UnivTrevesV1, PascalFrancis, Corpus, bibRecord, 000396

ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS

Identifieur interne : 000396 ( PascalFrancis/Corpus ); précédent : 000395; suivant : 000397

ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS

Auteurs : Klaus Fischer ; Susanne Höffler ; Axel Meyer

Source :

Analytical letters [ 0003-2719 ] ; 2011.

RBID : Pascal:11-0364028

Descripteurs français

Pascal (Inist)
- Spectrométrie masse, Ionisation chimique, Electrospray, Injection en écoulement, Activation par collision, Sélectivité, Identification, Cible, pH, Conversion, Libération, Carbone, Produit, Dissociation, Acide carboxylique, Sucre, Lactone, Dioxyde de carbone, Acide gluconique, Acide aldonique, Acide uronique.

English descriptors

KwdEn :
- Aldonic acid, Carbon, Carbon dioxide, Carboxylic acid, Chemical ionization, Collisional activation, Conversion, Dissociation, Electrospray, Flow injection, Gluconic acid, Identification, Lactone, Mass spectrometry, Product, Release, Selectivity, Sugar, Target, Uronic acid, pH.

Abstract

ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H₂O and CO₂ specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

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A08	`01`	`1`	`ENG`	`@1 ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS`
A11	`01`	`1`		`@1 FISCHER (Klaus)`
A11	`02`	`1`		`@1 HÖFFLER (Susanne)`
A11	`03`	`1`		`@1 MEYER (Axel)`
A14	`01`			`@1 Department of Analytical and Ecological Chemistry, University of Trier @2 Trier @3 DEU @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A20				`@1 1173-1186`
A21				`@1 2011`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 13703 @5 354000509473170010`
A44				`@0 0000 @1 © 2011 INIST-CNRS. All rights reserved.`
A45				`@0 1 p.`
A47	`01`	`1`		`@0 11-0364028`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Analytical letters`
A66	`01`			`@0 USA`
C01	`01`		`ENG`	@0 ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H₂O and CO₂ specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.
C02	`01`	`X`		`@0 001C04C`
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C03	`02`	`X`	`FRE`	`@0 Ionisation chimique @5 02`
C03	`02`	`X`	`ENG`	`@0 Chemical ionization @5 02`
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C03	`03`	`X`	`FRE`	`@0 Electrospray @5 03`
C03	`03`	`X`	`ENG`	`@0 Electrospray @5 03`
C03	`03`	`X`	`SPA`	`@0 Electrospray @5 03`
C03	`04`	`X`	`FRE`	`@0 Injection en écoulement @5 04`
C03	`04`	`X`	`ENG`	`@0 Flow injection @5 04`
C03	`04`	`X`	`SPA`	`@0 Inyección flujo @5 04`
C03	`05`	`X`	`FRE`	`@0 Activation par collision @5 05`
C03	`05`	`X`	`ENG`	`@0 Collisional activation @5 05`
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C03	`06`	`X`	`FRE`	`@0 Sélectivité @5 06`
C03	`06`	`X`	`ENG`	`@0 Selectivity @5 06`
C03	`06`	`X`	`SPA`	`@0 Selectividad @5 06`
C03	`07`	`X`	`FRE`	`@0 Identification @5 07`
C03	`07`	`X`	`ENG`	`@0 Identification @5 07`
C03	`07`	`X`	`SPA`	`@0 Identificación @5 07`
C03	`08`	`X`	`FRE`	`@0 Cible @5 08`
C03	`08`	`X`	`ENG`	`@0 Target @5 08`
C03	`08`	`X`	`SPA`	`@0 Blanco @5 08`
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C03	`09`	`X`	`ENG`	`@0 pH @5 09`
C03	`09`	`X`	`SPA`	`@0 pH @5 09`
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C03	`10`	`X`	`ENG`	`@0 Conversion @5 10`
C03	`10`	`X`	`SPA`	`@0 Conversión @5 10`
C03	`11`	`X`	`FRE`	`@0 Libération @5 11`
C03	`11`	`X`	`ENG`	`@0 Release @5 11`
C03	`11`	`X`	`SPA`	`@0 Liberación @5 11`
C03	`12`	`X`	`FRE`	`@0 Carbone @2 NC @5 12`
C03	`12`	`X`	`ENG`	`@0 Carbon @2 NC @5 12`
C03	`12`	`X`	`SPA`	`@0 Carbono @2 NC @5 12`
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C03	`14`	`X`	`ENG`	`@0 Dissociation @5 14`
C03	`14`	`X`	`SPA`	`@0 Disociación @5 14`
C03	`15`	`X`	`FRE`	`@0 Acide carboxylique @5 15`
C03	`15`	`X`	`ENG`	`@0 Carboxylic acid @5 15`
C03	`15`	`X`	`SPA`	`@0 Acido carboxílico @5 15`
C03	`16`	`X`	`FRE`	`@0 Sucre @5 16`
C03	`16`	`X`	`ENG`	`@0 Sugar @5 16`
C03	`16`	`X`	`SPA`	`@0 Azúcar @5 16`
C03	`17`	`X`	`FRE`	`@0 Lactone @5 17`
C03	`17`	`X`	`ENG`	`@0 Lactone @5 17`
C03	`17`	`X`	`SPA`	`@0 Lactona @5 17`
C03	`18`	`X`	`FRE`	`@0 Dioxyde de carbone @2 NK @2 FX @5 18`
C03	`18`	`X`	`ENG`	`@0 Carbon dioxide @2 NK @2 FX @5 18`
C03	`18`	`X`	`SPA`	`@0 Carbono dióxido @2 NK @2 FX @5 18`
C03	`19`	`X`	`FRE`	`@0 Acide gluconique @2 NK @5 19`
C03	`19`	`X`	`ENG`	`@0 Gluconic acid @2 NK @5 19`
C03	`19`	`X`	`SPA`	`@0 Glucónico ácido @2 NK @5 19`
C03	`20`	`X`	`FRE`	`@0 Acide aldonique @5 20`
C03	`20`	`X`	`ENG`	`@0 Aldonic acid @5 20`
C03	`20`	`X`	`SPA`	`@0 Acido aldónico @5 20`
C03	`21`	`X`	`FRE`	`@0 Acide uronique @5 21`
C03	`21`	`X`	`ENG`	`@0 Uronic acid @5 21`
C03	`21`	`X`	`SPA`	`@0 Acido urónico @5 21`
N21				`@1 249`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

