Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses
Identifieur interne : 001F93 ( Istex/Corpus ); précédent : 001F92; suivant : 001F94Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses
Auteurs : Xingfa Ma ; Guang Li ; Mang Wang ; Hongzheng ChenSource :
- Journal of Materials Science [ 0022-2461 ] ; 2006-11-01.
Abstract
Abstract: To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.
Url:
DOI: 10.1007/s10853-006-0849-2
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Abstract: To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.</div>
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<Para>To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10<Superscript>−1 </Superscript>
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<affiliation>E-mail: xingfamazju@yahoo.com.cn</affiliation>
<role><roleTerm type="text">author</roleTerm>
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<name type="personal"><namePart type="given">Guang</namePart>
<namePart type="family">Li</namePart>
<affiliation>Institute of Biomedical and Instrument Science, State Key Lab of Biosensors, Zhejiang University, 310027, Hangzhou, P.R. China</affiliation>
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<name type="personal"><namePart type="given">Mang</namePart>
<namePart type="family">Wang</namePart>
<affiliation>Department of Polymer Science & Engineering, State Key Lab of Silicon Materials, Zhejiang University, 310027, Hangzhou, P.R. China</affiliation>
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<name type="personal"><namePart type="given">Hongzheng</namePart>
<namePart type="family">Chen</namePart>
<affiliation>Department of Polymer Science & Engineering, State Key Lab of Silicon Materials, Zhejiang University, 310027, Hangzhou, P.R. China</affiliation>
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<originInfo><publisher>Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com</publisher>
<place><placeTerm type="text">New York</placeTerm>
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<dateCreated encoding="w3cdtf">2005-08-19</dateCreated>
<dateIssued encoding="w3cdtf">2006-11-01</dateIssued>
<copyrightDate encoding="w3cdtf">2006</copyrightDate>
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<abstract lang="en">Abstract: To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.</abstract>
<relatedItem type="host"><titleInfo><title>Journal of Materials Science</title>
</titleInfo>
<titleInfo type="abbreviated"><title>J Mater Sci</title>
</titleInfo>
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<originInfo><publisher>Springer</publisher>
<dateIssued encoding="w3cdtf">2006-11-27</dateIssued>
<copyrightDate encoding="w3cdtf">2006</copyrightDate>
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<subject><genre>Chemistry</genre>
<topic>Mechanics</topic>
<topic>Crystallography</topic>
<topic>Continuum Mechanics and Mechanics of Materials</topic>
<topic>Polymer Sciences</topic>
<topic>Characterization and Evaluation Materials</topic>
<topic>Materials Science</topic>
</subject>
<identifier type="ISSN">0022-2461</identifier>
<identifier type="eISSN">1573-4803</identifier>
<identifier type="JournalID">10853</identifier>
<identifier type="IssueArticleCount">54</identifier>
<identifier type="VolumeIssueCount">24</identifier>
<part><date>2006</date>
<detail type="volume"><number>41</number>
<caption>vol.</caption>
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<detail type="issue"><number>22</number>
<caption>no.</caption>
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<extent unit="pages"><start>7604</start>
<end>7610</end>
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<identifier type="ark">ark:/67375/VQC-CGKZKDL5-F</identifier>
<identifier type="DOI">10.1007/s10853-006-0849-2</identifier>
<identifier type="ArticleID">849</identifier>
<identifier type="ArticleID">s10853-006-0849-2</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Springer Science+Business Media, LLC, 2006</accessCondition>
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