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Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses

Identifieur interne : 001F93 ( Istex/Corpus ); précédent : 001F92; suivant : 001F94

Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses

Auteurs : Xingfa Ma ; Guang Li ; Mang Wang ; Hongzheng Chen

Source :

RBID : ISTEX:8A04DDBC2219AA2C4AF18BEF413952B2820880BF

Abstract

Abstract: To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.

Url:
DOI: 10.1007/s10853-006-0849-2

Links to Exploration step

ISTEX:8A04DDBC2219AA2C4AF18BEF413952B2820880BF

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<Para>To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10
<Superscript>−1 </Superscript>
mol/m
<Superscript>3</Superscript>
, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N
<Subscript>2 </Subscript>
at room temperature.</Para>
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<affiliation>Shandong Research Institute of Non-metallic Materials, 250031, Jinan, P.R. China</affiliation>
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<abstract lang="en">Abstract: To overcome the problem of film-forming technology, water-soluble polypyrrole was obtained in the process of chemical oxide by adding a small amount of poly (sodium-p-styrenesulfonate). The resulting product PPy/Poly(sodium-p-styrene sulfonat) was coated on the interdigital electrodes of carbon via spin-coating or casting approach, and its gas-sensitivity to trimethylamine at room temperature was investigated. The results indicated that, the technology of film-forming was not only improved greatly, but also this film still showed good gas-sensitivity to trimethylamine of 3.189 × 10−1 mol/m3, its value of gas-sensitivity had reached to 2–3 orders of magnitude within 3 min, had good selectivity to analogy gases, and its resistance to moisture was improved obviously. Otherwise, this film also exhibited good reproducibility and stability, and easily recovered with high-purity N2 at room temperature.</abstract>
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