Format Inist (serveur)

NO :	PASCAL 11-0364028 INIST
ET :	ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS
AU :	FISCHER (Klaus); HÖFFLER (Susanne); MEYER (Axel)
AF :	Department of Analytical and Ecological Chemistry, University of Trier/Trier/Allemagne (1 aut., 2 aut., 3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Analytical letters; ISSN 0003-2719; Coden ANALBP; Etats-Unis; Da. 2011; Vol. 44; No. 7-9; Pp. 1173-1186; Bibl. 1 p.
LA :	Anglais
EA :	ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H₂O and CO₂ specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.
CC :	001C04C
FD :	Spectrométrie masse; Ionisation chimique; Electrospray; Injection en écoulement; Activation par collision; Sélectivité; Identification; Cible; pH; Conversion; Libération; Carbone; Produit; Dissociation; Acide carboxylique; Sucre; Lactone; Dioxyde de carbone; Acide gluconique; Acide aldonique; Acide uronique
ED :	Mass spectrometry; Chemical ionization; Electrospray; Flow injection; Collisional activation; Selectivity; Identification; Target; pH; Conversion; Release; Carbon; Product; Dissociation; Carboxylic acid; Sugar; Lactone; Carbon dioxide; Gluconic acid; Aldonic acid; Uronic acid
SD :	Espectrometría masa; Ionización química; Electrospray; Inyección flujo; Activación por colisión; Selectividad; Identificación; Blanco; pH; Conversión; Liberación; Carbono; Producto; Disociación; Acido carboxílico; Azúcar; Lactona; Carbono dióxido; Glucónico ácido; Acido aldónico; Acido urónico
LO :	INIST-13703.354000509473170010
ID :	11-0364028

