Mixed Crossed Aldol Condensation between Conjugated Esters and Aldehydes Using Aluminum Tris(2,6‐diphenylphenoxide)
Identifieur interne : 000247 ( Istex/Corpus ); précédent : 000246; suivant : 000248Mixed Crossed Aldol Condensation between Conjugated Esters and Aldehydes Using Aluminum Tris(2,6‐diphenylphenoxide)
Auteurs : Susumu Saito ; Masahito Shiozawa ; Hisashi YamamotoSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 1999-06-14.
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Abstract
The combined use of aluminum tris(2,6‐diphenylphenoxide) (ATPH) and lithium 2,2,6,6‐tetramethylpiperidide (LTMP) has proven to be effective for the mixed crossed aldol condensation between conjugated esters and various aldehydes. An example is shown in Equation (1).
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DOI: 10.1002/(SICI)1521-3773(19990614)38:12<1769::AID-ANIE1769>3.0.CO;2-0
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<front><div type="abstract">The combined use of aluminum tris(2,6‐diphenylphenoxide) (ATPH) and lithium 2,2,6,6‐tetramethylpiperidide (LTMP) has proven to be effective for the mixed crossed aldol condensation between conjugated esters and various aldehydes. An example is shown in Equation (1).</div>
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<name type="personal"><namePart type="given">Susumu</namePart>
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<affiliation>Graduate School of Engineering, Nagoya University, CREST, Japan Science (and) Technology Corporation (JST), Furo‐cho, Chikusa, Nagoya 464‐8603 (Japan), Fax: (+81) 52‐789‐3222</affiliation>
<role><roleTerm type="text">author</roleTerm>
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<name type="personal"><namePart type="given">Masahito</namePart>
<namePart type="family">Shiozawa</namePart>
<affiliation>Graduate School of Engineering, Nagoya University, CREST, Japan Science (and) Technology Corporation (JST), Furo‐cho, Chikusa, Nagoya 464‐8603 (Japan), Fax: (+81) 52‐789‐3222</affiliation>
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</name>
<name type="personal"><namePart type="given">Hisashi</namePart>
<namePart type="family">Yamamoto</namePart>
<affiliation>E-mail: j45988a@nucc.cc.nagoya‐u.ac.jp</affiliation>
<affiliation>Graduate School of Engineering, Nagoya University, CREST, Japan Science (and) Technology Corporation (JST), Furo‐cho, Chikusa, Nagoya 464‐8603 (Japan), Fax: (+81) 52‐789‐3222</affiliation>
<affiliation>E-mail: j45988a@nucc.cc.nagoya‐u.ac.jp</affiliation>
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<dateIssued encoding="w3cdtf">1999-06-14</dateIssued>
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<physicalDescription><extent unit="figures">3</extent>
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<extent unit="references">9</extent>
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<abstract>The combined use of aluminum tris(2,6‐diphenylphenoxide) (ATPH) and lithium 2,2,6,6‐tetramethylpiperidide (LTMP) has proven to be effective for the mixed crossed aldol condensation between conjugated esters and various aldehydes. An example is shown in Equation (1).</abstract>
<subject lang="en"><genre>keywords</genre>
<topic>Aldol reactions</topic>
<topic>C−C coupling</topic>
<topic>Cross‐coupling</topic>
<topic>Enols</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title>
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<titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title>
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<subject><genre>article-category</genre>
<topic>Communication</topic>
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<identifier type="ISSN">1433-7851</identifier>
<identifier type="eISSN">1521-3773</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3773</identifier>
<identifier type="PublisherID">ANIE</identifier>
<part><date>1999</date>
<detail type="volume"><caption>vol.</caption>
<number>38</number>
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<detail type="issue"><caption>no.</caption>
<number>12</number>
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<extent unit="pages"><start>1769</start>
<end>1771</end>
<total>3</total>
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<identifier type="DOI">10.1002/(SICI)1521-3773(19990614)38:12<1769::AID-ANIE1769>3.0.CO;2-0</identifier>
<identifier type="ArticleID">ANIE1769</identifier>
<accessCondition type="use and reproduction" contentType="copyright">© 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</accessCondition>
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