N -alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media
Identifieur interne : 000448 ( Istex/Corpus ); précédent : 000447; suivant : 000449N -alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media
Auteurs : Abdesselam Benjelloun ; Christine Damas ; Alain Brembilla ; Pierre LochonSource :
- Polymer Bulletin [ 0170-0839 ] ; 1994-10-01.
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Abstract
Summary: We report on the preparation and the characterization of R-alkylated quaternary salts (with RCCH3, C12H25, C16H33, X=Br-) derived from 3-vinylpyridine (3-VP). Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.
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DOI: 10.1007/BF00296158
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ISTEX:0AB2166833F2FA73F9720366D13817EBDD6CBF02Le document en format XML
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aqueous media</title><author xml:id="author-0000"><persName><forename type="first">Abdesselam</forename><surname>Benjelloun</surname></persName><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation></author><author xml:id="author-0001"><persName><forename type="first">Christine</forename><surname>Damas</surname></persName><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation></author><author xml:id="author-0002"><persName><forename type="first">Alain</forename><surname>Brembilla</surname></persName><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation></author><author xml:id="author-0003"><persName><forename 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Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>Chemistry</head><item><term>Polymer Sciences</term></item><item><term>Industrial Chemistry/Chemical Engineering</term></item><item><term>Condensed Matter and Material Sciences</term></item><item><term>Materials Processing, Characterization, and Design</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1994-07-26">Created</change><change when="1994-10-01">Published</change><change xml:id="refBibs-istex" who="#ISTEX-API" when="2017-10-3">References 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media</ArticleTitle><ArticleFirstPage>513</ArticleFirstPage><ArticleLastPage>520</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2004</Year><Month>8</Month><Day>18</Day></RegistrationDate><Received><Year>1994</Year><Month>7</Month><Day>26</Day></Received><Accepted><Year>1994</Year><Month>8</Month><Day>16</Day></Accepted></ArticleHistory><ArticleCopyright><CopyrightHolderName>Springer-Verlag</CopyrightHolderName><CopyrightYear>1994</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant 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INPL</OrgName><OrgAddress><Street>1 Rue Grandville</Street><Postbox>BP 451</Postbox><Postcode>F-54001</Postcode><City>Nancy Cedex</City><Country>France</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Summary</Heading><Para>We report on the preparation and the characterization of R-alkylated quaternary salts (with RCCH<Subscript>3</Subscript>, C<Subscript>12</Subscript>H<Subscript>25</Subscript>, C<Subscript>16</Subscript>H<Subscript>33</Subscript>, X=Br<Superscript>-</Superscript>) derived from 3-vinylpyridine (3-VP). Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.</Para></Abstract></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>N -alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>N-alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media</title></titleInfo><name type="personal"><namePart type="given">Abdesselam</namePart><namePart type="family">Benjelloun</namePart><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Christine</namePart><namePart type="family">Damas</namePart><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Alain</namePart><namePart type="family">Brembilla</namePart><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Pierre</namePart><namePart type="family">Lochon</namePart><affiliation>Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>Springer-Verlag</publisher><place><placeTerm type="text">Berlin/Heidelberg</placeTerm></place><dateCreated encoding="w3cdtf">1994-07-26</dateCreated><dateIssued encoding="w3cdtf">1994-10-01</dateIssued><dateIssued encoding="w3cdtf">1994</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract lang="en">Summary: We report on the preparation and the characterization of R-alkylated quaternary salts (with RCCH3, C12H25, C16H33, X=Br-) derived from 3-vinylpyridine (3-VP). Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.</abstract><relatedItem type="host"><titleInfo><title>Polymer Bulletin</title></titleInfo><titleInfo type="abbreviated"><title>Polymer Bulletin</title></titleInfo><genre type="journal" displayLabel="Archive Journal" authority="ISTEX" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>Springer</publisher><dateIssued encoding="w3cdtf">1994-10-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Polymer Sciences</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Condensed Matter and Material Sciences</topic><topic>Materials Processing, Characterization, and Design</topic></subject><identifier type="ISSN">0170-0839</identifier><identifier type="eISSN">1436-2449</identifier><identifier type="JournalID">289</identifier><identifier type="IssueArticleCount">17</identifier><identifier type="VolumeIssueCount">6</identifier><part><date>1994</date><detail type="volume"><number>33</number><caption>vol.</caption></detail><detail type="issue"><number>5</number><caption>no.</caption></detail><extent unit="pages"><start>513</start><end>520</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></relatedItem><identifier type="istex">0AB2166833F2FA73F9720366D13817EBDD6CBF02</identifier><identifier type="ark">ark:/67375/1BB-CDX93NHN-W</identifier><identifier type="DOI">10.1007/BF00296158</identifier><identifier type="ArticleID">BF00296158</identifier><identifier type="ArticleID">Art3</identifier><accessCondition type="use and reproduction" contentType="copyright">Springer-Verlag, 1994</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</recordContentSource><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/0AB2166833F2FA73F9720366D13817EBDD6CBF02/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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