystal of the title compound 1. Compound 1 forms almost completely planar “dimers”. These findings are of interest, inter alia, in connection with the conformation of aromatic side chains in peptides.</abstract>
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