Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection
Identifieur interne : 000A02 ( Istex/Corpus ); précédent : 000A01; suivant : 000A03Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection
Auteurs : Günter Henze ; Axel Meyer ; Josef HausenSource :
- Fresenius' Journal of Analytical Chemistry [ 0937-0633 ] ; 1993-06-01.
Abstract
Summary: Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultravoilet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.
Url:
DOI: 10.1007/BF00321287
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ISTEX:D6E998DDBBB2B1AE5B5E3922674A7378029DC560Le document en format XML
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For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.</div></front></TEI><istex><corpusName>springer</corpusName><author><json:item><name>Günter Henze</name><affiliations><json:string>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</json:string></affiliations></json:item><json:item><name>Axel Meyer</name><affiliations><json:string>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</json:string></affiliations></json:item><json:item><name>Josef Hausen</name><affiliations><json:string>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</json:string></affiliations></json:item></author><articleId><json:string>BF00321287</json:string><json:string>Art56</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>OriginalPaper</json:string></originalGenre><abstract>Summary: Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultravoilet-amperometric detection. 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Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.</abstract><qualityIndicators><score>4.019</score><pdfVersion>1.3</pdfVersion><pdfPageSize>598 x 785 pts</pdfPageSize><refBibsNative>false</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>757</abstractCharCount><pdfWordCount>2675</pdfWordCount><pdfCharCount>15456</pdfCharCount><pdfPageCount>5</pdfPageCount><abstractWordCount>112</abstractWordCount></qualityIndicators><title>Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection</title><refBibs><json:item><host><pages><last>773</last><first>760</first></pages><author></author><title>Verordnung fiber Trinkwasser und fiber Wasser ffir Lebensmittelbetriebe (Trinkwasserverordnung -TVO) vom 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Goro</name></json:item></author><host><volume>16</volume><pages><first>247</first></pages><author></author><title>J Pestic Sci</title><publicationDate>1991</publicationDate></host><publicationDate>1991</publicationDate></json:item></refBibs><genre><json:string>research-article</json:string></genre><host><volume>346</volume><pages><last>765</last><first>761</first></pages><issn><json:string>0937-0633</json:string></issn><issue>6-9</issue><subject><json:item><value>Analytical Chemistry</value></json:item><json:item><value>Food Science</value></json:item><json:item><value>Inorganic Chemistry</value></json:item><json:item><value>Physical Chemistry</value></json:item><json:item><value>Monitoring/Environmental Analysis/Environmental 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by HPLC with serial ultraviolet and amperometric detection</title><respStmt><resp>Références bibliographiques récupérées via GROBID</resp><name resp="ISTEX-API">ISTEX-API (INIST-CNRS)</name></respStmt><respStmt><resp>Références bibliographiques récupérées via GROBID</resp><name resp="ISTEX-API">ISTEX-API (INIST-CNRS)</name></respStmt></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>Springer-Verlag</publisher><pubPlace>Berlin/Heidelberg</pubPlace><availability><p>Springer-Verlag, 1993</p></availability><date>1992-07-31</date></publicationStmt><notesStmt><note>Original Papers/Pesticides</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection</title><author xml:id="author-1" corresp="yes"><persName><forename type="first">Günter</forename><surname>Henze</surname></persName><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation></author><author xml:id="author-2"><persName><forename type="first">Axel</forename><surname>Meyer</surname></persName><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation></author><author xml:id="author-3"><persName><forename type="first">Josef</forename><surname>Hausen</surname></persName><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation></author></analytic><monogr><title level="j">Fresenius' Journal of Analytical Chemistry</title><title level="j" type="abbrev">Fresenius J Anal 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reversed-phase high performance liquid chromatography with serial ultravoilet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>Chemistry</head><item><term>Analytical Chemistry</term></item><item><term>Food Science</term></item><item><term>Inorganic Chemistry</term></item><item><term>Physical Chemistry</term></item><item><term>Monitoring/Environmental Analysis/Environmental Ecotoxicology</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1992-07-31">Created</change><change when="1993-06-01">Published</change><change xml:id="refBibs-istex" who="#ISTEX-API" when="2016-11-22">References added</change><change xml:id="refBibs-istex" who="#ISTEX-API" when="2017-01-20">References 