Hierarchically porous carbon derived from potassium-citrate-loaded poplar catkin for high performance supercapacitors.
Identifieur interne : 000356 ( Main/Exploration ); précédent : 000355; suivant : 000357Hierarchically porous carbon derived from potassium-citrate-loaded poplar catkin for high performance supercapacitors.
Auteurs : Xiaodong Luo [République populaire de Chine] ; Shaolong Li [République populaire de Chine] ; Haiyang Xu [République populaire de Chine] ; Xuhui Zou [République populaire de Chine] ; Yuan Wang [République populaire de Chine] ; Jun Cheng [République populaire de Chine] ; Xi Li [République populaire de Chine] ; Zhangfeng Shen [République populaire de Chine] ; Yangang Wang [République populaire de Chine] ; Lifeng Cui [République populaire de Chine]Source :
- Journal of colloid and interface science [ 1095-7103 ] ; 2020.
Abstract
A simple one-step preparation of biomass derived carbon materials with hierarchical pore structure for supercapacitor application is proposed. Briefly, potassium citrate is loaded onto poplar catkin, a forestry and agricultural residue, for carbonization at different temperature (750-900 ℃). With the confined effect of poplar catkin and pore-forming role of potassium compounds, interconnected carbon networks combining of macropores, small mesopores and micropores are obtained. The product carbonized at 850 ℃ (S-850) processes large surface area of 2186 m2/g with two main micropore ranges distributed in 0.5-0.7 nm and 0.7-1.5 nm, and the sample of S-900 processes relatively high electrical conductivity because of the high degree of graphitization. The electrodes based on these carbon materials show main electrical double-layer capacitors with small part of pseudo-capacitors due to O-doping. The S-850 sample displays superior specific capacity at low charge-discharge current density while the electrode based on S-900 shows high specific capacity under high current density. The symmetrical devices based on S-850 give a superb stability and high energy and power densities in alkaline electrolyte. Within a voltage window of 1.4 V, the device can deliver a 13.3 Wh/kg energy density at a power density of 720 W/kg and maintain 7.8 Wh/kg at 14040 W/kg.
DOI: 10.1016/j.jcis.2020.08.088
PubMed: 32927174
Affiliations:
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Electronic address: zfshen@mail.zjxu.edu.cn.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Wang, Yangang" sort="Wang, Yangang" uniqKey="Wang Y" first="Yangang" last="Wang">Yangang Wang</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China. Electronic address: ygwang8136@mail.zjxu.edu.cn.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Cui, Lifeng" sort="Cui, Lifeng" uniqKey="Cui L" first="Lifeng" last="Cui">Lifeng Cui</name><affiliation wicri:level="1"><nlm:affiliation>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China. 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College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China; College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Li, Shaolong" sort="Li, Shaolong" uniqKey="Li S" first="Shaolong" last="Li">Shaolong Li</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Xu, Haiyang" sort="Xu, Haiyang" uniqKey="Xu H" first="Haiyang" last="Xu">Haiyang Xu</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Zou, Xuhui" sort="Zou, Xuhui" uniqKey="Zou X" first="Xuhui" last="Zou">Xuhui Zou</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Wang, Yuan" sort="Wang, Yuan" uniqKey="Wang Y" first="Yuan" last="Wang">Yuan Wang</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Cheng, Jun" sort="Cheng, Jun" uniqKey="Cheng J" first="Jun" last="Cheng">Jun Cheng</name><affiliation wicri:level="4"><nlm:affiliation>State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027</wicri:regionArea><placeName><settlement type="city">Hangzhou</settlement><region type="province">Zhejiang</region></placeName><orgName type="university">Université de Zhejiang</orgName><placeName><settlement type="city">Hangzhou</settlement><region type="province">Zhejiang</region></placeName></affiliation></author><author><name sortKey="Li, Xi" sort="Li, Xi" uniqKey="Li X" first="Xi" last="Li">Xi Li</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Shen, Zhangfeng" sort="Shen, Zhangfeng" uniqKey="Shen Z" first="Zhangfeng" last="Shen">Zhangfeng Shen</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China. Electronic address: zfshen@mail.zjxu.edu.cn.