Links to Exploration step

Pascal:11-0364028

Le document en format XML

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<term>Electrospray</term>
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<term>Identification</term>
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<front><div type="abstract" xml:lang="en">ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H<sub>2</sub>
O and CO<sub>2</sub>
 specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.</div>
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<fC01 i1="01" l="ENG"><s0>ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H<sub>2</sub>
O and CO<sub>2</sub>
 specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.</s0>
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<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Cible</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Target</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Blanco</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>pH</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Conversion</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Conversion</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Conversión</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Libération</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Release</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Liberación</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Carbone</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Carbon</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Carbono</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Produit</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Product</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Producto</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Dissociation</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Dissociation</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Disociación</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Acide carboxylique</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Carboxylic acid</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Acido carboxílico</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Sucre</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Sugar</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Azúcar</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Lactone</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Lactone</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Lactona</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Dioxyde de carbone</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Carbon dioxide</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Carbono dióxido</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Acide gluconique</s0>
<s2>NK</s2>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Gluconic acid</s0>
<s2>NK</s2>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Glucónico ácido</s0>
<s2>NK</s2>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Acide aldonique</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>Aldonic acid</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Acido aldónico</s0>
<s5>20</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE"><s0>Acide uronique</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG"><s0>Uronic acid</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA"><s0>Acido urónico</s0>
<s5>21</s5>
</fC03>
<fN21><s1>249</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 11-0364028 INIST</NO>
<ET>ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS</ET>
<AU>FISCHER (Klaus); HÖFFLER (Susanne); MEYER (Axel)</AU>
<AF>Department of Analytical and Ecological Chemistry, University of Trier/Trier/Allemagne (1 aut., 2 aut., 3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Analytical letters; ISSN 0003-2719; Coden ANALBP; Etats-Unis; Da. 2011; Vol. 44; No. 7-9; Pp. 1173-1186; Bibl. 1 p.</SO>
<LA>Anglais</LA>
<EA>ESI-MS spectra were recorded with a FIA-MS system under CID conditions for 19 polyhydroxy carboxylic acids to assess the analytical selectivity of single quadrupole MS and to evaluate its suitability for the qualitative identification of the target compounds. Suited ESI operation conditions were defined for several sugar acids and their lactones and the pH dependence of the respective acid-lactone conversion was investigated. Besides the common neutral mass losses of H<sub>2</sub>
O and CO<sub>2</sub>
 specific mass losses, presumably belonging to the release of small carbon chain units, were established for isocitric and gluconic acids. A product ion with mlz 75 was part of the MS spectra of all aldonic acids, potentially indicating this structural subgroup of sugar acids. The spectra of other sugar acids and of tartaric, isocitric and shikimic acids had a product ion with mlz 73 in common. The results reveal that the CID mass spectra of several hydroxy acids show characteristic product ion patterns suited for a selective analyte identification.</EA>
<CC>001C04C</CC>
<FD>Spectrométrie masse; Ionisation chimique; Electrospray; Injection en écoulement; Activation par collision; Sélectivité; Identification; Cible; pH; Conversion; Libération; Carbone; Produit; Dissociation; Acide carboxylique; Sucre; Lactone; Dioxyde de carbone; Acide gluconique; Acide aldonique; Acide uronique</FD>
<ED>Mass spectrometry; Chemical ionization; Electrospray; Flow injection; Collisional activation; Selectivity; Identification; Target; pH; Conversion; Release; Carbon; Product; Dissociation; Carboxylic acid; Sugar; Lactone; Carbon dioxide; Gluconic acid; Aldonic acid; Uronic acid</ED>
<SD>Espectrometría masa; Ionización química; Electrospray; Inyección flujo; Activación por colisión; Selectividad; Identificación; Blanco; pH; Conversión; Liberación; Carbono; Producto; Disociación; Acido carboxílico; Azúcar; Lactona; Carbono dióxido; Glucónico ácido; Acido aldónico; Acido urónico</SD>
<LO>INIST-13703.354000509473170010</LO>
<ID>11-0364028</ID>
</server>
</inist>
</record>

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ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS

ESI SINGLE QUADRUPOLE MASS SPECTROMETRIC INVESTIGATION OF POLYHYDROXY ACIDS

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