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Concentrations and loads of dissolved xenobiotics and hormones in two small river catchments of different land use in Luxembourg

Identifieur interne : 001A61 ( Istex/Corpus ); précédent : 001A60; suivant : 001A62

Concentrations and loads of dissolved xenobiotics and hormones in two small river catchments of different land use in Luxembourg

Auteurs : A. Krein ; S. Ke Ler ; B. Meyer ; J. Pailler ; C. Guignard ; L. Hoffmann

Source :

RBID : ISTEX:ECA5A7D543DA848DFC5147FB487FEF0D13D662C4

Abstract

The investigation focuses on the analysis of dissolved sulfonamides, tetracyclines, analgesics, anticonvulsants and hormones in surface water. Runoff event and baseflow samples were analysed in two small river catchments of different land use in Luxembourg. For most of the flood events, similar pollutant loads to those transported during 1 day with average baseflow discharge were observed. The maximum contents during flood events and the event mean concentrations are controlled by pre‐event hydro‐climatological conditions. For all substances under investigation, maximum concentrations and event mean concentrations show a decrease with raising antecedent rainfall. In addition, the interstorm and intrastorm variability of the pollutant transport was determined. Runoff generation and corresponding transport of xenobiotic compounds show a complex pattern with many interrelated processes, taking place within bedrock, soil, anthropogenic facilities and channel and in different parts of the basins under investigation. Different sources of pollutants can be identified and related to particular locations in the basin. The influence of the sewer systems is obvious. In the agricultural Mess basin, higher rainfall amounts lead to greater quantities of laterally inflowing soil water with higher concentrations of dissolved oxytetracycline. This originates from veterinary medicines administered to livestock and enters the environment through the application of organic fertilisers, especially by slurry that is applied to the fields. Copyright © 2012 John Wiley & Sons, Ltd.

Url:
DOI: 10.1002/hyp.9209

Links to Exploration step

ISTEX:ECA5A7D543DA848DFC5147FB487FEF0D13D662C4

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<affiliation>Department of Environment and Agro‐Biotechnologies (EVA), Centre de Recherche Public–Gabriel Lippmann, Rue du Brill 41, L‐4422, Belvaux, Luxembourg</affiliation>
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<namePart type="family">Hoffmann</namePart>
<affiliation>Department of Environment and Agro‐Biotechnologies (EVA), Centre de Recherche Public–Gabriel Lippmann, Rue du Brill 41, L‐4422, Belvaux, Luxembourg</affiliation>
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<publisher>John Wiley & Sons, Ltd</publisher>
<place>
<placeTerm type="text">Chichester, UK</placeTerm>
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<dateIssued encoding="w3cdtf">2013-01-15</dateIssued>
<dateCreated encoding="w3cdtf">2012-01-27</dateCreated>
<dateCaptured encoding="w3cdtf">2011-09-07</dateCaptured>
<dateValid encoding="w3cdtf">2012-01-13</dateValid>
<copyrightDate encoding="w3cdtf">2013</copyrightDate>
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<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
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<abstract>The investigation focuses on the analysis of dissolved sulfonamides, tetracyclines, analgesics, anticonvulsants and hormones in surface water. Runoff event and baseflow samples were analysed in two small river catchments of different land use in Luxembourg. For most of the flood events, similar pollutant loads to those transported during 1 day with average baseflow discharge were observed. The maximum contents during flood events and the event mean concentrations are controlled by pre‐event hydro‐climatological conditions. For all substances under investigation, maximum concentrations and event mean concentrations show a decrease with raising antecedent rainfall. In addition, the interstorm and intrastorm variability of the pollutant transport was determined. Runoff generation and corresponding transport of xenobiotic compounds show a complex pattern with many interrelated processes, taking place within bedrock, soil, anthropogenic facilities and channel and in different parts of the basins under investigation. Different sources of pollutants can be identified and related to particular locations in the basin. The influence of the sewer systems is obvious. In the agricultural Mess basin, higher rainfall amounts lead to greater quantities of laterally inflowing soil water with higher concentrations of dissolved oxytetracycline. This originates from veterinary medicines administered to livestock and enters the environment through the application of organic fertilisers, especially by slurry that is applied to the fields. Copyright © 2012 John Wiley & Sons, Ltd.</abstract>
<subject>
<genre>keywords</genre>
<topic>analgesics</topic>
<topic>fluxes</topic>
<topic>hormones</topic>
<topic>Luxembourg</topic>
<topic>sulfonamides</topic>
<topic>surface water</topic>
<topic>tetracyclines</topic>
</subject>
<relatedItem type="host">
<titleInfo>
<title>Hydrological Processes</title>
</titleInfo>
<titleInfo type="abbreviated">
<title>Hydrol. Process.</title>
</titleInfo>
<genre type="journal">journal</genre>
<subject>
<genre>article-category</genre>
<topic>Research Article</topic>
</subject>
<identifier type="ISSN">0885-6087</identifier>
<identifier type="eISSN">1099-1085</identifier>
<identifier type="DOI">10.1002/(ISSN)1099-1085</identifier>
<identifier type="PublisherID">HYP</identifier>
<part>
<date>2013</date>
<detail type="volume">
<caption>vol.</caption>
<number>27</number>
</detail>
<detail type="issue">
<caption>no.</caption>
<number>2</number>
</detail>
<extent unit="pages">
<start>284</start>
<end>296</end>
<total>13</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">ECA5A7D543DA848DFC5147FB487FEF0D13D662C4</identifier>
<identifier type="DOI">10.1002/hyp.9209</identifier>
<identifier type="ArticleID">HYP9209</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2013 John Wiley & Sons, Ltd.Copyright © 2012 John Wiley & Sons, Ltd.</accessCondition>
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<recordOrigin>John Wiley & Sons, Ltd</recordOrigin>
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