Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).
Identifieur interne : 000829 ( Main/Corpus ); précédent : 000828; suivant : 000830Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).
Auteurs : Tengfei Li ; Gaojin Lyu ; Yu Liu ; Rui Lou ; Lucian A. Lucia ; Guihua Yang ; Jiachuan Chen ; Haroon A M. SaeedSource :
- International journal of molecular sciences [ 1422-0067 ] ; 2017.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Lignin, Solvents.
- chemical , isolation & purification : Lignin.
- chemistry : Salix.
- Magnetic Resonance Spectroscopy, Spectroscopy, Fourier Transform Infrared.
Abstract
Deep eutectic solvents (DESs) are a potentially high-value lignin extraction methodology. DESs prepared from choline chloride (ChCl) and three hydrogen-bond donors (HBD)-lactic acid (Lac), glycerol, and urea-were evaluated for isolation of willow (Salix matsudana cv. Zhuliu) lignin. DESs types, mole ratio of ChCl to HBD, extraction temperature, and time on the fractionated DES-lignin yield demonstrated that the optimal DES-lignin yield (91.8 wt % based on the initial lignin in willow) with high purity of 94.5% can be reached at a ChCl-to-Lac molar ratio of 1:10, extraction temperature of 120 °C, and time of 12 h. Fourier transform infrared spectroscopy (FT-IR) , 13C-NMR, and 31P-NMR showed that willow lignin extracted by ChCl-Lac was mainly composed of syringyl and guaiacyl units. Serendipitously, a majority of the glucan in willow was preserved after ChCl-Lac treatment.
DOI: 10.3390/ijms18112266
PubMed: 29143790
PubMed Central: PMC5713236
Links to Exploration step
pubmed:29143790Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).</title><author><name sortKey="Li, Tengfei" sort="Li, Tengfei" uniqKey="Li T" first="Tengfei" last="Li">Tengfei Li</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. leetengfly@gmail.com.</nlm:affiliation></affiliation></author><author><name sortKey="Lyu, Gaojin" sort="Lyu, Gaojin" uniqKey="Lyu G" first="Gaojin" last="Lyu">Gaojin Lyu</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. gaojinlv@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Liu, Yu" sort="Liu, Yu" uniqKey="Liu Y" first="Yu" last="Liu">Yu Liu</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. liuy@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Lou, Rui" sort="Lou, Rui" uniqKey="Lou R" first="Rui" last="Lou">Rui Lou</name><affiliation><nlm:affiliation>College of Mechanical and Electronic Engineering, Shaanxi University of Science and Technology, Xi'an 710021, Shaanxi, China. lourui@sust.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Lucia, Lucian A" sort="Lucia, Lucian A" uniqKey="Lucia L" first="Lucian A" last="Lucia">Lucian A. Lucia</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. lalucia@ncsu.edu.</nlm:affiliation></affiliation><affiliation><nlm:affiliation>Department of Forest Biomaterials, North Carolina State University, Box 8005, Raleigh, NC 27695-8005, USA. lalucia@ncsu.edu.</nlm:affiliation></affiliation></author><author><name sortKey="Yang, Guihua" sort="Yang, Guihua" uniqKey="Yang G" first="Guihua" last="Yang">Guihua Yang</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. ygh@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Chen, Jiachuan" sort="Chen, Jiachuan" uniqKey="Chen J" first="Jiachuan" last="Chen">Jiachuan Chen</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. chenjc@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Saeed, Haroon A M" sort="Saeed, Haroon A M" uniqKey="Saeed H" first="Haroon A M" last="Saeed">Haroon A M. Saeed</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. haroonsaeed75@gmail.com.</nlm:affiliation></affiliation><affiliation><nlm:affiliation>Center of Fibers, Papers and Recycling, Faculty of Textiles, University of Gezira, Box 20, Wad Medani 79371, Sudan. haroonsaeed75@gmail.com.</nlm:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2017">2017</date><idno type="RBID">pubmed:29143790</idno><idno type="pmid">29143790</idno><idno type="doi">10.3390/ijms18112266</idno><idno type="pmc">PMC5713236</idno><idno type="wicri:Area/Main/Corpus">000829</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Corpus" wicri:corpus="PubMed">000829</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).