Conformational Analysis and Chromic Acid Oxidation. Oxidation Rates and Equilibrium Constants of Epimeric Alcohols
Identifieur interne : 002256 ( Istex/Curation ); précédent : 002255; suivant : 002257Conformational Analysis and Chromic Acid Oxidation. Oxidation Rates and Equilibrium Constants of Epimeric Alcohols
Auteurs : Paul Müller [Suisse] ; Jean-Claude Perlberger [Suisse]Source :
- Helvetica Chimica Acta [ 0018-019X ] ; 1976-11-03.
English descriptors
- Teeft :
- Acetic acid, Acta, Alcohol oxidation, Amer, Chem, Chimica, Chromic acid oxidation, Column ffap, Correlation coefficient, Eliel, Energy diagram, Epimeric, Epimeric alcohols, Equilibrium constants, Fasc, Helvetica, Helvetica chimica acta, Isotope effect, Isotope effects, Lower limit, Oxidation rates, Rate constants, Regression line, Sicher, Sicher correlation, Sicher plot, Standard deviation, Strain difference, Tlie, Transition state, Transition states.
Abstract
The linear free energy relationship of Sicher for relative reactivity towards chromic acid oxidation (ΔΔG Ox≠) as a function of thermodynamic stability (ΔG eq0) has been reexamined with 23 pairs of epimeric alcohols. The plot of ΔG Ox≠ vs. ΔG eq0 has a slope of 0.8, a correlation coefficient of 0.97 and a standard deviation of 0.23 kcal/mol on ΔΔGOx Ox≠. The limitations of the relationship and the exceptions are discussed.
Url:
DOI: 10.1002/hlca.19760590706
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Oxidation Rates and Equilibrium Constants of Epimeric Alcohols</title><author><name sortKey="Muller, Paul" sort="Muller, Paul" uniqKey="Muller P" first="Paul" last="Müller">Paul Müller</name><affiliation wicri:level="4"><mods:affiliation>Département de Chimie Organique, Université de Genève, 1211 Genève 4</mods:affiliation><orgName type="university">Université de Genève</orgName><country>Suisse</country><placeName><settlement type="city">Genève</settlement><region nuts="3" type="region">Canton de Genève</region></placeName></affiliation></author><author><name sortKey="Perlberger, Jean Laude" sort="Perlberger, Jean Laude" uniqKey="Perlberger J" first="Jean-Claude" last="Perlberger">Jean-Claude Perlberger</name><affiliation wicri:level="4"><mods:affiliation>Département de Chimie Organique, Université de Genève, 1211 Genève 4</mods:affiliation><orgName type="university">Université de Genève</orgName><country>Suisse</country><placeName><settlement type="city">Genève</settlement><region nuts="3" type="region">Canton de Genève</region></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Helvetica Chimica Acta</title><title level="j" type="alt">HELVETICA CHIMICA ACTA</title><idno type="ISSN">0018-019X</idno><idno type="eISSN">1522-2675</idno><imprint><biblScope unit="vol">59</biblScope><biblScope unit="issue">7</biblScope><biblScope unit="page" from="2335">2335</biblScope><biblScope unit="page" to="2343">2343</biblScope><biblScope unit="page-count">9</biblScope><publisher>WILEY‐VCH Verlag GmbH</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="1976-11-03">1976-11-03</date></imprint><idno type="ISSN">0018-019X</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0018-019X</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Acetic acid</term><term>Acta</term><term>Alcohol oxidation</term><term>Amer</term><term>Chem</term><term>Chimica</term><term>Chromic acid oxidation</term><term>Column ffap</term><term>Correlation coefficient</term><term>Eliel</term><term>Energy diagram</term><term>Epimeric</term><term>Epimeric alcohols</term><term>Equilibrium constants</term><term>Fasc</term><term>Helvetica</term><term>Helvetica chimica acta</term><term>Isotope effect</term><term>Isotope effects</term><term>Lower limit</term><term>Oxidation rates</term><term>Rate constants</term><term>Regression line</term><term>Sicher</term><term>Sicher correlation</term><term>Sicher plot</term><term>Standard deviation</term><term>Strain difference</term><term>Tlie</term><term>Transition state</term><term>Transition states</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The linear free energy relationship of Sicher for relative reactivity towards chromic acid oxidation (ΔΔG Ox≠) as a function of thermodynamic stability (ΔG eq0) has been reexamined with 23 pairs of epimeric alcohols. The plot of ΔG Ox≠ vs. ΔG eq0 has a slope of 0.8, a correlation coefficient of 0.97 and a standard deviation of 0.23 kcal/mol on ΔΔGOx Ox≠. The limitations of the relationship and the exceptions are discussed.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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