Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids
Identifieur interne : 000481 ( Hal/Curation ); précédent : 000480; suivant : 000482Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids
Auteurs : Zehor Bensaid [Algérie] ; Fabrice Mutelet [France] ; Mohammed Bouroukba [France] ; Amina Negadi [Algérie]Source :
- Fluid Phase Equilibria [ 0378-3812 ] ; 2014-09.
Abstract
Activity coefficients at infinite dilution (gamma(infinity)(1,2)) for diverse probe solutes in three homologous 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids were measured by inverse gas chromatography at temperatures from 323 to 343 K. Accordingly, this family of ionic liquid can be ranked according to their interaction with organic compounds as follows: [HSO4] << [OTf] << [N(Tf)(2)]. The retention data were further converted to gas-to-IL and analyzed using the Abraham solvation parameter model. The LSER treatment indicates that the most dominant interaction constants for this family of ILs are strong dipolarity, hydrogen bond basicity and acidity. Then, the ChelpG atomic charges on the cation and the anions obtained by ab initio calculations are used to explain the interactions between methanol, thiophene and benzene and the anions or the cation.
Url:
DOI: 10.1016/j.fluid.2014.06.021
Links toward previous steps (curation, corpus...)
- to stream Hal, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000481
Links to Exploration step
Hal:hal-01274183Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids</title>
<author><name sortKey="Bensaid, Zehor" sort="Bensaid, Zehor" uniqKey="Bensaid Z" first="Zehor" last="Bensaid">Zehor Bensaid</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-236930" status="INCOMING"><orgName>Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire</orgName>
<orgName type="acronym">LATA2M</orgName>
<desc><address><addrLine>P.O. Box 119, Tlemcen 13000</addrLine>
<country key="DZ"></country>
</address>
</desc>
<listRelation><relation active="#struct-300843" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300843" type="direct"><org type="institution" xml:id="struct-300843" status="VALID"><orgName>Université Abou Bekr Belkaid Tlemcen</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>Algérie</country>
</affiliation>
</author>
<author><name sortKey="Mutelet, Fabrice" sort="Mutelet, Fabrice" uniqKey="Mutelet F" first="Fabrice" last="Mutelet">Fabrice Mutelet</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Bouroukba, Mohammed" sort="Bouroukba, Mohammed" uniqKey="Bouroukba M" first="Mohammed" last="Bouroukba">Mohammed Bouroukba</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Negadi, Amina" sort="Negadi, Amina" uniqKey="Negadi A" first="Amina" last="Negadi">Amina Negadi</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-236930" status="INCOMING"><orgName>Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire</orgName>
<orgName type="acronym">LATA2M</orgName>
<desc><address><addrLine>P.O. Box 119, Tlemcen 13000</addrLine>
<country key="DZ"></country>
</address>
</desc>
<listRelation><relation active="#struct-300843" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300843" type="direct"><org type="institution" xml:id="struct-300843" status="VALID"><orgName>Université Abou Bekr Belkaid Tlemcen</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>Algérie</country>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">HAL</idno>
<idno type="RBID">Hal:hal-01274183</idno>
<idno type="halId">hal-01274183</idno>
<idno type="halUri">https://hal.univ-lorraine.fr/hal-01274183</idno>
<idno type="url">https://hal.univ-lorraine.fr/hal-01274183</idno>
<idno type="doi">10.1016/j.fluid.2014.06.021</idno>
<date when="2014-09">2014-09</date>
<idno type="wicri:Area/Hal/Corpus">000481</idno>
<idno type="wicri:Area/Hal/Curation">000481</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids</title>
<author><name sortKey="Bensaid, Zehor" sort="Bensaid, Zehor" uniqKey="Bensaid Z" first="Zehor" last="Bensaid">Zehor Bensaid</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-236930" status="INCOMING"><orgName>Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire</orgName>
<orgName type="acronym">LATA2M</orgName>
<desc><address><addrLine>P.O. Box 119, Tlemcen 13000</addrLine>
<country key="DZ"></country>
</address>
</desc>
<listRelation><relation active="#struct-300843" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300843" type="direct"><org type="institution" xml:id="struct-300843" status="VALID"><orgName>Université Abou Bekr Belkaid Tlemcen</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>Algérie</country>
</affiliation>
</author>
<author><name sortKey="Mutelet, Fabrice" sort="Mutelet, Fabrice" uniqKey="Mutelet F" first="Fabrice" last="Mutelet">Fabrice Mutelet</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Bouroukba, Mohammed" sort="Bouroukba, Mohammed" uniqKey="Bouroukba M" first="Mohammed" last="Bouroukba">Mohammed Bouroukba</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>France</country>
<placeName><settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
<author><name sortKey="Negadi, Amina" sort="Negadi, Amina" uniqKey="Negadi A" first="Amina" last="Negadi">Amina Negadi</name>
<affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-236930" status="INCOMING"><orgName>Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire</orgName>
<orgName type="acronym">LATA2M</orgName>
<desc><address><addrLine>P.O. Box 119, Tlemcen 13000</addrLine>
<country key="DZ"></country>
</address>
</desc>
<listRelation><relation active="#struct-300843" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-300843" type="direct"><org type="institution" xml:id="struct-300843" status="VALID"><orgName>Université Abou Bekr Belkaid Tlemcen</orgName>
<desc><address><country key="FR"></country>
</address>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>Algérie</country>
</affiliation>
</author>
</analytic>
<idno type="DOI">10.1016/j.fluid.2014.06.021</idno>
<series><title level="j">Fluid Phase Equilibria</title>
<idno type="ISSN">0378-3812</idno>