</title><author><name sortKey="Li, Tengfei" sort="Li, Tengfei" uniqKey="Li T" first="Tengfei" last="Li">Tengfei Li</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. leetengfly@gmail.com.</nlm:affiliation></affiliation></author><author><name sortKey="Lyu, Gaojin" sort="Lyu, Gaojin" uniqKey="Lyu G" first="Gaojin" last="Lyu">Gaojin Lyu</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. gaojinlv@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Liu, Yu" sort="Liu, Yu" uniqKey="Liu Y" first="Yu" last="Liu">Yu Liu</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. liuy@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Lou, Rui" sort="Lou, Rui" uniqKey="Lou R" first="Rui" last="Lou">Rui Lou</name><affiliation><nlm:affiliation>College of Mechanical and Electronic Engineering, Shaanxi University of Science and Technology, Xi'an 710021, Shaanxi, China. lourui@sust.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Lucia, Lucian A" sort="Lucia, Lucian A" uniqKey="Lucia L" first="Lucian A" last="Lucia">Lucian A. Lucia</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. lalucia@ncsu.edu.</nlm:affiliation></affiliation><affiliation><nlm:affiliation>Department of Forest Biomaterials, North Carolina State University, Box 8005, Raleigh, NC 27695-8005, USA. lalucia@ncsu.edu.</nlm:affiliation></affiliation></author><author><name sortKey="Yang, Guihua" sort="Yang, Guihua" uniqKey="Yang G" first="Guihua" last="Yang">Guihua Yang</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. ygh@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Chen, Jiachuan" sort="Chen, Jiachuan" uniqKey="Chen J" first="Jiachuan" last="Chen">Jiachuan Chen</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. chenjc@qlu.edu.cn.</nlm:affiliation></affiliation></author><author><name sortKey="Saeed, Haroon A M" sort="Saeed, Haroon A M" uniqKey="Saeed H" first="Haroon A M" last="Saeed">Haroon A M. Saeed</name><affiliation><nlm:affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. haroonsaeed75@gmail.com.</nlm:affiliation></affiliation><affiliation><nlm:affiliation>Center of Fibers, Papers and Recycling, Faculty of Textiles, University of Gezira, Box 20, Wad Medani 79371, Sudan. haroonsaeed75@gmail.com.</nlm:affiliation></affiliation></author></analytic><series><title level="j">International journal of molecular sciences</title><idno type="eISSN">1422-0067</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Lignin (chemistry)</term><term>Lignin (isolation & purification)</term><term>Magnetic Resonance Spectroscopy (MeSH)</term><term>Salix (chemistry)</term><term>Solvents (chemistry)</term><term>Spectroscopy, Fourier Transform Infrared (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Lignin</term><term>Solvents</term></keywords><keywords scheme="MESH" type="chemical" qualifier="isolation & purification" xml:lang="en"><term>Lignin</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Salix</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Magnetic Resonance Spectroscopy</term><term>Spectroscopy, Fourier Transform Infrared</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Deep eutectic solvents (DESs) are a potentially high-value lignin extraction methodology. DESs prepared from choline chloride (ChCl) and three hydrogen-bond donors (HBD)-lactic acid (Lac), glycerol, and urea-were evaluated for isolation of willow (<i>Salix matsudana cv. Zhuliu</i>) lignin. DESs types, mole ratio of ChCl to HBD, extraction temperature, and time on the fractionated DES-lignin yield demonstrated that the optimal DES-lignin yield (91.8 wt % based on the initial lignin in willow) with high purity of 94.5% can be reached at a ChCl-to-Lac molar ratio of 1:10, extraction temperature of 120 °C, and time of 12 h. Fourier transform infrared spectroscopy (FT-IR) , <sup>13</sup>C-NMR, and <sup>31</sup>P-NMR showed that willow lignin extracted by ChCl-Lac was mainly composed of syringyl and guaiacyl units. Serendipitously, a majority of the glucan in willow was preserved after ChCl-Lac treatment.