Effect of silanized silica nanofiller on tack and green strength of selected filled rubbers
Identifieur interne : 000902 ( Main/Merge ); précédent : 000901; suivant : 000903Effect of silanized silica nanofiller on tack and green strength of selected filled rubbers
Auteurs : Saeed Ostad Movahed [Royaume-Uni] ; Ali Ansarifar [Royaume-Uni] ; Mo Song [Royaume-Uni]Source :
- Polymer International [ 0959-8103 ] ; 2009-04.
English descriptors
- Entity :
- org : CRC Press, International Scienti, Degussa Ltd, Hanau, Germany, Institute of Polymer Technology and Materials, Loughborough University, Loughborough, Ministry of Technology, Polimeri Europa UK Ltd, Wallace Instruments.
- pers : Degussa Limited, Mo, S.Ostad-Movahed, Van Beek.
- place : Amsterdam, Berlin, Cheshire, Cleveland, Germany, OH, UK, York.
- Teeft :
- Adhesion, Ambient temperature, Appl polym, Bond formation, Carbon black, Chem, Contact flow, Contact time, Coupsil, Different loading, Different rubber, Different silanized silica nanofiller loading, Filler, Filler loading, Filler particle, Green strength, Intimate contact, Loading, Matrix, Mooney, Mooney viscosity, Nanofiller, Optimum filler loading, Ostad movahed, Physical bond, Polym, Polymer, Polymer chain, Polymer chain mobility, Rubber, Rubber chem technol, Rubber matrix, Silanized, Silanized silica nanofiller, Silanized silica nanofiller loading, Silica, Silica particle, Strong bond, Tack, Tack strength, Technol, Test temperature.
Abstract
BACKGROUND: Tack and green strength of filled and gum (unfilled) natural rubber (NR), poly(styrene‐co‐butadiene) rubber (SBR), polybutadiene rubber (BR) and (SBR‐BR) blend with different loadings of reinforcement agent, silanized silica nanofiller (Coupsil 8113), were studied and the results compared and discussed. RESULTS: It was found that silica was fully dispersed in rubber matrix after 13 min of mixing. In addition, with some exceptions for NR and (SBR‐BR) blend, filler loading decreased the tack strength of the studied filled rubbers. Green strength and Mooney viscosity increased with filler loading for all studied filled rubbers but with different rates and amounts. The optimum filler loadings for NR and (SBR‐BR) filled blend were 30 and 10 phr, respectively. Tacks of NR filled rubbers were much higher than those of synthetic filled rubbers. CONCLUSION: It was concluded that filler loading alters substantially the tack and green strength of the rubbers under investigation. Copyright © 2009 Society of Chemical Industry
Url:
DOI: 10.1002/pi.2554
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ISTEX:0615678F3CD2932FE39A5B51F4474C5F05D901A7Le document en format XML
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<term>Germany</term>
<term>OH</term>
<term>UK</term>
<term>York</term>
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<keywords scheme="Teeft" xml:lang="en"><term>Adhesion</term>
<term>Ambient temperature</term>
<term>Appl polym</term>
<term>Bond formation</term>
<term>Carbon black</term>
<term>Chem</term>
<term>Contact flow</term>
<term>Contact time</term>
<term>Coupsil</term>
<term>Different loading</term>
<term>Different rubber</term>
<term>Different silanized silica nanofiller loading</term>
<term>Filler</term>
<term>Filler loading</term>
<term>Filler particle</term>
<term>Green strength</term>
<term>Intimate contact</term>
<term>Loading</term>
<term>Matrix</term>
<term>Mooney</term>
<term>Mooney viscosity</term>
<term>Nanofiller</term>
<term>Optimum filler loading</term>
<term>Ostad movahed</term>
<term>Physical bond</term>
<term>Polym</term>
<term>Polymer</term>
<term>Polymer chain</term>
<term>Polymer chain mobility</term>
<term>Rubber</term>
<term>Rubber chem technol</term>
<term>Rubber matrix</term>
<term>Silanized</term>
<term>Silanized silica nanofiller</term>
<term>Silanized silica nanofiller loading</term>
<term>Silica</term>
<term>Silica particle</term>
<term>Strong bond</term>
<term>Tack</term>
<term>Tack strength</term>
<term>Technol</term>
<term>Test temperature</term>
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<front><div type="abstract" xml:lang="en">BACKGROUND: Tack and green strength of filled and gum (unfilled) natural rubber (NR), poly(styrene‐co‐butadiene) rubber (SBR), polybutadiene rubber (BR) and (SBR‐BR) blend with different loadings of reinforcement agent, silanized silica nanofiller (Coupsil 8113), were studied and the results compared and discussed. RESULTS: It was found that silica was fully dispersed in rubber matrix after 13 min of mixing. In addition, with some exceptions for NR and (SBR‐BR) blend, filler loading decreased the tack strength of the studied filled rubbers. Green strength and Mooney viscosity increased with filler loading for all studied filled rubbers but with different rates and amounts. The optimum filler loadings for NR and (SBR‐BR) filled blend were 30 and 10 phr, respectively. Tacks of NR filled rubbers were much higher than those of synthetic filled rubbers. CONCLUSION: It was concluded that filler loading alters substantially the tack and green strength of the rubbers under investigation. Copyright © 2009 Society of Chemical Industry</div>
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