Analytical resolution of a cyclic two‐way chromatographic binary system
Identifieur interne : 000253 ( Istex/Corpus ); précédent : 000252; suivant : 000254Analytical resolution of a cyclic two‐way chromatographic binary system
Auteurs : C. Castel ; M. Sardin ; M. O. SimonnotSource :
- AIChE Journal [ 0001-1541 ] ; 2002-02.
English descriptors
- KwdEn :
- Aiche, Aiche journal, Analytical solution, Analytical solutions, Asymptotic, Asymptotic concentration profiles, Asymptotic profile, Asymptotic profiles, Binary system, Castel, Chem, Chloride, Chloride composition, Chloride profile, Composition velocity discontinuity, Concentration profile, Concentration profiles, Critical ratio, Cyclic, Dharmashankar subramanian, Discontinuity point, Discrete function, Discrete values, Elution, Elution solution, Elution solutions, Elution step, Elution steps, Equilibrium theory, February, Feed solution, Feed step, First elution step, Flow reversal, Fluoride ions, Full line, Hydrogen carbonate, Iterative calculation, Liquid phase, Local equilibrium theory, Mass balance, Multicomponent, Multicomponent chromatography, Nlimit, Normality, Numerical series, Periodic state, Pressure swing adsorption, Propagation velocity, Saturation step, Scomposition velocity, Selective removal, Sionic fraction, Slongitudinal position, Solid phase, Steady state, Theoretical limit, Thousandth cycle, Tondeur, Total normality.
- Teeft :
- Aiche, Aiche journal, Analytical solution, Analytical solutions, Asymptotic, Asymptotic concentration profiles, Asymptotic profile, Asymptotic profiles, Binary system, Castel, Chem, Chloride, Chloride composition, Chloride profile, Composition velocity discontinuity, Concentration profile, Concentration profiles, Critical ratio, Cyclic, Dharmashankar subramanian, Discontinuity point, Discrete function, Discrete values, Elution, Elution solution, Elution solutions, Elution step, Elution steps, Equilibrium theory, February, Feed solution, Feed step, First elution step, Flow reversal, Fluoride ions, Full line, Hydrogen carbonate, Iterative calculation, Liquid phase, Local equilibrium theory, Mass balance, Multicomponent, Multicomponent chromatography, Nlimit, Normality, Numerical series, Periodic state, Pressure swing adsorption, Propagation velocity, Saturation step, Scomposition velocity, Selective removal, Sionic fraction, Slongitudinal position, Solid phase, Steady state, Theoretical limit, Thousandth cycle, Tondeur, Total normality.
Abstract
The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.
Url:
DOI: 10.1002/aic.690480208
Links to Exploration step
ISTEX:6126A07AC7EC6AAA24F1528F5F63A07350DFADF3Le document en format XML
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Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>cyclic</json:string><json:string>tondeur</json:string><json:string>chem</json:string><json:string>nlimit</json:string><json:string>normality</json:string><json:string>castel</json:string><json:string>elution step</json:string><json:string>multicomponent</json:string><json:string>february</json:string><json:string>equilibrium theory</json:string><json:string>feed solution</json:string><json:string>sionic fraction</json:string><json:string>total normality</json:string><json:string>discontinuity point</json:string><json:string>asymptotic</json:string><json:string>steady state</json:string><json:string>concentration profiles</json:string><json:string>feed step</json:string><json:string>elution solutions</json:string><json:string>saturation step</json:string><json:string>concentration profile</json:string><json:string>binary system</json:string><json:string>aiche</json:string><json:string>chloride composition</json:string><json:string>elution solution</json:string><json:string>pressure swing adsorption</json:string><json:string>chloride profile</json:string><json:string>elution steps</json:string><json:string>asymptotic profile</json:string><json:string>composition velocity discontinuity</json:string><json:string>full line</json:string><json:string>mass balance</json:string><json:string>elution</json:string><json:string>chloride</json:string><json:string>analytical solutions</json:string><json:string>fluoride ions</json:string><json:string>selective removal</json:string><json:string>flow reversal</json:string><json:string>first elution step</json:string><json:string>asymptotic profiles</json:string><json:string>hydrogen carbonate</json:string><json:string>aiche journal</json:string><json:string>theoretical limit</json:string><json:string>numerical series</json:string><json:string>discrete values</json:string><json:string>dharmashankar subramanian</json:string><json:string>critical ratio</json:string><json:string>asymptotic concentration profiles</json:string><json:string>discrete function</json:string><json:string>periodic state</json:string><json:string>iterative calculation</json:string><json:string>thousandth cycle</json:string><json:string>slongitudinal position</json:string><json:string>scomposition velocity</json:string><json:string>local equilibrium theory</json:string><json:string>liquid