PoplarV1, Main, Exploration, bibRecord, 000704

Steam assisted slow pyrolysis of contaminated biomasses: Effect of plant parts and process temperature on heavy metals fate.

Identifieur interne : 000704 ( Main/Exploration ); précédent : 000703; suivant : 000705

Steam assisted slow pyrolysis of contaminated biomasses: Effect of plant parts and process temperature on heavy metals fate.

Auteurs : Corinna Maria Grottola [Italie] ; Paola Giudicianni [Italie] ; Stefania Pindozzi [Italie] ; Fernando Stanzione [Italie] ; Salvatore Faugno [Italie] ; Massimo Fagnano [Italie] ; Nunzio Fiorentino [Italie] ; Raffaele Ragucci [Italie]

Source :

Waste management (New York, N.Y.) [ 1879-2456 ] ; 2019.

RBID : pubmed:30803577

Descripteurs français

KwdFr :
- Biomasse (MeSH), Métaux lourds (MeSH), Pyrolyse (MeSH), Température (MeSH), Vapeur (MeSH).
MESH :
- Biomasse, Métaux lourds, Pyrolyse, Température, Vapeur.

English descriptors

KwdEn :
- Biomass (MeSH), Metals, Heavy (MeSH), Pyrolysis (MeSH), Steam (MeSH), Temperature (MeSH).
MESH :
- chemical : Metals, Heavy, Steam.
- Biomass, Pyrolysis, Temperature.

Abstract

The post-treatment of biomass from phytoremediation is not yet a well-established practice due to the risk induced by the presence of Potentially Toxic Elements (PTEs). Pyrolysis is a thermochemical treatment that reduces the volume and weight of contaminated matter producing a combustible vapor phase and a solid residue (char). A key factor enhancing the economic and the environmental sustainability of biomass valorization through pyrolysis is the production of a market value char. A proper choice of the pyrolysis operating conditions should take into account the effect of final temperature on PTEs release, on the char physicochemical properties as well as on the mobility of retained PTEs. In particular, in this work the influence of both the temperature and the plant parts is discussed (branches and leaves of Populus Nigra L. and rhizomes and culms of Arundo donax L.) on the release of Cd, Pb, Cu, and Zn in the temperature range 653-873 K under steam assisted slow pyrolysis conditions. The mobility of the heavy metals retained in the chars was also studied as well as the product yields, the gas composition and char porosity. The results suggested that in presence of Cd it is necessary to operate at low-temperature (lower than 703 K) to obtain a heavy metals free vapor phase fuel, whereas in presence of one or more metals among Pb, Cu, and Zn, it is possible to conduct a pyrolytic treatment at higher temperatures, thus obtaining a char with high BET surface area and lower metals mobility.

DOI: 10.1016/j.wasman.2018.12.028
PubMed: 30803577

Affiliations:

Italie

Links toward previous steps (curation, corpus...)

to stream Main, to step Corpus: 000A20
to stream Main, to step Curation: 000A20

Le document en format XML

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<front><div type="abstract" xml:lang="en">The post-treatment of biomass from phytoremediation is not yet a well-established practice due to the risk induced by the presence of Potentially Toxic Elements (PTEs). Pyrolysis is a thermochemical treatment that reduces the volume and weight of contaminated matter producing a combustible vapor phase and a solid residue (char). A key factor enhancing the economic and the environmental sustainability of biomass valorization through pyrolysis is the production of a market value char. A proper choice of the pyrolysis operating conditions should take into account the effect of final temperature on PTEs release, on the char physicochemical properties as well as on the mobility of retained PTEs. In particular, in this work the influence of both the temperature and the plant parts is discussed (branches and leaves of Populus Nigra L. and rhizomes and culms of Arundo donax L.) on the release of Cd, Pb, Cu, and Zn in the temperature range 653-873 K under steam assisted slow pyrolysis conditions. The mobility of the heavy metals retained in the chars was also studied as well as the product yields, the gas composition and char porosity. The results suggested that in presence of Cd it is necessary to operate at low-temperature (lower than 703 K) to obtain a heavy metals free vapor phase fuel, whereas in presence of one or more metals among Pb, Cu, and Zn, it is possible to conduct a pyrolytic treatment at higher temperatures, thus obtaining a char with high BET surface area and lower metals mobility.</div>
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<Abstract><AbstractText>The post-treatment of biomass from phytoremediation is not yet a well-established practice due to the risk induced by the presence of Potentially Toxic Elements (PTEs). Pyrolysis is a thermochemical treatment that reduces the volume and weight of contaminated matter producing a combustible vapor phase and a solid residue (char). A key factor enhancing the economic and the environmental sustainability of biomass valorization through pyrolysis is the production of a market value char. A proper choice of the pyrolysis operating conditions should take into account the effect of final temperature on PTEs release, on the char physicochemical properties as well as on the mobility of retained PTEs. In particular, in this work the influence of both the temperature and the plant parts is discussed (branches and leaves of Populus Nigra L. and rhizomes and culms of Arundo donax L.) on the release of Cd, Pb, Cu, and Zn in the temperature range 653-873 K under steam assisted slow pyrolysis conditions. The mobility of the heavy metals retained in the chars was also studied as well as the product yields, the gas composition and char porosity. The results suggested that in presence of Cd it is necessary to operate at low-temperature (lower than 703 K) to obtain a heavy metals free vapor phase fuel, whereas in presence of one or more metals among Pb, Cu, and Zn, it is possible to conduct a pyrolytic treatment at higher temperatures, thus obtaining a char with high BET surface area and lower metals mobility.</AbstractText>
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<name sortKey="Fiorentino, Nunzio" sort="Fiorentino, Nunzio" uniqKey="Fiorentino N" first="Nunzio" last="Fiorentino">Nunzio Fiorentino</name>
<name sortKey="Giudicianni, Paola" sort="Giudicianni, Paola" uniqKey="Giudicianni P" first="Paola" last="Giudicianni">Paola Giudicianni</name>
<name sortKey="Pindozzi, Stefania" sort="Pindozzi, Stefania" uniqKey="Pindozzi S" first="Stefania" last="Pindozzi">Stefania Pindozzi</name>
<name sortKey="Ragucci, Raffaele" sort="Ragucci, Raffaele" uniqKey="Ragucci R" first="Raffaele" last="Ragucci">Raffaele Ragucci</name>
<name sortKey="Stanzione, Fernando" sort="Stanzione, Fernando" uniqKey="Stanzione F" first="Fernando" last="Stanzione">Fernando Stanzione</name>
</country>
</tree>
</affiliations>
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   |clé=     pubmed:30803577
   |texte=   Steam assisted slow pyrolysis of contaminated biomasses: Effect of plant parts and process temperature on heavy metals fate.
}}

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Steam assisted slow pyrolysis of contaminated biomasses: Effect of plant parts and process temperature on heavy metals fate.

Steam assisted slow pyrolysis of contaminated biomasses: Effect of plant parts and process temperature on heavy metals fate.

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