Serveur d'exploration sur le LRGP

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CphenylH ċ O and CphenylH ċ N Interactions: Crystal Structure of (Z)‐4‐Benzylidene‐2‐methyl‐5(4H)‐oxazolone, an Intermediate for Dehydropeptide Synthesis

Identifieur interne : 000552 ( Istex/Corpus ); précédent : 000551; suivant : 000553

CphenylH ċ O and CphenylH ċ N Interactions: Crystal Structure of (Z)‐4‐Benzylidene‐2‐methyl‐5(4H)‐oxazolone, an Intermediate for Dehydropeptide Synthesis

Auteurs : Mohamed Souhassou ; André Aubry ; Guy Boussard ; Michel Marraud

Source :

RBID : ISTEX:5313666957DFB7A6877CCA8EF776265CD7EE776A

English descriptors

Abstract

A phenyl ring as proton‐donor to carbonyl oxygen atoms and doubly bonded nitrogen atoms is present in the crystal of the title compound 1. Compound 1 forms almost completely planar “dimers”. These findings are of interest, inter alia, in connection with the conformation of aromatic side chains in peptides.

Url:
DOI: 10.1002/anie.198604471

Links to Exploration step

ISTEX:5313666957DFB7A6877CCA8EF776265CD7EE776A

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