UnivTrevesV1, PascalFrancis, Corpus, bibRecord, 001649

Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection

Identifieur interne : 001649 ( PascalFrancis/Corpus ); précédent : 001648; suivant : 001650

Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection

Auteurs : G. Henze ; A. Meyer ; J. Hausen

Source :

Fresenius' journal of analytical chemistry [ 0937-0633 ] ; 1993.

RBID : Pascal:93-0570648

Descripteurs français

Pascal (Inist)
- Analyse chimique, Analyse trace, Chromatographie phase inverse, Chromatographie HPLC, Ampérométrie, Spectrométrie UV visible, Etat adsorbé, Enrichissement chimique, Herbicide, Métabolite, Urées, Chlore Composé organique, Eau, Sol, Linuron, Ultratrace.

English descriptors

KwdEn :
- Adsorbed state, Amperometry, Chemical analysis, Chemical enrichment, Chlorine Organic compounds, HPLC chromatography, Herbicide, Metabolite, Reversed phase chromatography, Soils, Trace analysis, Ultraviolet visible spectrometry, Ureas, Water.

Abstract

Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0937-0633`
A03		`1`		`@0 Fresenius' j. anal. chem.`
A05				`@2 346`
A06				`@2 6-9`
A08	`01`	`1`	`ENG`	`@1 Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection`
A11	`01`	`1`		`@1 HENZE (G.)`
A11	`02`	`1`		`@1 MEYER (A.)`
A11	`03`	`1`		`@1 HAUSEN (J.)`
A14	`01`			`@1 Univ. Kaiserslautern, Fachbereich Chemie @2 W-5500 Trier @3 DEU`
A20				`@1 761-765`
A21				`@1 1993`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 853 @5 354000035185040540`
A44				`@0 0000`
A45				`@0 24 ref.`
A47	`01`	`1`		`@0 93-0570648`
A60				`@1 P`
A61				`@0 A`
A64		`1`		`@0 Fresenius' journal of analytical chemistry`
A66	`01`			`@0 DEU`
C01	`01`		`ENG`	@0 Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng
C02	`01`	`X`		`@0 001C04E`
C03	`01`	`X`	`FRE`	`@0 Analyse chimique @5 01`
C03	`01`	`X`	`ENG`	`@0 Chemical analysis @5 01`
C03	`01`	`X`	`GER`	`@0 Chemische Analyse @5 01`
C03	`01`	`X`	`SPA`	`@0 Análisis químico @5 01`
C03	`02`	`X`	`FRE`	`@0 Analyse trace @5 02`
C03	`02`	`X`	`ENG`	`@0 Trace analysis @5 02`
C03	`02`	`X`	`GER`	`@0 Spurenanalyse @5 02`
C03	`02`	`X`	`SPA`	`@0 Análisis huella @5 02`
C03	`03`	`X`	`FRE`	`@0 Chromatographie phase inverse @5 03`
C03	`03`	`X`	`ENG`	`@0 Reversed phase chromatography @5 03`
C03	`03`	`X`	`SPA`	`@0 Cromatografìa fase inversa @5 03`
C03	`04`	`X`	`FRE`	`@0 Chromatographie HPLC @5 04`
C03	`04`	`X`	`ENG`	`@0 HPLC chromatography @5 04`
C03	`04`	`X`	`SPA`	`@0 Cromatografía HPLC @5 04`
C03	`05`	`X`	`FRE`	`@0 Ampérométrie @5 05`
C03	`05`	`X`	`ENG`	`@0 Amperometry @5 05`
C03	`05`	`X`	`GER`	`@0 Amperometrische Titration @5 05`
C03	`05`	`X`	`SPA`	`@0 Amperometría @5 05`
C03	`06`	`X`	`FRE`	`@0 Spectrométrie UV visible @5 06`
C03	`06`	`X`	`ENG`	`@0 Ultraviolet visible spectrometry @5 06`
C03	`06`	`X`	`SPA`	`@0 Espectrometría UV visible @5 06`
C03	`07`	`X`	`FRE`	`@0 Etat adsorbé @5 07`
C03	`07`	`X`	`ENG`	`@0 Adsorbed state @5 07`
C03	`07`	`X`	`SPA`	`@0 Estado adsorbido @5 07`
C03	`08`	`X`	`FRE`	`@0 Enrichissement chimique @5 08`
C03	`08`	`X`	`ENG`	`@0 Chemical enrichment @5 08`
C03	`08`	`X`	`SPA`	`@0 Enriquecimiento químico @5 08`
C03	`09`	`X`	`FRE`	`@0 Herbicide @5 10`
C03	`09`	`X`	`ENG`	`@0 Herbicide @5 10`
C03	`09`	`X`	`SPA`	`@0 Herbicida @5 10`
C03	`10`	`X`	`FRE`	`@0 Métabolite @5 11`
C03	`10`	`X`	`ENG`	`@0 Metabolite @5 11`
C03	`10`	`X`	`SPA`	`@0 Metabolito @5 11`
C03	`11`	`X`	`FRE`	`@0 Urées @5 12`
C03	`11`	`X`	`ENG`	`@0 Ureas @5 12`
C03	`11`	`X`	`SPA`	`@0 Ureas @5 12`
C03	`12`	`X`	`FRE`	`@0 Chlore Composé organique @2 NC @2 FX @2 NA @5 13`
C03	`12`	`X`	`ENG`	`@0 Chlorine Organic compounds @2 NC @2 FX @2 NA @5 13`
C03	`12`	`X`	`SPA`	`@0 Cloro Compuesto orgánico @2 NC @2 FX @2 NA @5 13`
C03	`13`	`X`	`FRE`	`@0 Eau @1 SUB @5 14`
C03	`13`	`X`	`ENG`	`@0 Water @1 SUB @5 14`
C03	`13`	`X`	`GER`	`@0 Wasser @1 SUB @5 14`
C03	`13`	`X`	`SPA`	`@0 Agua @1 SUB @5 14`
C03	`14`	`X`	`FRE`	`@0 Sol @1 SUB @2 NT @5 15`
C03	`14`	`X`	`ENG`	`@0 Soils @1 SUB @2 NT @5 15`
C03	`14`	`X`	`SPA`	`@0 Suelo @1 SUB @2 NT @5 15`
C03	`15`	`X`	`FRE`	`@0 Linuron @1 ANA @4 INC @5 32`
C03	`16`	`X`	`FRE`	`@0 Ultratrace @4 INC @5 33`
N21				`@1 265`

