Determination of titanium in ceramic samples by extraction-polarography
Identifieur interne : 000860 ( Istex/Corpus ); précédent : 000859; suivant : 000861Determination of titanium in ceramic samples by extraction-polarography
Auteurs : Uwe Greulach ; Günter Henze ; Gerhard KaiserSource :
- Fresenius' Journal of Analytical Chemistry [ 0937-0633 ] ; 1994-08-01.
Abstract
Abstract: An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.
Url:
DOI: 10.1007/BF00323482
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ISTEX:D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Determination of titanium in ceramic samples by extraction-polarography</title><author><name sortKey="Greulach, Uwe" sort="Greulach, Uwe" uniqKey="Greulach U" first="Uwe" last="Greulach">Uwe Greulach</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</mods:affiliation></affiliation></author><author><name sortKey="Henze, Gunter" sort="Henze, Gunter" uniqKey="Henze G" first="Günter" last="Henze">Günter Henze</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</mods:affiliation></affiliation></author><author><name sortKey="Kaiser, Gerhard" sort="Kaiser, Gerhard" uniqKey="Kaiser G" first="Gerhard" last="Kaiser">Gerhard Kaiser</name><affiliation><mods:affiliation>Pulvermetallurigsches Laboratorium, Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft, Heisenbergstrasse 5, D-70569, Stuttgart, Germany</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92</idno><date when="1994" year="1994">1994</date><idno type="doi">10.1007/BF00323482</idno><idno type="url">https://api.istex.fr/document/D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000860</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000860</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Determination of titanium in ceramic samples by extraction-polarography</title><author><name sortKey="Greulach, Uwe" sort="Greulach, Uwe" uniqKey="Greulach U" first="Uwe" last="Greulach">Uwe Greulach</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</mods:affiliation></affiliation></author><author><name sortKey="Henze, Gunter" sort="Henze, Gunter" uniqKey="Henze G" first="Günter" last="Henze">Günter Henze</name><affiliation><mods:affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</mods:affiliation></affiliation></author><author><name sortKey="Kaiser, Gerhard" sort="Kaiser, Gerhard" uniqKey="Kaiser G" first="Gerhard" last="Kaiser">Gerhard Kaiser</name><affiliation><mods:affiliation>Pulvermetallurigsches Laboratorium, Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft, Heisenbergstrasse 5, D-70569, Stuttgart, Germany</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Fresenius' Journal of Analytical Chemistry</title><title level="j" type="abbrev">Fresenius J Anal Chem</title><idno type="ISSN">0937-0633</idno><idno type="eISSN">1432-1130</idno><imprint><publisher>Springer-Verlag</publisher><pubPlace>Berlin/Heidelberg</pubPlace><date type="published" when="1994-08-01">1994-08-01</date><biblScope unit="volume">349</biblScope><biblScope unit="issue">8-9</biblScope><biblScope unit="page" from="688">688</biblScope><biblScope unit="page" to="691">691</biblScope></imprint><idno type="ISSN">0937-0633</idno></series><idno type="istex">D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92</idno><idno type="DOI">10.1007/BF00323482</idno><idno type="ArticleID">BF00323482</idno><idno type="ArticleID">Art27</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0937-0633</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.</div></front></TEI><istex><corpusName>springer</corpusName><author><json:item><name>Uwe Greulach</name><affiliations><json:string>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</json:string></affiliations></json:item><json:item><name>Günter Henze</name><affiliations><json:string>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</json:string></affiliations></json:item><json:item><name>Gerhard Kaiser</name><affiliations><json:string>Pulvermetallurigsches Laboratorium, Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft, Heisenbergstrasse 5, D-70569, Stuttgart, Germany</json:string></affiliations></json:item></author><articleId><json:string>BF00323482</json:string><json:string>Art27</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>OriginalPaper</json:string></originalGenre><abstract>Abstract: An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.</abstract><qualityIndicators><score>3.481</score><pdfVersion>1.3</pdfVersion><pdfPageSize>598 x 785 pts</pdfPageSize><refBibsNative>false</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>759</abstractCharCount><pdfWordCount>2245</pdfWordCount><pdfCharCount>12906</pdfCharCount><pdfPageCount>4</pdfPageCount><abstractWordCount>103</abstractWordCount></qualityIndicators><title>Determination of titanium in ceramic samples by extraction-polarography</title><refBibs><json:item><author><json:item><name>M Peuckert</name></json:item><json:item><name>T0 Vaahs</name></json:item><json:item><name>M Brfick</name></json:item></author><host><volume>9</volume><pages><first>398</first></pages><author></author><title>Adv 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xml:id="author-1"><persName><forename type="first">Uwe</forename><surname>Greulach</surname></persName><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</affiliation></author><author xml:id="author-2" corresp="yes"><persName><forename type="first">Günter</forename><surname>Henze</surname></persName><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</affiliation></author><author xml:id="author-3"><persName><forename type="first">Gerhard</forename><surname>Kaiser</surname></persName><affiliation>Pulvermetallurigsches Laboratorium, Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft, Heisenbergstrasse 5, D-70569, Stuttgart, Germany</affiliation></author></analytic><monogr><title level="j">Fresenius' Journal of Analytical Chemistry</title><title level="j" type="abbrev">Fresenius J Anal Chem</title><idno type="journal-ID">216</idno><idno type="pISSN">0937-0633</idno><idno type="eISSN">1432-1130</idno><idno type="issue-article-count">29</idno><idno