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">29143790</PMID><DateCompleted><Year>2018</Year><Month>06</Month><Day>27</Day></DateCompleted><DateRevised><Year>2018</Year><Month>11</Month><Day>13</Day></DateRevised><Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">1422-0067</ISSN><JournalIssue CitedMedium="Internet"><Volume>18</Volume><Issue>11</Issue><PubDate><Year>2017</Year><Month>Oct</Month><Day>28</Day></PubDate></JournalIssue><Title>International journal of molecular sciences</Title><ISOAbbreviation>Int J Mol Sci</ISOAbbreviation></Journal><ArticleTitle>Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).</ArticleTitle><ELocationID EIdType="pii" ValidYN="Y">E2266</ELocationID><ELocationID EIdType="doi" ValidYN="Y">10.3390/ijms18112266</ELocationID><Abstract><AbstractText>Deep eutectic solvents (DESs) are a potentially high-value lignin extraction methodology. DESs prepared from choline chloride (ChCl) and three hydrogen-bond donors (HBD)-lactic acid (Lac), glycerol, and urea-were evaluated for isolation of willow (<i>Salix matsudana cv. Zhuliu</i>) lignin. DESs types, mole ratio of ChCl to HBD, extraction temperature, and time on the fractionated DES-lignin yield demonstrated that the optimal DES-lignin yield (91.8 wt % based on the initial lignin in willow) with high purity of 94.5% can be reached at a ChCl-to-Lac molar ratio of 1:10, extraction temperature of 120 °C, and time of 12 h. Fourier transform infrared spectroscopy (FT-IR) , <sup>13</sup>C-NMR, and <sup>31</sup>P-NMR showed that willow lignin extracted by ChCl-Lac was mainly composed of syringyl and guaiacyl units. Serendipitously, a majority of the glucan in willow was preserved after ChCl-Lac treatment.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Tengfei</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. leetengfly@gmail.com.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lyu</LastName><ForeName>Gaojin</ForeName><Initials>G</Initials><Identifier Source="ORCID">0000-0002-8427-6391</Identifier><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. gaojinlv@qlu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Liu</LastName><ForeName>Yu</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. liuy@qlu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lou</LastName><ForeName>Rui</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>College of Mechanical and Electronic Engineering, Shaanxi University of Science and Technology, Xi'an 710021, Shaanxi, China. lourui@sust.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lucia</LastName><ForeName>Lucian A</ForeName><Initials>LA</Initials><Identifier Source="ORCID">0000-0003-0157-2505</Identifier><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. lalucia@ncsu.edu.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Department of Forest Biomaterials, North Carolina State University, Box 8005, Raleigh, NC 27695-8005, USA. lalucia@ncsu.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Yang</LastName><ForeName>Guihua</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. ygh@qlu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Chen</LastName><ForeName>Jiachuan</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. chenjc@qlu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Saeed</LastName><ForeName>Haroon A M</ForeName><Initials>HAM</Initials><AffiliationInfo><Affiliation>Key Lab of Pulp and Paper Science and Technology of the Ministry of Education, Qilu University of Technology, Jinan 250353, Shandong, China. haroonsaeed75@gmail.com.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Center of Fibers, Papers and Recycling, Faculty of Textiles, University of Gezira, Box 20, Wad Medani 79371, Sudan. haroonsaeed75@gmail.com.