Format Inist (serveur)

NO :	PASCAL 93-0570648 INIST
ET :	Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection
AU :	HENZE (G.); MEYER (A.); HAUSEN (J.)
AF :	Univ. Kaiserslautern, Fachbereich Chemie/W-5500 Trier/Allemagne
DT :	Publication en série; Niveau analytique
SO :	Fresenius' journal of analytical chemistry; ISSN 0937-0633; Allemagne; Da. 1993; Vol. 346; No. 6-9; Pp. 761-765; Bibl. 24 ref.
LA :	Anglais
EA :	Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng
CC :	001C04E
FD :	Analyse chimique; Analyse trace; Chromatographie phase inverse; Chromatographie HPLC; Ampérométrie; Spectrométrie UV visible; Etat adsorbé; Enrichissement chimique; Herbicide; Métabolite; Urées; Chlore Composé organique; Eau; Sol; Linuron; Ultratrace
ED :	Chemical analysis; Trace analysis; Reversed phase chromatography; HPLC chromatography; Amperometry; Ultraviolet visible spectrometry; Adsorbed state; Chemical enrichment; Herbicide; Metabolite; Ureas; Chlorine Organic compounds; Water; Soils
GD :	Chemische Analyse; Spurenanalyse; Amperometrische Titration; Wasser
SD :	Análisis químico; Análisis huella; Cromatografìa fase inversa; Cromatografía HPLC; Amperometría; Espectrometría UV visible; Estado adsorbido; Enriquecimiento químico; Herbicida; Metabolito; Ureas; Cloro Compuesto orgánico; Agua; Suelo
LO :	INIST-853.354000035185040540
ID :	93-0570648

Links to Exploration step

Pascal:93-0570648

Le document en format XML

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<front><div type="abstract" xml:lang="en">Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng</div>
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<s5>08</s5>
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<s5>08</s5>
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<s2>FX</s2>
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<s1>SUB</s1>
<s2>NT</s2>
<s5>15</s5>
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<fC03 i1="14" i2="X" l="ENG"><s0>Soils</s0>
<s1>SUB</s1>
<s2>NT</s2>
<s5>15</s5>
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<fC03 i1="14" i2="X" l="SPA"><s0>Suelo</s0>
<s1>SUB</s1>
<s2>NT</s2>
<s5>15</s5>
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<fC03 i1="15" i2="X" l="FRE"><s0>Linuron</s0>
<s1>ANA</s1>
<s4>INC</s4>
<s5>32</s5>
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<fC03 i1="16" i2="X" l="FRE"><s0>Ultratrace</s0>
<s4>INC</s4>
<s5>33</s5>
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<server><NO>PASCAL 93-0570648 INIST</NO>
<ET>Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC  with serial ultraviolet and amperometric detection</ET>
<AU>HENZE (G.); MEYER (A.); HAUSEN (J.)</AU>
<AF>Univ. Kaiserslautern, Fachbereich Chemie/W-5500 Trier/Allemagne</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Fresenius' journal of analytical chemistry; ISSN 0937-0633; Allemagne; Da. 1993; Vol. 346; No. 6-9; Pp. 761-765; Bibl. 24 ref.</SO>
<LA>Anglais</LA>
<EA>Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng</EA>
<CC>001C04E</CC>
<FD>Analyse chimique; Analyse trace; Chromatographie phase inverse; Chromatographie HPLC; Ampérométrie; Spectrométrie UV visible; Etat adsorbé; Enrichissement chimique; Herbicide; Métabolite; Urées; Chlore Composé organique; Eau; Sol; Linuron; Ultratrace</FD>
<ED>Chemical analysis; Trace analysis; Reversed phase chromatography; HPLC chromatography; Amperometry; Ultraviolet visible spectrometry; Adsorbed state; Chemical enrichment; Herbicide; Metabolite; Ureas; Chlorine Organic compounds; Water; Soils</ED>
<GD>Chemische Analyse; Spurenanalyse; Amperometrische Titration; Wasser</GD>
<SD>Análisis químico; Análisis huella; Cromatografìa fase inversa; Cromatografía HPLC; Amperometría; Espectrometría UV visible; Estado adsorbido; Enriquecimiento químico; Herbicida; Metabolito; Ureas; Cloro Compuesto orgánico; Agua; Suelo</SD>
<LO>INIST-853.354000035185040540</LO>
<ID>93-0570648</ID>
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Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection

Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection

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