State-to-state quantum dynamics calculations of the C + OH reaction on the second excited potential energy surface.
Identifieur interne : 000207 ( PubMed/Corpus ); précédent : 000206; suivant : 000208State-to-state quantum dynamics calculations of the C + OH reaction on the second excited potential energy surface.
Auteurs : M. Jorfi ; P. HonvaultSource :
- The journal of physical chemistry. A [ 1520-5215 ] ; 2011.
Abstract
Accurate three-dimensional quantum-mechanical scattering calculations using a time-indepedent hyperspherical method have been performed for the C((3)P) + OH(X(2)Π) → CO(a(3)Π) + H((2)S) reaction on the second excited potential energy surface of 1(4)A″ symmetry. State-to-state reaction probabilities at a total angular momentum J = 0 have been computed in a wide range of collision energies. Many pronounced resonances have been found, espcially at low energy. The product vibrational distributions are noninverted. The present results therefore suggest that the title reaction proceeds via a long-lived intermediate complex. An approximate quantum-mechanical rate constant has also been calculated, and large differences are observed with the quasi-classical trajectory prediction.
DOI: 10.1021/jp202879n
PubMed: 21761901
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pubmed:21761901Le document en format XML
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<front><div type="abstract" xml:lang="en">Accurate three-dimensional quantum-mechanical scattering calculations using a time-indepedent hyperspherical method have been performed for the C((3)P) + OH(X(2)Π) → CO(a(3)Π) + H((2)S) reaction on the second excited potential energy surface of 1(4)A″ symmetry. State-to-state reaction probabilities at a total angular momentum J = 0 have been computed in a wide range of collision energies. Many pronounced resonances have been found, espcially at low energy. The product vibrational distributions are noninverted. The present results therefore suggest that the title reaction proceeds via a long-lived intermediate complex. An approximate quantum-mechanical rate constant has also been calculated, and large differences are observed with the quasi-classical trajectory prediction.</div>
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<Abstract><AbstractText>Accurate three-dimensional quantum-mechanical scattering calculations using a time-indepedent hyperspherical method have been performed for the C((3)P) + OH(X(2)Π) → CO(a(3)Π) + H((2)S) reaction on the second excited potential energy surface of 1(4)A″ symmetry. State-to-state reaction probabilities at a total angular momentum J = 0 have been computed in a wide range of collision energies. Many pronounced resonances have been found, espcially at low energy. The product vibrational distributions are noninverted. The present results therefore suggest that the title reaction proceeds via a long-lived intermediate complex. An approximate quantum-mechanical rate constant has also been calculated, and large differences are observed with the quasi-classical trajectory prediction.</AbstractText>
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