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III</DateString><Year>1993</Year><Month>6</Month></CoverDate></IssueHistory><IssueCopyright><CopyrightHolderName>Springer-Verlag</CopyrightHolderName><CopyrightYear>1993</CopyrightYear></IssueCopyright></IssueInfo><Article ID="Art56"><ArticleInfo Language="En" ArticleType="OriginalPaper" NumberingStyle="Unnumbered" TocLevels="0" ContainsESM="No"><ArticleID>BF00321287</ArticleID><ArticleDOI>10.1007/BF00321287</ArticleDOI><ArticleSequenceNumber>56</ArticleSequenceNumber><ArticleTitle Language="En">Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection</ArticleTitle><ArticleCategory>Original Papers</ArticleCategory><ArticleSubCategory>Pesticides</ArticleSubCategory><ArticleFirstPage>761</ArticleFirstPage><ArticleLastPage>765</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2004</Year><Month>8</Month><Day>26</Day></RegistrationDate><Received><Year>1992</Year><Month>7</Month><Day>31</Day></Received></ArticleHistory><ArticleCopyright><CopyrightHolderName>Springer-Verlag</CopyrightHolderName><CopyrightYear>1993</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant Grant="Restricted"></ESMGrant></ArticleGrants><ArticleContext><JournalID>216</JournalID><VolumeIDStart>346</VolumeIDStart><VolumeIDEnd>346</VolumeIDEnd><IssueIDStart>6</IssueIDStart><IssueIDEnd>9</IssueIDEnd></ArticleContext></ArticleInfo><ArticleHeader><AuthorGroup><Author AffiliationIDS="Aff1" CorrespondingAffiliationID="Aff1"><AuthorName DisplayOrder="Western"><GivenName>Günter</GivenName><FamilyName>Henze</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>Axel</GivenName><FamilyName>Meyer</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>Josef</GivenName><FamilyName>Hausen</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgDivision>Fachbereich Chemie</OrgDivision><OrgName>Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier</OrgName><OrgAddress><Postbox>Postfach 3825</Postbox><Postcode>W-5500</Postcode><City>Trier</City><Country>Germany</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Summary</Heading><Para>Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultravoilet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.</Para></Abstract><ArticleNote Type="Dedication"><SimplePara>Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday</SimplePara></ArticleNote></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Determination of the phenylurea herbicide linuron and its metabolites in environmental samples by HPLC with serial ultraviolet and amperometric detection</title></titleInfo><name type="personal" displayLabel="corresp"><namePart type="given">Günter</namePart><namePart type="family">Henze</namePart><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Axel</namePart><namePart type="family">Meyer</namePart><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Josef</namePart><namePart type="family">Hausen</namePart><affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, W-5500, Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper"></genre><originInfo><publisher>Springer-Verlag</publisher><place><placeTerm type="text">Berlin/Heidelberg</placeTerm></place><dateCreated encoding="w3cdtf">1992-07-31</dateCreated><dateIssued encoding="w3cdtf">1993-06-01</dateIssued><copyrightDate encoding="w3cdtf">1993</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">Summary: Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultravoilet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at +1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.</abstract><note>Original Papers/Pesticides</note><relatedItem type="host"><titleInfo><title>Fresenius' Journal of Analytical Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Fresenius J Anal Chem</title></titleInfo><genre type="journal" displayLabel="Archive Journal"></genre><originInfo><dateIssued encoding="w3cdtf">1993-06-01</dateIssued><copyrightDate encoding="w3cdtf">1993</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Analytical Chemistry</topic><topic>Food Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Monitoring/Environmental Analysis/Environmental Ecotoxicology</topic></subject><identifier type="ISSN">0937-0633</identifier><identifier type="eISSN">1432-1130</identifier><identifier type="JournalID">216</identifier><identifier type="IssueArticleCount">76</identifier><identifier type="VolumeIssueCount">12</identifier><part><date>1993</date><detail type="volume"><number>346</number><caption>vol.</caption></detail><detail type="issue"><number>6-9</number><caption>no.</caption></detail><extent unit="pages"><start>761</start><end>765</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1993</recordOrigin></recordInfo></relatedItem><identifier type="istex">D6E998DDBBB2B1AE5B5E3922674A7378029DC560</identifier><identifier type="DOI">10.1007/BF00321287</identifier><identifier type="ArticleID">BF00321287</identifier><identifier type="ArticleID">Art56</identifier><accessCondition type="use and reproduction" contentType="copyright">Springer-Verlag, 1993</accessCondition><recordInfo><recordContentSource>SPRINGER</recordContentSource><recordOrigin>Springer-Verlag, 1993</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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