type="volume-issue-count">12</idno><imprint><publisher>Springer-Verlag</publisher><pubPlace>Berlin/Heidelberg</pubPlace><date type="published" when="1994-08-01"></date><biblScope unit="volume">349</biblScope><biblScope unit="issue">8-9</biblScope><biblScope unit="page" from="688">688</biblScope><biblScope unit="page" to="691">691</biblScope></imprint></monogr><idno type="istex">D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92</idno><idno type="DOI">10.1007/BF00323482</idno><idno type="ArticleID">BF00323482</idno><idno type="ArticleID">Art27</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1993-03-19</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Abstract: An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>Chemistry</head><item><term>Analytical Chemistry</term></item><item><term>Food Science</term></item><item><term>Inorganic Chemistry</term></item><item><term>Physical Chemistry</term></item><item><term>Monitoring/Environmental Analysis/Environmental Ecotoxicology</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1993-03-19">Created</change><change when="1994-08-01">Published</change><change xml:id="refBibs-istex" who="#ISTEX-API" when="2016-11-22">References added</change><change xml:id="refBibs-istex" who="#ISTEX-API" when="2017-01-20">References 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AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>Uwe</GivenName><FamilyName>Greulach</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1" CorrespondingAffiliationID="Aff1"><AuthorName DisplayOrder="Western"><GivenName>Günter</GivenName><FamilyName>Henze</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff2"><AuthorName DisplayOrder="Western"><GivenName>Gerhard</GivenName><FamilyName>Kaiser</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgName>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier</OrgName><OrgAddress><Postbox>Postfach 3825</Postbox><Postcode>D-54228</Postcode><City>Trier</City><Country>Germany</Country></OrgAddress></Affiliation><Affiliation ID="Aff2"><OrgDivision>Pulvermetallurigsches Laboratorium</OrgDivision><OrgName>Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft</OrgName><OrgAddress><Street>Heisenbergstrasse 5</Street><Postcode>D-70569</Postcode><City>Stuttgart</City><Country>Germany</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Abstract</Heading><Para>An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.</Para></Abstract><ArticleNote Type="Dedication"><SimplePara>Dedicated to Professor Dr. Rudolf Geyer on the occasion of his 80th birthday</SimplePara></ArticleNote></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Determination of titanium in ceramic samples by extraction-polarography</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Determination of titanium in ceramic samples by extraction-polarography</title></titleInfo><name type="personal"><namePart type="given">Uwe</namePart><namePart type="family">Greulach</namePart><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal" displayLabel="corresp"><namePart type="given">Günter</namePart><namePart type="family">Henze</namePart><affiliation>Fachbereich Chemie der Universität Kaiserslautern und Abteilung für anorganische und analytische Chemie der Universität Trier, Postfach 3825, D-54228, Trier, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Gerhard</namePart><namePart type="family">Kaiser</namePart><affiliation>Pulvermetallurigsches Laboratorium, Max-Planck-Institut für Metallforschung, Institut für Werkstoffwissenschaft, Heisenbergstrasse 5, D-70569, Stuttgart, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper"></genre><originInfo><publisher>Springer-Verlag</publisher><place><placeTerm type="text">Berlin/Heidelberg</placeTerm></place><dateCreated encoding="w3cdtf">1993-03-19</dateCreated><dateIssued encoding="w3cdtf">1994-08-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">Abstract: An extraction-polarographic procedure was developed for the determination of the Ti main component in ceramic samples after pressurized wet decomposition. Dichloromethane with tetrabutylammoniumhexafluorophosphate as supporting electrolyte proved to be excellently suitable as extractant and solvent of the well-known 8-quinolinol (oxine) complex of Ti(IV). Interference by high fluoride concentrations in the decomposition solution can be avoided by application of the method of standard additions. The linear range for the determination of Ti lies between 0.5 and 15 μg/ml related to the aqueous decomposition sample. The results compare well with those obtained by emission spectrometry with an inductively coupled Ar plasma as excitation source.</abstract><note>Lectures And Posters</note><relatedItem type="host"><titleInfo><title>Fresenius' Journal of Analytical Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Fresenius J Anal Chem</title></titleInfo><genre type="journal" displayLabel="Archive Journal"></genre><originInfo><dateIssued encoding="w3cdtf">1994-08-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Analytical Chemistry</topic><topic>Food Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Monitoring/Environmental Analysis/Environmental Ecotoxicology</topic></subject><identifier type="ISSN">0937-0633</identifier><identifier type="eISSN">1432-1130</identifier><identifier type="JournalID">216</identifier><identifier type="IssueArticleCount">29</identifier><identifier type="VolumeIssueCount">12</identifier><part><date>1994</date><detail type="volume"><number>349</number><caption>vol.</caption></detail><detail type="issue"><number>8-9</number><caption>no.</caption></detail><extent unit="pages"><start>688</start><end>691</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></relatedItem><identifier type="istex">D3E8BB12EA48B8D1FB0B8072BD1BFE42D4100D92</identifier><identifier type="DOI">10.1007/BF00323482</identifier><identifier type="ArticleID">BF00323482</identifier><identifier type="ArticleID">Art27</identifier><accessCondition type="use and reproduction" contentType="copyright">Springer-Verlag, 1994</accessCondition><recordInfo><recordContentSource>SPRINGER</recordContentSource><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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