Analysis of arsenic(V) by cathodic stripping voltammetry
Identifieur interne : 000911 ( Istex/Corpus ); précédent : 000910; suivant : 000912Analysis of arsenic(V) by cathodic stripping voltammetry
Auteurs : U. Greulach ; G. HenzeSource :
- Analytica Chimica Acta [ 0003-2670 ] ; 1995.
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Abstract
A novel electrochemical stripping approach is presented for the trace measurement of arsenate. It is based on the reduction of As(V) in a mannitol and perchlorate containing solution, the coprecipitation with copper and the voltammetric determination by further reduction to AsH3 at the hanging mercury drop electrode. For an accumulation period of 60 s, the detection limit has been found to be 4.4 μg1; the determination limit was calculated to be 11 μg1. The method has been applied to the analysis of arsenic in a standard stream sediment and in water samples.
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DOI: 10.1016/0003-2670(94)00681-B
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Box 3825, 54228 Trier, Germany</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:5BC5A6B305D58550E9CCE50118E7B24B0D035521</idno><date when="1995" year="1995">1995</date><idno type="doi">10.1016/0003-2670(94)00681-B</idno><idno type="url">https://api.istex.fr/document/5BC5A6B305D58550E9CCE50118E7B24B0D035521/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000911</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000911</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Analysis of arsenic(V) by cathodic stripping voltammetry</title><author><name sortKey="Greulach, U" sort="Greulach, U" uniqKey="Greulach U" first="U." last="Greulach">U. Greulach</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</mods:affiliation></affiliation></author><author><name sortKey="Henze, G" sort="Henze, G" uniqKey="Henze G" first="G." last="Henze">G. Henze</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Analytica Chimica Acta</title><title level="j" type="abbrev">ACA</title><idno type="ISSN">0003-2670</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1995">1995</date><biblScope unit="volume">306</biblScope><biblScope unit="issue">2–3</biblScope><biblScope unit="page" from="217">217</biblScope><biblScope unit="page" to="223">223</biblScope></imprint><idno type="ISSN">0003-2670</idno></series><idno type="istex">5BC5A6B305D58550E9CCE50118E7B24B0D035521</idno><idno type="DOI">10.1016/0003-2670(94)00681-B</idno><idno type="PII">0003-2670(94)00681-B</idno><idno type="ArticleID">9400681B</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0003-2670</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Arsenic</term><term>Environmental samples</term><term>Stripping voltammetry</term><term>Waters</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A novel electrochemical stripping approach is presented for the trace measurement of arsenate. 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For an accumulation period of 60 s, the detection limit has been found to be 4.4 μg1; the determination limit was calculated to be 11 μg1. The method has been applied to the analysis of arsenic in a standard stream sediment and in water samples.</abstract><qualityIndicators><score>3.678</score><pdfVersion>1.2</pdfVersion><pdfPageSize>540 x 720 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>4</keywordCount><abstractCharCount>564</abstractCharCount><pdfWordCount>2574</pdfWordCount><pdfCharCount>15768</pdfCharCount><pdfPageCount>7</pdfPageCount><abstractWordCount>92</abstractWordCount></qualityIndicators><title>Analysis of arsenic(V) by cathodic stripping voltammetry</title><pii><json:string>0003-2670(94)00681-B</json:string></pii><refBibs><json:item><author><json:item><name>G. Henze</name></json:item><json:item><name>R. 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Chem.</title></host></json:item><json:item><host><volume>52</volume><pages><first>2189</first></pages><author></author><title>Anal. Chem.</title></host></json:item><json:item><host><volume>289</volume><pages><first>291</first></pages><author></author><title>Anal. Chim. Acta</title></host></json:item><json:item><host><volume>47</volume><pages><first>1586</first></pages><author></author><title>Anal. Chem.</title></host></json:item><json:item><host><volume>50</volume><pages><first>137</first></pages><author></author><title>Anal. Chem.</title></host></json:item><json:item><host><volume>119</volume><pages><first>225</first></pages><author></author><title>Anal. Chim. Acta</title></host></json:item><json:item><host><volume>311</volume><pages><first>187</first></pages><author></author><title>Fresenius′ J. Anal. Chem.</title></host></json:item><json:item><host><volume>28</volume><pages><first>984</first></pages><issue>A</issue><author></author><title>Indian J. 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Box 3825, 54228 Trier, Germany</affiliation></author><author xml:id="author-2"><persName><forename type="first">G.</forename><surname>Henze</surname></persName><note type="correspondence"><p>Corresponding author.</p></note><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</affiliation></author></analytic><monogr><title level="j">Analytica Chimica Acta</title><title level="j" type="abbrev">ACA</title><idno type="pISSN">0003-2670</idno><idno type="PII">S0003-2670(00)X0045-1</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1995"></date><biblScope unit="volume">306</biblScope><biblScope unit="issue">2–3</biblScope><biblScope unit="page" from="217">217</biblScope><biblScope unit="page" to="223">223</biblScope></imprint></monogr><idno type="istex">5BC5A6B305D58550E9CCE50118E7B24B0D035521</idno><idno type="DOI">10.1016/0003-2670(94)00681-B</idno><idno type="PII">0003-2670(94)00681-B</idno><idno type="ArticleID">9400681B</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1995</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>A novel electrochemical stripping approach is presented for the trace measurement of arsenate. It is based on the reduction of As(V) in a mannitol and perchlorate containing solution, the coprecipitation with copper and the voltammetric determination by further reduction to AsH3 at the hanging mercury drop electrode. For an accumulation period of 60 s, the detection limit has been found to be 4.4 μg1; the determination limit was calculated to be 11 μg1. The method has been applied to the analysis of arsenic in a standard stream sediment and in water samples.