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Wang, Yangang" sort="Wang, Yangang" uniqKey="Wang Y" first="Yangang" last="Wang">Yangang Wang</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China. Electronic address: ygwang8136@mail.zjxu.edu.cn.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001</wicri:regionArea><wicri:noRegion>Jiaxing 314001</wicri:noRegion></affiliation></author><author><name sortKey="Cui, Lifeng" sort="Cui, Lifeng" uniqKey="Cui L" first="Lifeng" last="Cui">Lifeng Cui</name><affiliation wicri:level="1"><nlm:affiliation>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address: lifeng.cui@gmail.com.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093</wicri:regionArea><wicri:noRegion>Shanghai 200093</wicri:noRegion></affiliation></author></analytic><series><title level="j">Journal of colloid and interface science</title><idno type="eISSN">1095-7103</idno><imprint><date when="2020" type="published">2020</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A simple one-step preparation of biomass derived carbon materials with hierarchical pore structure for supercapacitor application is proposed. Briefly, potassium citrate is loaded onto poplar catkin, a forestry and agricultural residue, for carbonization at different temperature (750-900 ℃). With the confined effect of poplar catkin and pore-forming role of potassium compounds, interconnected carbon networks combining of macropores, small mesopores and micropores are obtained. The product carbonized at 850 ℃ (S-850) processes large surface area of 2186 m<sup>2</sup>/g with two main micropore ranges distributed in 0.5-0.7 nm and 0.7-1.5 nm, and the sample of S-900 processes relatively high electrical conductivity because of the high degree of graphitization. The electrodes based on these carbon materials show main electrical double-layer capacitors with small part of pseudo-capacitors due to O-doping. The S-850 sample displays superior specific capacity at low charge-discharge current density while the electrode based on S-900 shows high specific capacity under high current density. The symmetrical devices based on S-850 give a superb stability and high energy and power densities in alkaline electrolyte. Within a voltage window of 1.4 V, the device can deliver a 13.3 Wh/kg energy density at a power density of 720 W/kg and maintain 7.8 Wh/kg at 14040 W/kg.</div></front></TEI><pubmed><MedlineCitation Status="Publisher" Owner="NLM"><PMID Version="1">32927174</PMID><DateRevised><Year>2020</Year><Month>09</Month><Day>28</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1095-7103</ISSN><JournalIssue CitedMedium="Internet"><Volume>582</Volume><Issue>Pt B</Issue><PubDate><Year>2020</Year><Month>Aug</Month><Day>27</Day></PubDate></JournalIssue><Title>Journal of colloid and interface science</Title><ISOAbbreviation>J Colloid Interface Sci</ISOAbbreviation></Journal><ArticleTitle>Hierarchically porous carbon derived from potassium-citrate-loaded poplar catkin for high performance supercapacitors.</ArticleTitle><Pagination><MedlinePgn>940-949</MedlinePgn></Pagination><ELocationID EIdType="pii" ValidYN="Y">S0021-9797(20)31130-9</ELocationID><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.jcis.2020.08.088</ELocationID><Abstract><AbstractText>A simple one-step preparation of biomass derived carbon materials with hierarchical pore structure for supercapacitor application is proposed. Briefly, potassium citrate is loaded onto poplar catkin, a forestry and agricultural residue, for carbonization at different temperature (750-900 ℃). With the confined effect of poplar catkin and pore-forming role of potassium compounds, interconnected carbon networks combining of macropores, small mesopores and micropores are obtained. The product carbonized at 850 ℃ (S-850) processes large surface area of 2186 m<sup>2</sup>/g with two main micropore ranges distributed in 0.5-0.7 nm and 0.7-1.5 nm, and the sample of S-900 processes relatively high electrical conductivity because of the high degree of graphitization. The electrodes based on these carbon materials show main electrical double-layer capacitors with small part of pseudo-capacitors due to O-doping. The S-850 sample displays superior specific capacity at low charge-discharge current density while the electrode based on S-900 shows high specific capacity under high current density. The symmetrical devices based on S-850 give a superb stability and high energy and power densities in alkaline electrolyte. Within a voltage window of 1.4 V, the device can deliver a 13.3 Wh/kg energy density at a power density of 720 W/kg and maintain 7.8 Wh/kg at 14040 W/kg.