phase</json:string><json:string>solid phase</json:string><json:string>propagation velocity</json:string><json:string>analytical solution</json:string><json:string>multicomponent chromatography</json:string></teeft></keywords><author><json:item><name>C. Castel</name><affiliations><json:string>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</json:string><json:string>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</json:string></affiliations></json:item><json:item><name>M. Sardin</name><affiliations><json:string>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</json:string></affiliations></json:item><json:item><name>M. O. Simonnot</name><affiliations><json:string>LSGC and EEIGM, F‐54000 Nancy, France</json:string></affiliations></json:item></author><articleId><json:string>AIC690480208</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</abstract><qualityIndicators><score>5.014</score><pdfVersion>1.3</pdfVersion><pdfPageSize>612 x 792 pts (letter)</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>736</abstractCharCount><pdfWordCount>3694</pdfWordCount><pdfCharCount>19233</pdfCharCount><pdfPageCount>7</pdfPageCount><abstractWordCount>110</abstractWordCount></qualityIndicators><title>Analytical resolution of a cyclic two‐way chromatographic binary system</title><genre><json:string>article</json:string></genre><host><title>AIChE Journal</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1547-5905</json:string></doi><issn><json:string>0001-1541</json:string></issn><eissn><json:string>1547-5905</json:string></eissn><publisherId><json:string>AIC</json:string></publisherId><volume>48</volume><issue>2</issue><pages><first>245</first><last>251</last><total>7</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Separation</value></json:item></subject></host><categories><wos><json:string>science</json:string><json:string>engineering, chemical</json:string></wos><scienceMetrix><json:string>applied sciences</json:string><json:string>engineering</json:string><json:string>chemical engineering</json:string></scienceMetrix><inist><json:string>sciences appliquees, technologies et medecines</json:string><json:string>sciences exactes et technologie</json:string><json:string>chimie</json:string><json:string>chimie analytique</json:string></inist></categories><publicationDate>2002</publicationDate><copyrightDate>2002</copyrightDate><doi><json:string>10.1002/aic.690480208</json:string></doi><id>6126A07AC7EC6AAA24F1528F5F63A07350DFADF3</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Analytical resolution of a cyclic two‐way chromatographic binary system</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>Hoboken</pubPlace><availability><licence>Copyright © 2002 American Institute of Chemical Engineers (AIChE)</licence></availability><date type="published" when="2002-02"></date></publicationStmt><notesStmt><note type="content-type" subtype="article" source="article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="article"><analytic><title level="a" type="main" xml:lang="en">Analytical resolution of a cyclic two‐way chromatographic binary system</title><title level="a" type="short" xml:lang="en">Analytical Resolution of a Cyclic Two‐Way Chromatographic Binary System</title><author xml:id="author-0000" role="corresp"><persName><forename type="first">C.</forename><surname>Castel</surname></persName><affiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France<address><country key="FR"></country></address></affiliation><affiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</affiliation></author><author xml:id="author-0001"><persName><forename type="first">M.</forename><surname>Sardin</surname></persName><affiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">M. O.</forename><surname>Simonnot</surname></persName><affiliation>LSGC and EEIGM, F‐54000 Nancy, France<address><country key="FR"></country></address></affiliation></author><idno type="istex">6126A07AC7EC6AAA24F1528F5F63A07350DFADF3</idno><idno type="ark">ark:/67375/WNG-09LR54SH-C</idno><idno type="DOI">10.1002/aic.690480208</idno><idno type="unit">AIC690480208</idno><idno type="toTypesetVersion">file:AIC.AIC690480208.pdf</idno></analytic><monogr><title level="j" type="main">AIChE Journal</title><title level="j" type="alt">AICHE JOURNAL</title><idno type="pISSN">0001-1541</idno><idno type="eISSN">1547-5905</idno><idno type="book-DOI">10.1002/(ISSN)1547-5905</idno><idno type="book-part-DOI">10.1002/aic.v48:2</idno><idno type="product">AIC</idno><imprint><biblScope unit="vol">48</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="245">245</biblScope><biblScope unit="page" to="251">251</biblScope><biblScope unit="page-count">7</biblScope><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>Hoboken</pubPlace><date type="published" when="2002-02"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</p></abstract><textClass><keywords rend="articleCategory"><term>Separation</term></keywords><keywords rend="tocHeading1"><term>Separations</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Wiley Subscription Services, Inc., A Wiley Company</publisherName><publisherLoc>Hoboken</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1547-5905</doi><issn type="print">0001-1541</issn><issn type="electronic">1547-5905</issn><idGroup><id type="product" value="AIC"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="AICHE JOURNAL">AIChE Journal</title><title type="short">AIChE J.