</p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>Keywords</head><item><term>Stripping voltammetry</term></item><item><term>Arsenic</term></item><item><term>Environmental samples</term></item><item><term>Waters</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1994-12-06">Modified</change><change when="1995">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/5BC5A6B305D58550E9CCE50118E7B24B0D035521/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="UTF-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="en"><item-info><jid>ACA</jid><aid>9400681B</aid><ce:pii>0003-2670(94)00681-B</ce:pii><ce:doi>10.1016/0003-2670(94)00681-B</ce:doi><ce:copyright type="unknown" year="1995"></ce:copyright></item-info><head><ce:dochead><ce:textfn>Electroanalytical chemistry and sensor</ce:textfn></ce:dochead><ce:title>Analysis of arsenic(V) by cathodic stripping voltammetry</ce:title><ce:author-group><ce:author><ce:given-name>U.</ce:given-name><ce:surname>Greulach</ce:surname></ce:author><ce:author><ce:given-name>G.</ce:given-name><ce:surname>Henze</ce:surname><ce:cross-ref refid="COR1"><ce:sup loc="post">∗</ce:sup></ce:cross-ref></ce:author><ce:affiliation><ce:textfn>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</ce:textfn></ce:affiliation><ce:correspondence id="COR1"><ce:label>∗</ce:label><ce:text>Corresponding author.</ce:text></ce:correspondence></ce:author-group><ce:date-received day="3" month="10" year="1994"></ce:date-received><ce:date-revised day="6" month="12" year="1994"></ce:date-revised><ce:date-accepted day="10" month="12" year="1994"></ce:date-accepted><ce:abstract class="author"><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para view="all" id="simple-para.0010">A novel electrochemical stripping approach is presented for the trace measurement of arsenate. It is based on the reduction of As(V) in a mannitol and perchlorate containing solution, the coprecipitation with copper and the voltammetric determination by further reduction to AsH<ce:inf loc="post">3</ce:inf> at the hanging mercury drop electrode. For an accumulation period of 60 s, the detection limit has been found to be <math altimg="si1.gif">4.4 <fr shape="sol" align="c" style="s"><nu>μg</nu><de>1</de></fr></math>; the determination limit was calculated to be <math altimg="si2.gif">11 <fr shape="sol" align="c" style="s"><nu>μg</nu><de>1</de></fr></math>. The method has been applied to the analysis of arsenic in a standard stream sediment and in water samples.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Stripping voltammetry</ce:text></ce:keyword><ce:keyword><ce:text>Arsenic</ce:text></ce:keyword><ce:keyword><ce:text>Environmental samples</ce:text></ce:keyword><ce:keyword><ce:text>Waters</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Analysis of arsenic(V) by cathodic stripping voltammetry</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>Analysis of arsenic(V) by cathodic stripping voltammetry</title></titleInfo><name type="personal"><namePart type="given">U.</namePart><namePart type="family">Greulach</namePart><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">G.</namePart><namePart type="family">Henze</namePart><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, P.O. Box 3825, 54228 Trier, Germany</affiliation><description>Corresponding author.</description><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1995</dateIssued><dateModified encoding="w3cdtf">1994-12-06</dateModified><copyrightDate encoding="w3cdtf">1995</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">A novel electrochemical stripping approach is presented for the trace measurement of arsenate. It is based on the reduction of As(V) in a mannitol and perchlorate containing solution, the coprecipitation with copper and the voltammetric determination by further reduction to AsH3 at the hanging mercury drop electrode. For an accumulation period of 60 s, the detection limit has been found to be 4.4 μg1; the determination limit was calculated to be 11 μg1. The method has been applied to the analysis of arsenic in a standard stream sediment and in water samples.</abstract><note type="content">Section title: Electroanalytical chemistry and sensor</note><subject lang="en"><genre>Keywords</genre><topic>Stripping voltammetry</topic><topic>Arsenic</topic><topic>Environmental samples</topic><topic>Waters</topic></subject><relatedItem type="host"><titleInfo><title>Analytica Chimica Acta</title></titleInfo><titleInfo type="abbreviated"><title>ACA</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">19950510</dateIssued></originInfo><identifier type="ISSN">0003-2670</identifier><identifier type="PII">S0003-2670(00)X0045-1</identifier><part><date>19950510</date><detail type="volume"><number>306</number><caption>vol.</caption></detail><detail type="issue"><number>2–3</number><caption>no.</caption></detail><extent unit="issue pages"><start>173</start><end>370</end></extent><extent unit="pages"><start>217</start><end>223</end></extent></part></relatedItem><identifier type="istex">5BC5A6B305D58550E9CCE50118E7B24B0D035521</identifier><identifier type="DOI">10.1016/0003-2670(94)00681-B</identifier><identifier type="PII">0003-2670(94)00681-B</identifier><identifier type="ArticleID">9400681B</identifier><recordInfo><recordContentSource>ELSEVIER</recordContentSource></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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