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Distribution of polycyclic musks in surface sediments from the Pearl River Delta and Macao coastal region, South China

Identifieur interne : 000533 ( Istex/Checkpoint ); précédent : 000532; suivant : 000534

Distribution of polycyclic musks in surface sediments from the Pearl River Delta and Macao coastal region, South China

Auteurs : Xiangying Zeng [République populaire de Chine] ; Bixian Mai [République populaire de Chine] ; Guoying Sheng [République populaire de Chine] ; Xiaojun Luo [République populaire de Chine] ; Wenlan Shao [République populaire de Chine] ; Taicheng An [République populaire de Chine] ; Jiamo Fu [République populaire de Chine]

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RBID : ISTEX:E8D0208097EFC67ADCEB1DC53F82F6455BB13BD4

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English descriptors

Abstract

Polycyclic musks were measured in surface sediments collected from the Pearl River Delta and Macao coastal region, South China, to investigate contamination from domestic sewage. Three polycyclic musk compounds—4‐acetyl‐1,1‐dimethyl‐6‐tert‐butylindan, 1,3,4,6,7,8‐hexahydro‐4,6,6,7,8,8‐hexamethylcyclopenta(g)‐2‐benzopyran (HHCB), and 7‐acetyl‐1,1,3,4,4,6–hexa‐methyl‐1,2,3,4‐tetrahydronaphthalene (AHTN)—were detected in sediment samples. Two polycyclic musks, HHCB and AHTN, were dominant components in sediment, consistent with the use pattern of polycyclic musks by perfume industries in the Pearl River Delta region. The concentrations of total polycyclic musks ranged from 5.76 to 167 u,g/kg. Because of the large amount of domestic sewage and industrial wastewater discharged from the city of Guangzhou, the highest concentration of polycyclic musks was found in sediments from the Zhujiang River. The significant positive correlation between the HHCB to AHTN ratios and the concentrations of polycyclic musks suggested that the HHCB to AHTN ratio could be used as a tracer for source discrimination and for the degree of degradation in the environment.

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DOI: 10.1897/07-106.1


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ISTEX:E8D0208097EFC67ADCEB1DC53F82F6455BB13BD4

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<div type="abstract" xml:lang="en">Polycyclic musks were measured in surface sediments collected from the Pearl River Delta and Macao coastal region, South China, to investigate contamination from domestic sewage. Three polycyclic musk compounds—4‐acetyl‐1,1‐dimethyl‐6‐tert‐butylindan, 1,3,4,6,7,8‐hexahydro‐4,6,6,7,8,8‐hexamethylcyclopenta(g)‐2‐benzopyran (HHCB), and 7‐acetyl‐1,1,3,4,4,6–hexa‐methyl‐1,2,3,4‐tetrahydronaphthalene (AHTN)—were detected in sediment samples. Two polycyclic musks, HHCB and AHTN, were dominant components in sediment, consistent with the use pattern of polycyclic musks by perfume industries in the Pearl River Delta region. The concentrations of total polycyclic musks ranged from 5.76 to 167 u,g/kg. Because of the large amount of domestic sewage and industrial wastewater discharged from the city of Guangzhou, the highest concentration of polycyclic musks was found in sediments from the Zhujiang River. The significant positive correlation between the HHCB to AHTN ratios and the concentrations of polycyclic musks suggested that the HHCB to AHTN ratio could be used as a tracer for source discrimination and for the degree of degradation in the environment.</div>
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