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2017</Year><Month>10</Month><Day>28</Day></ArticleDate></Article><MedlineJournalInfo><Country>Switzerland</Country><MedlineTA>Int J Mol Sci</MedlineTA><NlmUniqueID>101092791</NlmUniqueID><ISSNLinking>1422-0067</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D012997">Solvents</NameOfSubstance></Chemical><Chemical><RegistryNumber>9005-53-2</RegistryNumber><NameOfSubstance UI="D008031">Lignin</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D008031" MajorTopicYN="N">Lignin</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName><QualifierName UI="Q000302" MajorTopicYN="Y">isolation & purification</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D009682" MajorTopicYN="N">Magnetic Resonance Spectroscopy</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D032108" MajorTopicYN="N">Salix</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D012997" MajorTopicYN="N">Solvents</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D017550" MajorTopicYN="N">Spectroscopy, Fourier Transform Infrared</DescriptorName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">DES-lignin</Keyword><Keyword MajorTopicYN="N">choline chloride</Keyword><Keyword MajorTopicYN="N">deep eutectic solvents</Keyword><Keyword MajorTopicYN="N">lactic acid</Keyword></KeywordList><CoiStatement>The authors declare no conflict of interest.</CoiStatement></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2017</Year><Month>09</Month><Day>23</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2017</Year><Month>10</Month><Day>24</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2017</Year><Month>10</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2017</Year><Month>11</Month><Day>17</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2017</Year><Month>11</Month><Day>17</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2018</Year><Month>6</Month><Day>28</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">29143790</ArticleId><ArticleId IdType="pii">ijms18112266</ArticleId><ArticleId IdType="doi">10.3390/ijms18112266</ArticleId><ArticleId IdType="pmc">PMC5713236</ArticleId></ArticleIdList><ReferenceList><Reference><Citation>Chem Soc Rev. 2012 Nov 7;41(21):7108-46</Citation><ArticleIdList><ArticleId IdType="pubmed">22806597</ArticleId></ArticleIdList></Reference><Reference><Citation>Chem Commun (Camb). 2003 Jan 7;(1):70-1</Citation><ArticleIdList><ArticleId IdType="pubmed">12610970</ArticleId></ArticleIdList></Reference><Reference><Citation>Bioresour Technol. 2016 Jan;199:1</Citation><ArticleIdList><ArticleId IdType="pubmed">26549773</ArticleId></ArticleIdList></Reference><Reference><Citation>Int J Mol Sci. 2014 Oct 20;15(10):18967-84</Citation><ArticleIdList><ArticleId IdType="pubmed">25334065</ArticleId></ArticleIdList></Reference><Reference><Citation>AMB Express. 2017 Dec;7(1):72</Citation><ArticleIdList><ArticleId IdType="pubmed">28353158</ArticleId></ArticleIdList></Reference><Reference><Citation>Anal Chim Acta. 2017 Aug 1;979:1-23</Citation><ArticleIdList><ArticleId IdType="pubmed">28599704</ArticleId></ArticleIdList></Reference><Reference><Citation>Bioresour Technol. 2011 Nov;102(21):10035-9</Citation><ArticleIdList><ArticleId IdType="pubmed">21907575</ArticleId></ArticleIdList></Reference><Reference><Citation>Int J Mol Sci. 2017 Feb 04;18(2):</Citation><ArticleIdList><ArticleId IdType="pubmed">28165411</ArticleId></ArticleIdList></Reference><Reference><Citation>Langmuir. 2017 Jul 11;33(27):6878-6884</Citation><ArticleIdList><ArticleId IdType="pubmed">28627891</ArticleId></ArticleIdList></Reference></ReferenceList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Bois/explor/WillowV1/Data/Main/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000829 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Corpus/biblio.hfd -nk 000829 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Bois
|area= WillowV1
|flux= Main
|étape= Corpus
|type= RBID
|clé= pubmed:29143790
|texte= Deep Eutectic Solvents (DESs) for the Isolation of Willow Lignin (Salix matsudana cv. Zhuliu).
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Corpus/RBID.i -Sk "pubmed:29143790" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Corpus/biblio.hfd \
| NlmPubMed2Wicri -a WillowV1
| This area was generated with Dilib version V0.6.37. |  |