</title></titleGroup></publicationMeta><publicationMeta level="part" position="20"><doi origin="wiley" registered="yes">10.1002/aic.v48:2</doi><numberingGroup><numbering type="journalVolume" number="48">48</numbering><numbering type="journalIssue">2</numbering></numberingGroup><coverDate startDate="2002-02">February 2002</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="8" status="forIssue"><doi origin="wiley" registered="yes">10.1002/aic.690480208</doi><idGroup><id type="unit" value="AIC690480208"></id></idGroup><countGroup><count type="pageTotal" number="7"></count></countGroup><titleGroup><title type="articleCategory">Separation</title><title type="tocHeading1">Separations</title></titleGroup><copyright ownership="thirdParty">Copyright © 2002 American Institute of Chemical Engineers (AIChE)</copyright><eventGroup><event type="manuscriptReceived" date="2000-06-15"></event><event type="manuscriptRevised" date="2001-08-01"></event><event type="firstOnline" date="2004-04-16"></event><event type="publishedOnlineFinalForm" date="2004-04-16"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.2 mode:FullText source:HeaderRef result:HeaderRef" date="2010-03-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-01"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">245</numbering><numbering type="pageLast">251</numbering></numberingGroup><correspondenceTo>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:AIC.AIC690480208.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="6"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="18"></count></countGroup><titleGroup><title type="main" xml:lang="en">Analytical resolution of a cyclic two‐way chromatographic binary system</title><title type="short" xml:lang="en">Analytical Resolution of a Cyclic Two‐Way Chromatographic Binary System</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><givenNames>C.</givenNames><familyName>Castel</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>M.</givenNames><familyName>Sardin</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af2"><personName><givenNames>M. O.</givenNames><familyName>Simonnot</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>LSGC and EEIGM, F‐54000 Nancy, France</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Analytical resolution of a cyclic two‐way chromatographic binary system</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Analytical Resolution of a Cyclic Two‐Way Chromatographic Binary System</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Analytical resolution of a cyclic two‐way chromatographic binary system</title></titleInfo><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Castel</namePart><affiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</affiliation><affiliation>Correspondence address: LSGC‐CNRS‐INPL, F‐54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Sardin</namePart><affiliation>LSGC‐CNRS‐INPL, F‐54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M. O.</namePart><namePart type="family">Simonnot</namePart><affiliation>LSGC and EEIGM, F‐54000 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><place><placeTerm type="text">Hoboken</placeTerm></place><dateIssued encoding="w3cdtf">2002-02</dateIssued><dateCaptured encoding="w3cdtf">2000-06-15</dateCaptured><copyrightDate encoding="w3cdtf">2002</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">6</extent><extent unit="tables">1</extent><extent unit="references">18</extent></physicalDescription><abstract lang="en">The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</abstract><relatedItem type="host"><titleInfo><title>AIChE Journal</title></titleInfo><titleInfo type="abbreviated"><title>AIChE J.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Separation</topic></subject><identifier type="ISSN">0001-1541</identifier><identifier type="eISSN">1547-5905</identifier><identifier type="DOI">10.1002/(ISSN)1547-5905</identifier><identifier type="PublisherID">AIC</identifier><part><date>2002</date><detail type="volume"><caption>vol.</caption><number>48</number></detail><detail type="issue"><caption>no.</caption><number>2</number></detail><extent unit="pages"><start>245</start><end>251</end><total>7</total></extent></part></relatedItem><identifier type="istex">6126A07AC7EC6AAA24F1528F5F63A07350DFADF3</identifier><identifier type="ark">ark:/67375/WNG-09LR54SH-C</identifier><identifier type="DOI">10.1002/aic.690480208</identifier><identifier type="ArticleID">AIC690480208</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2002 American Institute of Chemical Engineers (AIChE)</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Wiley Subscription Services, Inc., A Wiley Company</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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