</AbstractText><CopyrightInformation>Copyright © 2020 Elsevier Inc. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Luo</LastName><ForeName>Xiaodong</ForeName><Initials>X</Initials><AffiliationInfo><Affiliation>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China; College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Shaolong</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Xu</LastName><ForeName>Haiyang</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Zou</LastName><ForeName>Xuhui</ForeName><Initials>X</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Wang</LastName><ForeName>Yuan</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Cheng</LastName><ForeName>Jun</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Xi</ForeName><Initials>X</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Shen</LastName><ForeName>Zhangfeng</ForeName><Initials>Z</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China. Electronic address: zfshen@mail.zjxu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Wang</LastName><ForeName>Yangang</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China. Electronic address: ygwang8136@mail.zjxu.edu.cn.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Cui</LastName><ForeName>Lifeng</ForeName><Initials>L</Initials><AffiliationInfo><Affiliation>Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address: lifeng.cui@gmail.com.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2020</Year><Month>08</Month><Day>27</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Colloid Interface Sci</MedlineTA><NlmUniqueID>0043125</NlmUniqueID><ISSNLinking>0021-9797</ISSNLinking></MedlineJournalInfo><CitationSubset>IM</CitationSubset><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Biomass</Keyword><Keyword MajorTopicYN="N">Hierarchical porous carbon materials</Keyword><Keyword MajorTopicYN="N">Poplar catkin</Keyword><Keyword MajorTopicYN="N">Supercapacitor</Keyword></KeywordList><CoiStatement>Declaration of Competing Interest The authors declared that there is no conflict of interest.</CoiStatement></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2020</Year><Month>07</Month><Day>16</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2020</Year><Month>08</Month><Day>23</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2020</Year><Month>08</Month><Day>24</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2020</Year><Month>9</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2020</Year><Month>9</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2020</Year><Month>9</Month><Day>14</Day><Hour>20</Hour><Minute>14</Minute></PubMedPubDate></History><PublicationStatus>aheadofprint</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">32927174</ArticleId><ArticleId IdType="pii">S0021-9797(20)31130-9</ArticleId><ArticleId IdType="doi">10.1016/j.jcis.2020.08.088</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>République populaire de Chine</li></country><region><li>Zhejiang</li></region><settlement><li>Hangzhou</li></settlement><orgName><li>Université de Zhejiang</li></orgName></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Luo, Xiaodong" sort="Luo, Xiaodong" uniqKey="Luo X" first="Xiaodong" last="Luo">Xiaodong Luo</name></noRegion><name sortKey="Cheng, Jun" sort="Cheng, Jun" uniqKey="Cheng J" first="Jun" last="Cheng">Jun Cheng</name><name sortKey="Cui, Lifeng" sort="Cui, Lifeng" uniqKey="Cui L" first="Lifeng" last="Cui">Lifeng Cui</name><name sortKey="Li, Shaolong" sort="Li, Shaolong" uniqKey="Li S" first="Shaolong" last="Li">Shaolong Li</name><name sortKey="Li, Xi" sort="Li, Xi" uniqKey="Li X" first="Xi" last="Li">Xi Li</name><name sortKey="Shen, Zhangfeng" sort="Shen, Zhangfeng" uniqKey="Shen Z" first="Zhangfeng" last="Shen">Zhangfeng Shen</name><name sortKey="Wang, Yangang" sort="Wang, Yangang" uniqKey="Wang Y" first="Yangang" last="Wang">Yangang Wang</name><name sortKey="Wang, Yuan" sort="Wang, Yuan" uniqKey="Wang Y" first="Yuan" last="Wang">Yuan Wang</name><name sortKey="Xu, Haiyang" sort="Xu, Haiyang" uniqKey="Xu H" first="Haiyang" last="Xu">Haiyang Xu</name><name sortKey="Zou, Xuhui" sort="Zou, Xuhui" uniqKey="Zou X" first="Xuhui" last="Zou">Xuhui Zou</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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