<imprint><date type="datePub">2014-09</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Activity coefficients at infinite dilution (gamma(infinity)(1,2)) for diverse probe solutes in three homologous 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids were measured by inverse gas chromatography at temperatures from 323 to 343 K. Accordingly, this family of ionic liquid can be ranked according to their interaction with organic compounds as follows: [HSO4] << [OTf] << [N(Tf)(2)]. The retention data were further converted to gas-to-IL and analyzed using the Abraham solvation parameter model. The LSER treatment indicates that the most dominant interaction constants for this family of ILs are strong dipolarity, hydrogen bond basicity and acidity. Then, the ChelpG atomic charges on the cation and the anions obtained by ab initio calculations are used to explain the interactions between methanol, thiophene and benzene and the anions or the cation.</div>
</front>
</TEI>
<hal api="V3"><titleStmt><title xml:lang="en">Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids</title>
<author role="aut"><persName><forename type="first">Zehor</forename>
<surname>Bensaid</surname>
</persName>
<email></email>
<idno type="halauthor">1293857</idno>
<affiliation ref="#struct-236930"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Fabrice</forename>
<surname>Mutelet</surname>
</persName>
<email></email>
<idno type="halauthor">994778</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Mohammed</forename>
<surname>Bouroukba</surname>
</persName>
<email></email>
<idno type="halauthor">850078</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Amina</forename>
<surname>Negadi</surname>
</persName>
<email></email>
<idno type="halauthor">905100</idno>
<affiliation ref="#struct-236930"></affiliation>
</author>
<editor role="depositor"><persName><forename>LRGP</forename>
<surname>UL</surname>
</persName>
<email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email>
</editor>
</titleStmt>
<editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2016-02-15 15:29:13</date>
<date type="whenModified">2016-05-10 16:53:48</date>
<date type="whenReleased">2016-02-15 15:29:13</date>
<date type="whenProduced">2014-09</date>
</edition>
<respStmt><resp>contributor</resp>
<name key="329568"><persName><forename>LRGP</forename>
<surname>UL</surname>
</persName>
<email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email>
</name>
</respStmt>
</editionStmt>
<publicationStmt><distributor>CCSD</distributor>
<idno type="halId">hal-01274183</idno>
<idno type="halUri">https://hal.univ-lorraine.fr/hal-01274183</idno>
<idno type="halBibtex">bensaid:hal-01274183</idno>
<idno type="halRefHtml">Fluid Phase Equilibria, Elsevier, 2014, 378, pp.34-43. <10.1016/j.fluid.2014.06.021></idno>
<idno type="halRef">Fluid Phase Equilibria, Elsevier, 2014, 378, pp.34-43. <10.1016/j.fluid.2014.06.021></idno>
</publicationStmt>
<seriesStmt><idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno>
<idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
<idno type="stamp" n="LRGP-UL">LRGP</idno>
</seriesStmt>
<notesStmt><note type="audience" n="2">International</note>
<note type="popular" n="0">No</note>
<note type="peer" n="1">Yes</note>
</notesStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids</title>
<author role="aut"><persName><forename type="first">Zehor</forename>
<surname>Bensaid</surname>
</persName>
<idno type="halAuthorId">1293857</idno>
<affiliation ref="#struct-236930"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Fabrice</forename>
<surname>Mutelet</surname>
</persName>
<idno type="halAuthorId">994778</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Mohammed</forename>
<surname>Bouroukba</surname>
</persName>
<idno type="halAuthorId">850078</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Amina</forename>
<surname>Negadi</surname>
</persName>
<idno type="halAuthorId">905100</idno>
<affiliation ref="#struct-236930"></affiliation>
</author>
</analytic>
<monogr><idno type="halJournalId" status="VALID">13383</idno>
<idno type="issn">0378-3812</idno>
<title level="j">Fluid Phase Equilibria</title>
<imprint><publisher>Elsevier</publisher>
<biblScope unit="volume">378</biblScope>
<biblScope unit="pp">34-43</biblScope>
<date type="datePub">2014-09</date>
</imprint>
</monogr>
<idno type="doi">10.1016/j.fluid.2014.06.021</idno>
</biblStruct>
</sourceDesc>
<profileDesc><langUsage><language ident="en">English</language>
</langUsage>
<textClass><classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
<classCode scheme="halTypology" n="ART">Journal articles</classCode>
</textClass>
<abstract xml:lang="en">Activity coefficients at infinite dilution (gamma(infinity)(1,2)) for diverse probe solutes in three homologous 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids were measured by inverse gas chromatography at temperatures from 323 to 343 K. Accordingly, this family of ionic liquid can be ranked according to their interaction with organic compounds as follows: [HSO4] << [OTf] << [N(Tf)(2)]. The retention data were further converted to gas-to-IL and analyzed using the Abraham solvation parameter model. The LSER treatment indicates that the most dominant interaction constants for this family of ILs are strong dipolarity, hydrogen bond basicity and acidity. Then, the ChelpG atomic charges on the cation and the anions obtained by ab initio calculations are used to explain the interactions between methanol, thiophene and benzene and the anions or the cation.</abstract>
</profileDesc>
</hal>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Hal/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000481 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Hal/Curation/biblio.hfd -nk 000481 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Lorraine |area= LrgpV1 |flux= Hal |étape= Curation |type= RBID |clé= Hal:hal-01274183 |texte= Experimental and theoretical study of interaction between organic compounds and 1-(4-sulfobutyl)-3-methylimidazolium based ionic liquids }}
This area was generated with Dilib version V0.6.32. |